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101.
CaMoO4:Eu3+,Bi3+,Li+红色荧光粉的共沉淀制备与表征 总被引:1,自引:0,他引:1
采用共沉淀法合成了红色荧光粉Ca0.75MoO4:Eu0.253+、Ca0.75MoO4:Eu0.25-x3+,Bix3+及Ca0.5MoO4:Eu0.25-2x3+, Bix3+,Li0.25+x+,并采用X射线衍射(XRD)、拉曼光谱,扫描电镜(SEM)和荧光光谱(PL)测定分析了其结构形貌特征及发光性能。结果表明:制备的CaMoO4:Eu3+,Bi3+,Li+红色荧光粉为白钨矿结构,颗粒尺寸约为0.5~1 μm。掺杂Bi3+的Ca0.75MoO4:Eu0.25-x3+,Bix3+的相对发光强度明显高于未掺Bi3+的Ca0.75MoO4:Eu0.253+荧光粉。Bi3+离子的掺杂将吸收来的能量传递给激活离子Eu3+,起到了能量传递的作用。当Bi3+掺杂量为x=0.005时,在395 nm激发下,主发射峰在616 nm处的相对发光强度最大,但掺杂浓度过高时会出现浓度猝灭现象。另外,电荷补偿剂的掺入能够解决材料中因同晶取代引起的电荷不平衡的问题,以Li+作电荷补偿剂、Eu3+和 Bi3+共掺合成的Ca0.5MoO4:Eu3+0.23,Bi0.013+,Li+0.26红色荧光粉的发光性能强于Ca0.75MoO4:Eu0.253+、Ca0.5MoO4:Eu0.253+, Li0.25+及Ca0.75MoO4:Eu0.243+,Bi0.013+。 相似文献
102.
Reagen Ying‐Tai Su Li‐Ko Chiu Shan‐Wei Weng Ying‐Shiun Chou Raymond Chien‐Chao Tsiang 《Journal of Polymer Science.Polymer Physics》2012,50(4):280-288
White polymeric light‐emitting diode (WPLED) based on a single polymer, poly(3‐hexylthiophene‐alt‐9,9‐dioctylfluorene) (PTAF), has been successfully demonstrated. This conjugated alternating copolymer, PTAF, comprises 50 mol % of 3‐hexylthiophene which is an orange‐red color chromophore and 50 mol % 9,9‐dioctylfluorene which is a bluish‐green color chromophore. It was synthesized by Suzuki cross‐coupling reaction and has a molecular weight of 15,021 and polydispersity of 1.36. Nanocomposite consisting PTAF and graphene nanosheets enhances the optoelectronic properties and the device fabricated with a configuration of ITO/PEDOT:PSS/(PTAF + 1% graphene)/Ca/Al shows two‐color white electroluminescence with CIE 1931 coordinates of (0.28, 0.34). The white luminescence from a single polymer affords the WPLED device a simple structure and low fabrication cost. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
103.
Yasemin Yuksel Durmaz Marco Sangermano Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):2862-2868
A novel method for surface modification of UV‐cured epoxy network was described. Photoinitiated cationic copolymerization of a bisepoxide, namely 3,4‐epoxy cyclohexylmethyl 3,4‐epoxycyclohexanecarboxylate (EEC) with epibromohydrine (EBH) by using a cationic photoinitiator, [4‐(2‐methylpropyl)phenyl]4‐methylphenyl‐iodonium hexafluorophosphate, in propylene carbonate solution was studied. The real‐time Fourier transform infrared spectroscopic, gel content determination and thermal characterization studies revealed that both EEC and EBH monomers take part in the polymerization and epoxy network possessing bromomethyl functional groups was obtained. The bromine functions of the cured product formed on the glass surface were converted to azide functionalities with sodium azide. Independently prepared alkyne functional poly(ethylene glycol) (PEG) was subsequently anchored to azide‐modified epoxy surface by a “click” reaction. Surface modification of the network through incorporation of hydrophilic PEG chain was evidenced by contact angle measurements. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2862–2868, 2010 相似文献
104.
Anna Hayer Tanguy Van Regemorter Bianca Höfer Chris S. K. Mak David Beljonne Anna Köhler 《Journal of Polymer Science.Polymer Physics》2012,50(5):361-369
Although carbazole‐containing copolymers are frequently used as hole‐transporting host materials for polymer organic light‐emitting diodes (OLEDs), they often suffer from the formation of undesired exciplexes when the OLED is operated. The reason why exciplexes sometimes form for electrical excitation, yet not for optical excitation is not well understood. Here, we use luminescence measurements and quantum chemical calculations to investigate the mechanism of such exciplex formation for electrical excitation (electroplex formation) in a carbazole–pyridine copolymer. Our results suggest that the exciplex is formed via a positively charged interchain precursor complex. This complex is stabilized by interactions that involve the nitrogen lone pairs on both chain segments. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 相似文献
105.
