全文获取类型
收费全文 | 37668篇 |
免费 | 2474篇 |
国内免费 | 2926篇 |
专业分类
化学 | 27493篇 |
晶体学 | 525篇 |
力学 | 1483篇 |
综合类 | 215篇 |
数学 | 3135篇 |
物理学 | 10217篇 |
出版年
2023年 | 330篇 |
2022年 | 718篇 |
2021年 | 741篇 |
2020年 | 933篇 |
2019年 | 990篇 |
2018年 | 989篇 |
2017年 | 1333篇 |
2016年 | 1524篇 |
2015年 | 1210篇 |
2014年 | 1445篇 |
2013年 | 3138篇 |
2012年 | 1953篇 |
2011年 | 1966篇 |
2010年 | 1720篇 |
2009年 | 2310篇 |
2008年 | 2147篇 |
2007年 | 2322篇 |
2006年 | 2021篇 |
2005年 | 1547篇 |
2004年 | 1409篇 |
2003年 | 1253篇 |
2002年 | 1147篇 |
2001年 | 1013篇 |
2000年 | 991篇 |
1999年 | 824篇 |
1998年 | 810篇 |
1997年 | 626篇 |
1996年 | 538篇 |
1995年 | 557篇 |
1994年 | 468篇 |
1993年 | 407篇 |
1992年 | 443篇 |
1991年 | 310篇 |
1990年 | 261篇 |
1989年 | 223篇 |
1988年 | 261篇 |
1987年 | 264篇 |
1986年 | 177篇 |
1985年 | 149篇 |
1984年 | 165篇 |
1983年 | 67篇 |
1982年 | 142篇 |
1981年 | 192篇 |
1980年 | 199篇 |
1979年 | 194篇 |
1978年 | 169篇 |
1977年 | 105篇 |
1976年 | 110篇 |
1973年 | 92篇 |
1972年 | 38篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
82.
K. Y. Sandhya C. K. S. Pillai K. Sree Kumar 《Journal of Polymer Science.Polymer Physics》2004,42(7):1289-1298
New hydrogen‐bonded liquid‐crystalline poly(ester amide)s (PEA)s were obtained from 1,4‐terephthaloyl[bis‐(3‐nitro‐N‐anthranilic acid)] (5) or 1,4‐terephthaloyl[bis‐(N‐anthranilic acid)] (6), with or without nitro groups, respectively, through the separate condensation of each with hydroquinone or dihydroxynaphthalene. The dicarboxylic monomers were synthesized from 2‐aminobenzoic acid. The phase behavior of the monomers and polymers were studied with differential scanning calorimetry, polarized light microscopy, and wide‐angle X‐ray diffraction methods. Monomer 5, containing nitro groups, exhibited a smectic liquid‐crystalline phase, whereas the texture of monomer 6 without nitro groups appeared to be nematic. The PEAs containing nitro groups exhibited polymorphism (smectic and nematic), whereas those without nitro groups exhibited only one phase transition (a nematic threaded texture). The changes occurring in the phase behavior of the polymers were explained by the introduction of nitro groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1289–1298, 2004 相似文献
83.
Nylon‐6/glass‐fiber (GF)/liquid‐crystalline‐polymer (LCP) ternary blends with different viscosity ratios were prepared with three kinds of nylon‐6 with different viscosities as matrices. The rheological behaviors of these blends were characterized with capillary rheometry. The morphology was observed with scanning electron microscopy and polarizing optical microscopy. This study showed that although LCP did not fibrillate in binary nylon‐6/LCP blends, LCP fibrillated to a large aspect ratio in some ternary blends after GF was added. The addition of 5 wt % LCP significantly reduced the melt viscosity of nylon‐6/GF blends to such an extent that some nylon‐6/GF/LCP blends had quite low viscosities, not only lower than those of neat resins and nylon‐6/GF blends but also lower than those of corresponding nylon‐6/LCP blends. The mutual influence of the morphology and rheological properties was examined. The great reduction of the melt viscosity was considered the result of LCP fibrillation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1619–1627, 2004 相似文献
84.
