一次消解测定蔬菜中多种重金属的简捷方法

针对一般实验室检测人员少,检测任务重的问题,研究了蔬菜通过一次湿化消解后,消解液可以测定多种重金属元素的方法,大大提高了效率,减轻了工作量.     

重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物的合成及Tb3+的发光

合成了重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物RE(ClO4)3·L5·C2H5OH(RE=Gd,Tb,Dy,Tm,Yb;L=C6H5COCH2SOCH3).经元素分析、稀土络合滴定、摩尔电导及热重分析确定了配合物的组成,测定了配体及配合物的IR谱、1H NMR及铽配合物的磷光光谱、荧光激发和发射光谱,根据荧光发射光谱数据计算了铽配合物的各能级值.     

Numerical study of charge ordering in NaxCoO2

A simple microscopic model of charge ordering in the Na_xCoO₂ system is presented. The model takes into account the interplane interactions between the ordered Na ions and d electrons from the CoO₂ layers as well as the nearest-neighbor intraplane Coulomb interactions between d electrons. It is shown that a driving force of charge ordering in the CoO₂ layers is the interplane interaction that alone is able to describe various types of inhomogeneous charge ordering (e.g., the striped phases) as well as to predict correctly the conducting properties of the system.     

An expansion in the exponent for compound binomial approximations

The purpose of this paper is two-fold. First, we introduce a new asymptotic expansion in the exponent for the compound binomial approximation of the generalized Poisson binomial distribution. The dependence of its accuracy on the symmetry and shifting of distributions is investigated. Second, for compound binomial and compound Poisson distributions, we present new smoothness estimates, some of which contain explicit constants. Finally, the ideas used in this paper enable us to prove new precise bounds in the compound Poisson approximation. Published in Lietuvos Matematikos Rinkinys, Vol. 46, No. 1, pp. 67–110, January–March, 2006.     

混杂配体金属簇合物的分子振动光谱与结构

由于原子簇化合物在催化，生物活性，功能材料等方面所呈现的重要性，使其成为无机和物理化学最重要的研究领域之一。文章中和谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行.     

Reactions of mercury salts with benzo- and tetrafluorobenzobarrelenes

Regiochemistry and stereochemistry of the addition of mercury salts to benzobarrelene and tetrafluorobenzobarrelene have been studied in acetic acid and methanol. The effect of the substrate structure on the regiochemistry of the reaction is discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1105–1108, June, 1994.     

Metallic radii of nonmetals

Experimental data are used to determine the atomic volumes and radii of the elements of subgroups IV–VIIA in the structures of metallic phases at high pressures. Metallic radii of nonmetals are compared with values based on Pauling and Goldschmidt calculations.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 220–222, February, 1994.     

Features of the Motion of a Gas-Liquid Medium in a Compound Shell (Sphere and Truncated Cone) Subject to Vibration

The results from an experimental study into the dynamic behavior of a gas-liquid medium and solid particles in a compound shell (sphere-truncated cone) are reported on. The following processes are studied: formation of gas bubbles and their clusters, strong macroflows, and intensive chaotic motion of the medium in the truncated cone as a nonlinear vibrating liquid-gas system__________Translated from Prikladnaya Mekhanika, Vol. 41, No. 1, pp. 112–118, January 2005.     

Basic principles of technological shaping of optical properties and radiation hardness of PWO crystals

Technological conditions ensuring growth of optically homogeneous lead tungstate (PWO) crystals are reported. It is shown that the basic scintillator characteristics of PWO grown from highly purified raw material and properly doped with lanthanides are mainly determined by inclusions of oxides W_1−yL_yO_3−x (L=Y, La, Gd; 0<x<0.3). Moreover, surface-located inclusions with structure close to tungstenite may also be of importance. It is demonstrated that the scintillation properties can be intentionally designed by varying the oxygen content in the inclusions x and the surface structure. The optimal value for x and the most favorable surface structure are achieved by proper thermal regimes and environment content during the crystal annealing. The results enabled low-cost fabrication of PWO scintillators with steady and reproducible characteristics acceptable for the CERN project ALICE and ensured production of PWO on an industrial scale by “North Crystals” company at a rate of 125–135 crystals per year from every growth apparatus.     

Influence of the light illumination on thermoluminescence properties of PbWO4

The thermally stimulated properties of PbWO₄ in the temperature range 90–400 K have been investigated on undoped and terbium-doped crystals after X-ray irradiation at 90 K. Doping with terbium changes the concentration of shallow traps, which are responsible for retrapping free electrons and holes. Light illumination can change the distribution of the traps. The optically stimulated luminescence is observed. The influence of light illumination on the TSL curves and emission properties is studied. The possible mechanism of TSL phototransformation is discussed.