Anharmonic dynamical behaviour in bcc zirconium

We present inelastic neutron scattering measurements of the low energy and strongly damped phonons in the high temperature bcc phase of zirconium. These phonons were investigated at different scattering vectors but equivalent phonon wave vectors in different Brillouin zones or along different but equivalent paths in the same Brillouin zone. Neither the observed differences in intensity nor in line shapes can be explained by the coherent one-phonon scattering law . This leads to an apparent violation of the fundamental symmetry of lattice dynamics. Taking into account the strong anharmonicity of these phonons, interferences between one- and multi-phonon scattering are held responsible for these effects. Measurements in different scattering planes reveal that due to the symmetry of the bcc lattice, these effects can only be observed in certain directions. Received: 24 December 1997 / Received in final form: 9 March 1998 / Accepted: 19 March 1998     

Problems of the electronic structure of nonmetals in a wide energy region of fundamental absorption (review)

The article surveys the main unsolved problems of the electronic structure of nonmetals in a wide energy region of fundamental absorption. Udmurtia State University, 71, Krasnogeroiskaya Str., Izhevsk, 426034, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 3, pp. 299–315, May–June, 1999.     

Electronic structure of C60 films

A complete set of fundamental optical functions of fullerite (C₆₀) films in energy ranges of 2.5–5.0 and 4.0–9.0 eV is calculated using the known spectra of the imaginary and real parts of the dielectric constant. An integrated spectrum of the dielectric constant is decomposed into elementary components. Three basic parameters of each component (the maximum and halfwidth energies and oscillator strength) are determined. Based on the known theoretical calculations of fullerite zones, a scheme of the nature of these components of the dielectric constant is suggested. Udmurt State University, 71, Krasnogeroiskaya Str., Izhevsk, 426034, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 2, pp. 227–232, March–April, 1999.     

The 2ν5 overtone bands of perchloryl fluoride

The high-resolution infrared spectra of the monoisotopic species F³⁵Cl¹⁶O₃, F³⁷Cl¹⁶O₃, F³⁵Cl¹⁸O₃ and F³⁷Cl¹⁸O₃ have been studied in the region of the 2ν₅ overtones, from 1100 to 1200 cm⁻¹. Both the parallel and the perpendicular components are clearly observed in the spectra, their origins differing by about 0.4 cm⁻¹. In each spectrum about 2000 transitions have been assigned, 35% of them belonging to . The parallel and perpendicular bands in each manifold have been analyzed separately since no evidence of perturbations has been observed. The rovibration parameters of the v₅ = 2, l₅ = 0 and v₅ = 2, l₅=?2 excited states have been obtained. For the four species combining the and band origins with those of the ν₅ fundamentals the harmonic wavenumbers, , and the x₅₅ and g₅₅ anharmonicity constants have also been derived.     

基于PHI影像敏感波段组合的冬小麦条锈病遥感监测研究

利用ASD地面非成像光谱仪对不同严重度的冬小麦条锈病的冠层光谱反射率进行测定,同时调查病情指数。通过对地面实测的46组病情指数与相应的光谱反射率进行相关性分析,筛选出了小麦条锈病在350～1 500 nm的敏感波段。结合多时相的高光谱航空飞行遥感图像数据的特点和规律,最终选择红波段的620～718 nm与近红外波段的770～805 nm为条锈病在PHI影像上的敏感波段。并利用620～718 nm和770～805 nm的平均光谱反射率与相应的病情指数建立了多元线性回归模型:DI=19.241 R_1—2.207 R_2+12.274,验证结果表明,该模型的历史拟合度很好。并利用此模型最终在PHI影像上成功的实现了对冬小麦条锈病发生程度与发生范围的监测。     

Lifetime measurements in chiral nucleus 130Cs

The level lifetimes in partner bands of 130Cs have been measured using the Doppler Shift Attenuation method. The high-spin states of 130Cs were populated via fusion evaporation reaction 124Sn(11B,5n)130Cs at a beam energy of 65 MeV. The absolute M1 and E2 transition probabilities have been deduced. The results indicate that the partner bands of 130Cs manifest the chiral properties.     

190区超形变核中转动带的组态结构

通过系统研究A～190区超形变核中转动带的转动惯量、角动量顺排、旋称分裂随转动频率的变化规律, 结合我们用处理对力的粒子数守恒方法的计算结果, 对A～190区所有转动带的组态结构给出了一个整体的描述. 绝大多数超形变带都建立在强耦合轨道上, 例如中子[512]5/2, [624]9/2. 少数超形变带则建立在高j闯入轨道上, 即中子[761]3/2, [752]5/2. 根据我们提出的组态结构所进行的理论计算结果表明, A～190区所有转动带的一般行为、反常变化和带交叉都得到了满意的解释.     

Gas-phase Raman spectra of hot bands of fundamentals and combinations associated with the torsional vibration of s-trans-1,3-butadiene and its deuterated isotopologues

The gas-phase Raman spectra of 1,3-butadiene and its 2,3-d₂, 1,1,4,4-d₄, and d₆ isotopologues have been recorded with high sensitivity and resolution of 0.7 cm⁻¹. Hot band series of fundamentals and combinations involving the ν₁₃ torsional vibration of the s-trans rotamer have been observed for each of the isotopologues. Modes studied were ν₁₀ (CH wag), ν₁₂ (CH₂ twist), ν₁₀ + ν₁₂, ν₁₅ (CH₂ wag) + ν₁₆ (CH₂ twist), and ν₂₃ (CH₂ rock) + ν₂₄ (CCC deformation). The spacings of the quantum states of the torsional contribution were found to decrease with additional excitation of this mode (ν₁₃) in the upper vibrational states except for the ν₂₃ + ν₂₄ combination state.     

High-resolution study of the ν1 + ν2 and ν2 + ν3 strongly interacting bands of D2Se

A high-resolution Fourier transform spectrum of the D₂^MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm⁻¹ was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D₂⁸⁰Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm⁻¹. The ν₁ + ν₂ and ν₂ + ν₃ bands of the other four isotopic species are analyzed as well.     

Enhanced complete photonic band gap in the optimized planar diamond structure

The diamond photonic crystal with dielectric rods has been modified to enlarge the fundamental band gap. By planarizing the diamond structure and reducing the thickness of the hexagonal meshes, the band gap can be increased substantially. The band gap is 29% for a refractive index contrast of 3.6. The modified structure is amenable to fabrication at optical and infrared wavelengths using state-of-the-art silicon-processing methods. Transfer matrix calculations demonstrate a large attenuation within the band gap.