85.
采用高速PIN光电探测器和高带宽的数字存储示波器,实时检测透射光脉冲和散射光脉冲的变化特征,并将之用作材料破坏的光学判据,测量得到K9玻璃在1.06μm纳秒脉冲激光作用下的能量损伤阈值约18mJ,相应的能量密度阈值为1.0kJ/cm2。通过分析透射光脉冲和散射光脉冲的特征,给出了材料的破坏时刻,并推断出K9玻璃所能承受的极限光强为1015W/m2。研究了能量透过率与泵浦能量的关系,并初步探讨了透明材料的破坏机理。结果表明:在多纵模激光的作用下,透明光学材料破坏是电离击穿与自聚焦效应综合作用的结果。 相似文献
86.
87.
波长19.6nm的类氖锗X光激光适合作为诊断激光等离子体界面不稳定性的光源。用经过实验检验的系列程序对预-主短脉冲驱动类氖锗进行了系统的优化设计和理论分析。采用2%~3%的预脉冲强度,6~8ns的预-主脉冲时间间隔,在4×1013W/cm2功率密度驱动下, 波长19.6nm增益区的宽度可以超过60μm,增益区的维持时间可以达到90ps。对于16mm长的平板靶,增益系数可达11.8/cm;弯曲靶增益系数可达13.3/cm;单靶小增益长度积可达21.3,单靶就可以获得饱和增益。采用双靶对接,其小讯号增益可达38.4,可以获得深度饱和增益,能满足应用演示所需的X光激光光源。 相似文献
88.
从激光推进的要求出发,阐述了用于激光推进的高功率激光器的选择原则,即激光器必须满足:(1)高的平均功率和峰值功率;(2)高的单脉冲能量;(3)高的重复频率;(4)优良的大气传输特性。主要分析了目前YAG固体激光器、自由电子激光器和TEA脉冲CO2激光器的特点,通过上述4个方面性能的比较,认为在目前水平下,TEA脉冲CO2激光器是进行激光推进的首选强激光源,其优点表现在:功率可达10kW量级,单脉冲能量可达0.5~1kJ,重复频率为20~40Hz;激光波长处于大气传输窗口,对大气变化不敏感;工作物质快速流动,不存在热透镜效应和破坏阈值;相关光学元件易于制造;光束质量较好;运行成本低。 相似文献
89.
Xanthenediones derivatives have attracted considerable interests in recent times because they constitute a structural unit in a number of natural products1 and have been used as versatile synthons due to the inherent reactivity of the inbuilt pyran ring2. The conventional syntheses of xanthenediones were acid or base catalyzed condensation of appropriate active methylene carbonyl compounds with aldehydes3. However, many of these procedures involved longer reaction times,low yields and side reactions of aldehydes. In recent years, room temperature ionic liquids (RTILs) have been used as novel green reaction media4. Considering that InCl3 is an efficient Lewis acid catalyst used in promoting many organic reactions, especially in several condensation processes, we herein wish to report a very simple and green method for the preparation of poly-hydrogenated xanthenediones through InCl3·4H2O promoted cascade reaction of aldehydes and 5,5-dimethyl-l,3-cyclohexanedione in ionic liquid,1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]). The preparative process presented here is operationally simple, environmentally benign and has the advantage of enhanced atom utilization. Furthermore, the solvent and the catalyst used can be recovered easily and reused efficiently. 相似文献
90.
Lahcne Mezrag 《Mathematische Nachrichten》2004,266(1):60-67
In [5], it is proved that a bounded linear operator u, from a Banach space Y into an Lp(S, ν) factors through Lp1 (S, ν) for some p1 > 1, if Y* is of finite cotype; (S, ν) is a probability space for p = 0, and any measure space for 0 < p < 1. In this paper, we generalize this result to uv, where u : Y → Lp(S, ν) and v : X → Y are linear operators such that v* is of finite Ka?in cotype. This result gives also a new proof of Grothendieck's theorem. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献