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101.
It is found that the unrelaxed impurity dipoles can arrange themselves linearly in the structure joining each other end-to-end
in pseudocubic [110] direction at the tetragonal to the orthorhombic phase transition. It is shown that this alignment precedes
the domain formation at the phase transition, which implies quick movements of the dipoles in the structure, and a strong
dipolar interaction. The experiments with the application of dc fields to the crystals showed that the dipolar interaction
becomes stronger with the field. The dipoles can see each other across the existing domain walls implying the large distance
nature of the interaction. The observation of impurity clusters arranged in pseudocubic [110] direction confirmed the large
distance nature of the interaction. It is concluded that this strong, large distance interaction is very interesting in as
much as such an interaction of dipoles forms the basis of ferroelectricity. 相似文献
102.
转动喇曼散射截面的群论计算 总被引:1,自引:1,他引:0
本文利用群链U(4)U(3)O(3)描述双原子分子N_2和O_2振转谱的对称性质,并利用群论方法计算了N_2和O_2分子转动喇曼散射的跃迁矩阵元,给出了它们的转动喇曼散射的截面。结果与实验较好地符合。 相似文献
103.
有限维路代数的K_1群 总被引:1,自引:0,他引:1
本文通过计算有限维路代数k△的单位群和单位群的阿贝尔化,完全刻划了 任意域上有限维路代数的K1群. 相似文献
104.
REN QingBao ZHU WeiTing HONG Bo & ZHANG YuHeng Department of Physics Lishui University Lishui China National High Magnetic Field Laboratory University of Science Technology of China Hefei China 《中国科学G辑(英文版)》2007,(3)
Magnetic properties of Nd_(0.5)Sr_(0.5)Mn_(1-x)(Ga_x, Ti_x)O_3 system (0.04≤x≤0.4) were inves- tigated through magnetization and electron spin resonance (ESR) measurements. It was observed that a small amount of Ti substitution for Mn will destroy the charge-ordering (CO) phase completely and induce the cluster-spin-glass phase in the system, which displays a procedure of collapse of CO and of an enhancement of spin ordering (SO) phase. In contrast, the Ga substitution for Mn induces a melt- ing of CO phase in the system. It was observed that with substitution the CO phase is suppressed gradually and the remanent CO phase is retained all the while, and withal, there is a co-existence of AFM CO phase and FM SO at low temperature. In addition, an abrupt rise of magnetization was observed in M-T curves. We attributed this abnormal phenomenon to a transition from canted AFM SO to FM SO in CO region. 相似文献
105.
Calculations of helicity amplitudes for the low-lying nucleon resonances are displayed based on a non-relativistic constituent quark model with a harmonic oscillator confinement. The explicit effect of quark confinement isshown. Our results show that the effect plays sizable role on some transition amplitudes of S11(1535) and D13(1520)resonances. The effect on the △(1232) transition amplitudes islessthan 10%. However, the effect on the Roper resonanceis remarkable but is inconclusive. 相似文献
106.
N-Acylalkylation of neutral and anionic N-nucleophiles with α-halocarbonyl compounds was investigated by quantum chemical methods
in terms of the density functional theory and by experimental methods for 2,3-dihydroimidazo[2,1-b]quinazolin-1(10)H-5-one, its N-anion, and simpler model structures. High reactivity of these reagents is determined primarily by stabilization
of transition states (TS) by bridge bonds involving halogen or nitrogen atoms rather than by conjugation, as has been commonly
accepted. Bridged TS are formed by both the substitution mechanism S
N
2 and the addition-elimination mechanism. α-Haloalkyl-substituted zwitterions, which are potential intermediates of stepwise
N-acylalkylation of neutral N-nucleophiles, do not exist in the isolated state, but they are rather efficiently stabilized
upon solvation. These zwitterions, as well as analogous O-anions generated from anionic N-nucleophiles, can serve as intermediates
of N-acylalkylation, as was demonstrated by localization of the corresponding TS.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1150–1164, June, 2007. 相似文献
107.
Ignacio Villanueva 《Mathematische Nachrichten》2003,250(1):98-103
We clarify and prove in a simpler way a result of Taskinen about symmetric operators on C(Kn), K an uncountable metrizable compact space. To do this we prove that, for any compact space K and any n ∈ ?, the symmetric injective n–tensor product of C(K), , is complemented in C(BC(K)*), a result of independent interest. The techniques we develop allow us to extend the result in several directions. We also show that the hypothesis of metrizability and uncountability cannot be removed. 相似文献
108.
衍射辐射是由于运动的带电粒子遇到随空间变化的电介质而由感应电流产生的一种辐射. 衍射辐射由于其非阻拦性, 多参数性, 可在线性, 非常适合下一代对撞机和第四代光源的电子束诊断. 简要介绍了其物理机制, 系统的讨论了其在电子束诊断中的应用. 相似文献
109.
M.S. Bratiychuk 《Insurance: Mathematics and Economics》2007,41(1):156-162
In this paper, we present the classical risk process with two-step premium function. This means that the gross risk premium rate changes if the insurer’s surplus reaches a certain threshold level. The formula for the infinite-time ruin probability is obtained. The asymptotic behaviour of the ruin probability in the case where the claim size distribution has a light tail is considered as well. 相似文献
110.
We report the coexistence of γ(γ′) and θ alumina grown on the CoAl(1 0 0) surface. Both phases were observed after annealing of alumina at 1150 K by means of scanning tunnelling microscopy (STM). The crystal structures of γ(γ′) and θ alumina were indexed based on low energy electron diffraction (LEED) and STM experimental data. 相似文献