全文获取类型
收费全文 | 33篇 |
免费 | 84篇 |
国内免费 | 26篇 |
专业分类
化学 | 52篇 |
数学 | 3篇 |
物理学 | 88篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 3篇 |
2012年 | 4篇 |
2011年 | 3篇 |
2010年 | 5篇 |
2009年 | 6篇 |
2008年 | 4篇 |
2007年 | 2篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 37篇 |
2003年 | 15篇 |
2002年 | 21篇 |
2001年 | 10篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1994年 | 2篇 |
1989年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
排序方式: 共有143条查询结果,搜索用时 15 毫秒
91.
本文举出反例说明文献[7]中关于一致β-正则的充要条件是错误的,并分别给出了诱导极限为β-正则与一致β-正则的正确的充要条件. 相似文献
92.
以NaH粉和Al 粉为合成原料, 分别采用2% (摩尔分数, x) CeCl3和2% CeCl3/y% KH (y=0.02, 0.04)为催化添加剂, 在室温和3 MPa氢压下, 通过反应球磨(NaH/Al+CeCl3)和(NaH/Al+CeCl3/yKH) (y=0.02, 0.04)复合物成功制备出Na-Al-H 配位氢化物. 吸放氢性能测试结果表明, KH的加入能有效改善Na-Al-H 体系中第二步脱氢反应放氢动力学性能. (NaH/Al+CeCl3/0.02KH)复合物170℃放氢时可在20 min内完成脱氢过程, 且在较低温度(100-140℃)下具有良好的可逆吸放氢性能. Kissenger 方法计算表明, 添加KH可降低Na-Al-H 体系第二步脱氢反应的表观活化能, 降低其放氢峰值温度. 相结构分析表明, KH的添加使Na-Al-H 体系中Na3AlH6的晶胞体积发生膨胀, 进而提高体系的第二步放氢动力学性能. 相似文献
93.
KH2PO4 crystal is a crucial optical component of inertial confinement fusion. Modulation of an incident laser by surface micro-defects will induce the growth of surface damage, which largely restricts the enhancement of the laser induced damage threshold. The modulation of an incident laser by using different kinds of surface defects are simulated by employing the three-dimensional finite-difference time-domain method. The results indicate that after the modulation of surface defects, the light intensity distribution inside the crystal is badly distorted, with the light intensity enhanced symmetrically. The relations between modulation properties and defect geometries (e.g., width, morphology, and depth of defects) are quite different for different defects. The modulation action is most obvious when the width of surface defects reaches 1.064 p-m. For defects with smooth morphology, such as spherical pits, the degree of modulation is the smallest and the light intensity distribution seems relatively uniform. The degree of modulation increases rapidly with the increase of the depth of surface defects and becomes stable when the depth reaches a critical value. The critical depth is 1.064 μm for cuboid pits and radial cracks, while for ellipsoidal pits the value depends on both the width and the length of the defects. 相似文献
94.
95.
96.
提出了一种基于乙醇-电解质-水体系双水相萃取、固体基质室温燐光法(SS-RTP)测定色氨酸的新方法:将适量电解质和乙醇加入试液中,离心后用SS-RTP测定上相中的色氨酸.在最佳萃取体系乙醇-K2HPO4-KH2PO4-H2O中,测定色氨酸的线性范围1.0×10-7~2.0×10-6mol/L、检出限5.4×10-9mol/L(S/N=3).用于大豆、大米、玉米和竹笋中色氨酸的测定,相对标准偏差2.2%~3.3%,与荧光法比较,相对误差-3.3%~3.2%. 相似文献
97.
使用纳米SiO2粉体为原料,在2.0~4.2 GPa、150~1200 ℃范围内进行了一系列的高压高温实验研究,得到了该压力温度范围内晶化产物α-石英与柯石英的p-T相图,而且该相图中的相边界在650 ℃以下斜率为负,在650 ℃以上基本水平。通过X射线衍射仪(XRD)、Raman光谱仪(Raman)、傅立叶红外光谱仪(FT-IR)、DSC-TGA差热分析仪(TG-DTA)-等表征手段,发现纳米SiO2原粉中水分(包含Si-OH和吸附水)的存在能显著降低合成柯石英的温度和时间,在4.2 GPa压力下得到了目前合成柯石英的最低温度190 ℃。常压下,合成的柯石英在800 ℃以下能够稳定存在,在1 000 ℃以上转化为α-方石英。 相似文献
98.
We consider the problem of scheduling jobs that are given as groups of non-intersecting intervals on the real line. Each job j is associated with a t-interval (which consists of up to t segments, for some t≥1), a demand, dj[0,1], and a weight, w(j). A feasible schedule is a collection of jobs such that, for every , the total demand of the jobs in the schedule whose t-interval contains s does not exceed 1. Our goal is to find a feasible schedule that maximizes the total weight of scheduled jobs.We present a 6t-approximation algorithm for this problem that uses a novel extension of the primal–dual schema called fractional primal–dual. The first step in a fractional primal–dual r-approximation algorithm is to compute an optimal solution, x*, of an LP relaxation of the problem. Next, the algorithm produces an integral primal solution x, and a new LP, denoted by P′, that has the same objective function as the original problem, but contains inequalities that may not be valid with respect to the original problem. Moreover, x* is a feasible solution of P′. The algorithm also computes a solution y to the dual of P′. The solution x is r-approximate, since its weight is bounded by the value of y divided by r.We present a fractional local ratio interpretation of our 6t-approximation algorithm. We also discuss the connection between fractional primal–dual and the fractional local ratio technique. Specifically, we show that the former is the primal–dual manifestation of the latter. 相似文献
99.
The structure and magnetic properties of Nd_{0.5}Pb_{0.5-x}Sr_xMnO_3 (0≤x≤0.4) manganites were systematically investigated. Significant changes in Curie temperature and metal-insulator (MI) transition temperature of the samples were observed. All samples exhibited a transition from paramagnetic semiconducting to ferromagnetic metallic state. Curie temperature T_C and the MI transition temperature T_p increased with increasing Sr content. We attributed these behaviours to the enhancing of both the double exchange mechanism and the Jahn-Teller electron-phonon coupling. 相似文献
100.
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and 2, as well as of the reference compound, i.e. the 1,10-saturated 5α-p-nitrobenzoate. Kinetic data and product analysis revealed that the relative spatial orientation of the 1(10)-olefinic double bond and the chiral center at C(5) in the 10-membered ring, which these secosteroidal 5-p-nitrobenzoates can adopt in the transition state, is the main factor which determines their solvolytic behaviour, so that the esters 1,2 and 5 solvolyse with transannular double bond participation, while such an interaction is not present in the case of the (Z)-5β-ester 4. 相似文献