Suchinder K. Sharma Shreyas S. Pitale T.K. GunduRao M.S. Qureshi 《Journal of luminescence》2010,130(2):240-248
A simple solution combustion synthesis route for preparation of Cu-doped SrAl4O7 has been described. Average particle size of 33 nm and platelet-like morphology has been observed. ESR studies confirm the presence of Cu in polycrystalline SrAl4O7. Bright-green luminescence under near-UV irradiation arising due to transition between Cu+ levels with microsecond level decay time makes it suitable for application in phosphor converted light emitting diode (LED). TL measurements show broad glow peaks which when deconvoluted indicate activation energies in the range of 0.6-1.1 eV and elucidate the trapping dynamics. 相似文献
106.
David R. Harding Holly Goodrich Aaron Caveglia Mitchell Anthamatten 《Journal of Polymer Science.Polymer Physics》2014,52(14):936-945
Knowing the mechanical properties of UV‐curable resins at cryogenic conditions is important to ongoing fusion‐energy research and to emerging aerospace applications. The tensile and interfacial shear strengths of two commercially available UV‐curable resins were measured at room‐temperature and cryogenic conditions for both bulk and reduced (subnanoliter) specimen volumes. The tensile properties of cured specimens are remarkably sensitive to both testing temperature and specimen size. For one type of resin, the cold (?150 °C) tensile strength of subnanoliter specimens is ~9× larger (179 ± 19 MPa) than bulk values at room temperature. The interfacial shear strength between SiC fibers and small volumes of resin volumes is comparable to the bulk, room‐temperature tensile strength, but it varies over a wide range at ?150 °C (15–53 MPa). All resins were fully cured, and an analysis of fractured surfaces revealed microstructural features. The enhanced strength in microscopic specimens may be related to inhomogeneous stress fields that develop during cure. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 936–945 相似文献
107.
Road signs must provide a conspicuous signal to a wide variety of drivers over a broad range of environmental and geometric
conditions. Recently, there are an increasing number of applications in which light emitting diodes (LEDs) are used as the
light source, including critical transportation signaling. In the presence of fog, the resulting visual signal is disturbed
due to light scattering by airborne water droplets. By measuring LED brightness with human spectral sensitivity in various
densities and various droplet sizes (10, 30, 50, and 100 μm), it is understood that the particle size distribution (fog droplet
size) and density of fog does affect visibility in fog. The colored LEDs that contain a yellow component had high brightness
evaluation, blue component had low brightness evaluation in all densities and different droplet sizes. The result in this
paper can contribute to air and land traffic safety and the prevention of accidents. 相似文献
108.
Xufeng Wu Gaoquan Shi Feng'En Chen Shaohu Han Junbiao Peng 《Journal of polymer science. Part A, Polymer chemistry》2004,42(12):3049-3054
Poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐p‐phenylenevinylene] (MEH‐PPV) with a molar mass of 26–47 × 104 g mol?1 and a polydispersity of 2.5–3.2 was synthesized by a liquid–solid two‐phase reaction. The liquid phase was tetrahydrofuran (THF) containing 1,4‐bis(chloromethyl)‐2‐methoxy‐5‐(2′‐ethylhexyloxy)benzene as the monomer and a certain amount of tetrabutylammonium bromide as a phase‐transfer catalyst. The solid phase consisted of potassium hydroxide particles with diameters smaller than 0.5 mm. The reaction was carried out at a low temperature of 0 °C and under nitrogen protection. No gelation was observed during the polymerization process, and the polymer was soluble in the usual organic solvents, such as chloroform, toluene, THF, and xylene. A polymer light‐emitting diode was fabricated with MEH‐PPV as an active luminescent layer. The device had an indium tin oxide/poly(3,4‐ethylenedioxylthiophene) (PEDOT)/MEH‐PPV/Ba/Al configuration. It showed a turn‐on voltage of 3.3 V, a luminescence intensity at 6.1 V of 550 cd/m2, a luminescence efficiency of 0.43 cd/A, and a quantum efficiency of 0.57%. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3049–3054, 2004 相似文献
109.
Qinghua Zhao Thi Tuyet Mai Dang Dong‐Cheol Shin Hong You Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):341-347
Diphenylaminobiphenylated stryl based alternating copolymers with phenyl or fluorene, which were expected to have a terphenylene vinylene backbone containing an (N,N‐diphenylamino)biphenyl pendant and a phenyl/fluorene/phenylene vinylene backbone containing an (N,N‐diphenylamino)biphenyl pendant, were synthesized by a Suzuki coupling reaction. The obtained copolymers were confirmed with various types of spectroscopy. The alternating copolymers showed good hole‐injection properties because of their low oxidation potential and good solubility and high thermal stability with a high glass‐transition temperature. The alternating copolymers showed blue emissions because of the adjusted conjugation lengths; the maximum wavelength was 460 nm for poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐5‐(2′‐ethylhexyloxy)‐2‐methoxybenzene} and 487 nm for poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl] vinylene‐alt‐9,9‐dihexylfluorene}. The maximum brightness of indium tin oxide/poly(3,4‐ethylene dioxythiophene)/polymer/LiF/Al devices with poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐5‐(2′‐ethylhexyloxy)‐2‐methoxybenzene} or poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐9,9‐dihexylfluorene} as the emitting layer was 250 or 1000 cd/m2, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 341–347, 2007 相似文献
110.