全文获取类型
收费全文 | 9691篇 |
免费 | 1528篇 |
国内免费 | 621篇 |
专业分类
化学 | 5123篇 |
晶体学 | 695篇 |
力学 | 580篇 |
综合类 | 61篇 |
数学 | 1048篇 |
物理学 | 4333篇 |
出版年
2024年 | 16篇 |
2023年 | 86篇 |
2022年 | 205篇 |
2021年 | 223篇 |
2020年 | 305篇 |
2019年 | 261篇 |
2018年 | 275篇 |
2017年 | 344篇 |
2016年 | 471篇 |
2015年 | 393篇 |
2014年 | 545篇 |
2013年 | 1201篇 |
2012年 | 487篇 |
2011年 | 625篇 |
2010年 | 523篇 |
2009年 | 633篇 |
2008年 | 567篇 |
2007年 | 678篇 |
2006年 | 555篇 |
2005年 | 470篇 |
2004年 | 411篇 |
2003年 | 385篇 |
2002年 | 266篇 |
2001年 | 251篇 |
2000年 | 215篇 |
1999年 | 238篇 |
1998年 | 177篇 |
1997年 | 156篇 |
1996年 | 165篇 |
1995年 | 108篇 |
1994年 | 82篇 |
1993年 | 75篇 |
1992年 | 61篇 |
1991年 | 52篇 |
1990年 | 54篇 |
1989年 | 30篇 |
1988年 | 44篇 |
1987年 | 31篇 |
1986年 | 32篇 |
1985年 | 17篇 |
1984年 | 25篇 |
1983年 | 12篇 |
1982年 | 17篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 12篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1975年 | 6篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
The behavior of zirconium atoms at the W(100) surface associated with oxygen adsorption at different sample temperatures has been studied by Auger electron spectroscopy (AES), ion scattering spectroscopy (ISS), and the relative change of the work function (Δф) measured by the onset of the secondary electron energy distribution. The results have revealed: (i) adsorption of zirconium onto the W(100) surface followed by the elevation of the sample temperature up to 1710 K in an oxygen partial pressure of 2.7 × 10−4 induces complete diffusion of zirconium atoms into the W(100) substrate; (ii) further exposure of oxygen induces co-existence of oxygen and tungsten on the surface at 1710 K, resulting in a work function of 4.37 eV; (iii) keeping the sample temperature at 1710 K, simple evacuation of the system has resulted in surface segregation of zirconium atoms to the surface to form a zirconium atomic layer on the top-most surface, reducing the work function to 2.7 eV. The results have revealed that this specific behavior of zirconium atoms at high temperature assures, with very good reproducibility, the highly stable performance and long service life of Zr---O/W(100)-emitters in practical use, even in a low vacuum of 10−6 Pa. 相似文献
82.
83.
Summary The nematic planar anchoring is usually explained by using simple elastic models: the surface easy axis corresponds to the
surface direction that minimizes the excess of nematic elastic energy. When anisotropic rough substrates are used to align
nematic liquid crystals, due to the complex surface morphology, usual elastic models are not directly applicable. This paper
presents quantitative topographical data of rough substrates, obtained with oblique SiO evaporation under vacuum for nematic
planar anchoring. Experimental data are obtained by means of Atomic Force Microscopy and they are used to demonstrate the
self-affine nature of these substrates and to relate the nematic anchoring with the anisotropy of the local fractal properties
of the substrate itself.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
84.
Brad M. Rosen Virgil Percec 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4950-4964
Atom transfer radical polymerization (ATRP) and single electron‐transfer living radical polymerization (SET‐LRP) both utilize copper complexes of various oxidation states with N‐ligands to perform their respective activation and deactivation steps. Herein, we utilize DFT (B3YLP) methods to determine the preferred ligand‐binding geometries for Cu/N‐ligand complexes related to ATRP and SET‐LRP. We find that those ligands capable of achieving tetrahedral complexes with CuI and trigonal bipyramidal with axial halide complexes with [CuIIX]+ have higher energies of stabilization. We were able to correlate calculated preferential stabilization of [CuIIX]+ with those ligands that perform best in SET‐LRP. A crude calculation of energy of disproportionation revealed that the same preferential binding of [CuIIX]+ results in increased propensity for disproportionation. Finally, by examining the relative energies of the basic steps of ATRP and SET‐LRP, we were able to rationalize the transition from the ATRP mechanism to the SET‐LRP mechanism as we transition from typical nonpolar ATRP solvents to polar SET‐LRP solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4950–4964, 2007 相似文献
85.
