全文获取类型
收费全文 | 2210篇 |
免费 | 137篇 |
国内免费 | 354篇 |
专业分类
化学 | 1973篇 |
晶体学 | 6篇 |
力学 | 90篇 |
综合类 | 18篇 |
数学 | 42篇 |
物理学 | 572篇 |
出版年
2024年 | 2篇 |
2023年 | 15篇 |
2022年 | 21篇 |
2021年 | 47篇 |
2020年 | 57篇 |
2019年 | 54篇 |
2018年 | 59篇 |
2017年 | 61篇 |
2016年 | 63篇 |
2015年 | 77篇 |
2014年 | 121篇 |
2013年 | 296篇 |
2012年 | 85篇 |
2011年 | 149篇 |
2010年 | 101篇 |
2009年 | 110篇 |
2008年 | 124篇 |
2007年 | 162篇 |
2006年 | 126篇 |
2005年 | 113篇 |
2004年 | 112篇 |
2003年 | 120篇 |
2002年 | 95篇 |
2001年 | 81篇 |
2000年 | 72篇 |
1999年 | 56篇 |
1998年 | 60篇 |
1997年 | 43篇 |
1996年 | 35篇 |
1995年 | 24篇 |
1994年 | 32篇 |
1993年 | 33篇 |
1992年 | 21篇 |
1991年 | 12篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 9篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1970年 | 4篇 |
排序方式: 共有2701条查询结果,搜索用时 218 毫秒
31.
微波促进下N,N-二甲基甲酰胺中的Knoevenagel反应 总被引:2,自引:0,他引:2
在微波促进下,芳醛与丙二腈或氰基乙酸乙酯在DMF中进行Knoevenagel缩合反应,以77%~98%的产率生成相应E-式烯烃。 相似文献
32.
33.
STUDY ON THE CARDANOL-ALDEHYDE CONDENSATION POLYMER CONTAINING BORON-NITROGEN COORDINATE BOND 总被引:1,自引:0,他引:1
Cardanol-aldehyde condensation polymer containing boron-nitrogen co-ordinate bond (CFBN) has been synthesized and characterized by IR, XPS, HPLC andDTA-TG. Its properties were also investigated. The results show that the coating filmof CFBN has excellent physico-mechanical properties, good anticorrosive properties andstable at high temperature. 相似文献
34.
Kh. S. Shikhaliev A. V. Falaleev G. I. Ermolova A. S. Solov'ev 《Chemistry of Heterocyclic Compounds》2002,38(2):210-212
4,6,6-Trimethyl-1,4-dihydropyrimidines have been synthesized by condensation of 2-quinazolylguanidines with mesityl oxide. The analogous reaction with benzalacetone leads to unstable 4-methyl-6-phenyl-1,4-dihydropyrimidines, which are oxidized to the corresponding 4-methyl-6-phenylpyrimidines. 相似文献
35.
Production of submicron-size monodisperse polymer particles having aldehyde groups by seeded aldol condensation polymerization 总被引:2,自引:0,他引:2
Submicron-size monodisperse polystyrene/polyglutaraldehyde composite particles having aldehyde groups at the surfaces were produced by seeded aldol condensation polymerization of glutaraldehyde in the presence of polystyrene particles prepared by emulsifier-free emulsion polymerization. This technique is expected to be useful for the production of size-controlled polymer particles having aldehyde groups.Part CXXXVI of the series Studies on Suspension and Emulsion 相似文献
36.
Guo Hua GAO Jin Bao GAO Wen Juan ZHOU Liang LU Ming Yuan HE 《中国化学快报》2006,17(10):1293-1296
Since much more attention has been paid to the sustainable development, many researchers try to improve conventional chemical process and find new and more, environmentally friendly routes1. Aqueous-phase reactions are of interest as environ- mentally ben… 相似文献
37.
38.
A. I. Kovalev Yu. I. Lyakhovetskli M. M. Teplyakov A. L. Rusanov P. V. Petrovskii S. O. Yakushin 《Russian Chemical Bulletin》1993,42(9):1529-1535
The chemical heterogeneity of polyphenylenes obtained by trimerization poiycycio-condensation of acetylaromatic compounds has been investigated by GLC-MS analysis of the products of trimerization cyclocondensation of acetophenone. The mechanism for the formation of side products of the reaction is discussed. The presence of dypnone fragments in the polyphenylene structure results in a decrease in the thermal stability of these polymers.Deceased March, 1993.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1595–1601, September, 1993. 相似文献
39.
The molecular weight distribution (MWD) and arm length distribution of AB, Ar type condensation polymers obtained by adding AB monomers in batches have been derived by statistical and kinetic methods. Calculations show the MWD of condensation polymers obtained by this process is much narrower than that of one batch reaction and agrees with the Monte Carlo results very well. 相似文献
40.