Aurelien Drezet 《Pramana》2007,68(3):389-396
In a paper by Home and Agarwal [1], it is claimed that quantum nonlocality can be revealed in a simple interferometry experiment
using only single particles. A critical analysis of the concept of hidden variable used by the authors of [1] shows that the
reasoning is not correct.
相似文献
86.
FANG Qi LEI Hong CUI Yuezhi HUANG Zhenli XUE Gang & YU Wentao . State Key Laboratory of Crystal Materials Shandong University Jinan China . School of Information Science Engineering Shandong University Jinan China . Department of Chemical Engineering Light Industry College of Shandong Jinan China . Key Laboratory of Biomedical Photonics Ministry of Education Huazhong University of Science Technology Wuhan China 《中国科学B辑(英文版)》2005,48(3)
Organic nonlinear optics (NLO) is also called mo-lecular nonlinear optics. In recent years organic mate-rials have been intensively studied because of their large NLO coefficients and structural diversities[1―3]. Second harmonic generation (SHG) is a bas… 相似文献
87.
P. Galatola M. Zelazna I. Lelidis 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(1):51-56
We study the surface behavior of a semi-infinite smectogenic sample bounded by a solid wall, in the presence of an external
electric field. Our analysis is performed in the framework of a Landau-de Gennes theory. For the sake of simplicity, we consider
only the case in which, in the absence of field and surfaces, a direct isotropic to smectic-A transition occurs, while in
the presence of the electric field a nonspontaneous nematic phase appears. Two new surface phases are identified, namely a
parasmectic and a surface-induced smectic phase. The shifts in the transition temperatures and the critical behavior of the surface states are analyzed.
Received: 25 August 1997 / Accepted: 23 January 1998 相似文献
88.
本文将布拉格方程推广应用到高聚物的结构研究中,得到了经不同剂量辐照的聚乙烯单晶的长周期,并辅以示差扫描量热法研究了γ-射线辐照对聚乙烯单晶结构的影响. 相似文献
89.
The adsorption of CN on Cu(1 1 1), Ni(1 1 1) and Ni(1 0 0) has been investigated using density functional theory (DFT). While experimental studies of CN on Cu(1 1 1) show the molecular axis to be essentially parallel to the surface, the normally-preferred DFT approach using the generalised gradient approximation (GGA) yields a lowest energy configuration with the C-N axis perpendicular to the surface, although calculations using the local density approximation (LDA) do indicate that the experimental geometry is energetically favoured. The same conclusions are found for CN on Ni(1 1 1); on both surfaces bonding through the N atom is always unfavourable, in contrast to some earlier published results of ab initio calculations for Ni(1 1 1)/CN and Ni(1 0 0)/CN. The different predictions of the GGA and LDA approaches may lie in subtly different relative energies of the CN 5σ and 1π orbitals, a situation somewhat similar to that for CO adsorbed on Pt(1 1 1) which has proved challenging for DFT calculations. On Ni(1 0 0) GGA calculations favour a lying-down species in a hollow site in a geometry rather similar to that found experimentally and in GGA calculations for CN on Ni(1 1 0). 相似文献
90.
A novel method of obtaining shearing interferogram by slightly moving the crystal in a photorefractive interferometer is proposed. This method can measure the phase of an object itself instead of its diffraction field, and it is easy to realize continuously changeable shearing distance in any lateral direction and introduce carrier fringes at the same time. Both the theoretical analysis and experimental verification are given. 相似文献