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151.
皂甙分离和结构鉴定研究进展 总被引:7,自引:0,他引:7
本文对近十年来皂甙分离方法和结构签定技术进行了综述,尤其是对HPLC及1DNMR、2DNMR各种新技术在皂甙分离和结构鉴定方面的应用,作了较为详细的总结。 相似文献
152.
153.
人工培养菌种茯苓菌丝体多糖的分离、组成和分子量 总被引:6,自引:0,他引:6
由人工培育的茯苓菌种 (5·78号 )在含麸皮的培养液中于 2 5℃培养 1 8天得到茯苓菌丝体 .分别用9g LNaCl水溶液、热水、0 .5mol LNaOH和 88%甲酸从菌丝体中提取 7种多糖依次为 :ab PCM1、ab PCM2 I、ab PCM2 II、ab PCM3 I、ab PCM3 II、ab PCM4 I、ab PCM4 II,并从培养液中提取一种多糖ab PCM0 .红外光谱 (IR)、气相色谱 (GC)和1 3C NMR分析结果表明ab PCM0至ab PCM3 I多糖主要由α (1→ 3 ) D 葡萄糖、α D 甘露糖、β D 半乳糖和乙酰葡萄糖胺组成 ,而且随提取过程进行 ,葡萄糖含量逐渐增加 ,即从杂多糖到α 葡聚糖 .ab PCM3 II、ab PCM4 I和ab PCM4 II则主要是 β (1→ 3 ) D葡聚糖 .有趣的是 ,α 葡聚糖和 β 葡聚糖共存在该菌丝体的碱水提取液中 .由粘度法和光散射法测定了多糖的特性粘数 [η]和重均分子量Mw .ab PCM0、ab PCM1、ab PCM2 I、ab PCM2 II、ab PCM3 I和ab PCM4 II多糖的Mw 值分别为 7 7× 1 0 4、5 2× 1 0 4、5 0× 1 0 4、2 4 3× 1 0 4、65 2×1 0 4和 2 5 5× 1 0 4. 相似文献
154.
Masaki Kita Kaori Konishi Tomoyuki Koyama Makoto Kitamura Daisuke Uemura 《Tetrahedron》2007,63(27):6241-6251
A 62-membered novel polyol macrolide with a molecular weight of 2859 mu, symbiodinolide, was isolated from the symbiotic dinoflagellate Symbiodinium sp. Symbiodinolide exhibited a potent voltage-dependent N-type Ca2+ channel-opening activity at 7 nM and immediately ruptured the tissue surface of the acoel flatworm Amphiscolops sp. at 2.5 μM. The planar structure of symbiodinolide was elucidated by spectroscopic analysis and chemical degradations including hydrolysis and ethenolysis using the second-generation Grubbs' catalyst. Symbiodinolide was found to be a structural congener of zooxanthellatoxins. The relative stereochemistries of C26-C32, C44-C51, and C64-C66 parts, and the absolute stereochemistries of C69-73, C83-C103, and C3′-C18′ parts in symbiodinolide were established. 相似文献
155.
Application of combined chromatographic techniques in the screening and purification of ecdysteroids
Summary Plants were found to contain ecdysteroids in concentrations in the order of 0.1% which are higher than those of the insects,
and are adequate for the preparative production of ecdysteroids.
A TLC screening method is elaborated for the qualitative and semiquantitative analysis of the ecdysteroid content of plants.
The combined TLC method differentiates several characteristic ecdysteroids ranging from the apolar 2-deoxyecdysone to the
polar 20,26-dihydroxyecdysone. A preparative purification method was developed consisting of solvent extraction, precipitation,
crystallization and column liquid chromatography; these procedures permit the isolation of the main ecdysteroids in gram quantities.
In some cases, droplet counter-current chromatography was also applied.
Altogether, the isolation of thirteen ecdysteroids from five different plant species was accomplished by using a fast, simple
and low-cost procedure, resulting in pure substances. 相似文献
156.
F. Esaka K.T. Esaka C.G. Lee M. Magara S. Sakurai S. Usuda K. Watanabe 《Talanta》2007,71(3):1011-1015
A new technique to measure 234U/238U and 236U/238U isotope ratios for individual particles in environmental samples was developed, which was a combination of particle isolation under scanning electron microscope (SEM) and secondary ion mass spectrometry (SIMS). The technique was verified by measuring 234U/238U and 236U/238U isotope ratios in individual particles in a simulated environmental sample containing uranium standard (NBL CRM U010) and Pb metal particles. When the uranium particles were not isolated, the relative deviations of the measured isotope ratios from the reference values increased with increasing the signal intensity ratio of 208Pb to 238U, which was due to the molecular ion interferences by the Pb particles co-existing in the sputtered area. By the isolation of individual uranium particles, the interferences were eliminated and the measured isotope ratios were in good agreement with the reference values. The maximum relative deviations among 20 particles were 8.9% for 234U/238U and 13.1% for 236U/238U isotope ratios, respectively. The technique was also successfully applied to the analysis of a real swipe sample containing various kinds of elements. 相似文献
157.
Hiromitsu Takayama Yohei Matsuda Kyohei Masubuchi Atsushi Ishida Mariko Kitajima Norio Aimi 《Tetrahedron》2004,60(4):893-900
Two new tryptamine-related alkaloids, chimonamidine and chimonanthidine, were isolated from the seeds of Chimonanthus praecox Link. and their structures including absolute configuration were elucidated by spectroscopic analysis and biomimetic total synthesis from tryptamine. 相似文献
158.
Makoto Ojika Hideo Kigoshi Takeshi Ishigaki Itaru Tsukada Hisao Ekimoto Kiyoyuki Yamada 《Tetrahedron》2007,63(15):3138-3167
Aplyronine A (2), a potent antitumor macrolide was isolated from the sea hare Aplysia kurodai together with the congeners aplyronines B (3) and C (4). The absolute stereostructure of aplyronine A (2) was determined by the instrumental analysis (mainly NMR and MS) and the enantioselective synthesis of the fragments obtained from chemical degradation of aplyronine A (2). The structures of aplyronines B (3) and C (4) were also elucidated. Cytotoxicity and antitumor activity of aplyronine A (2) were evaluated. 相似文献
159.
灯丝电源是中性束注入器等离子体发生器电源系统的重要组成部分,为了满足其低电压大电流输出特性要求,提出了带平衡电抗器双反星形整流电路的拓扑结构的电源设计方案。该拓扑结构与三相桥式整流电路相比较在采用相同器件下可达到更高功率,减少交流侧输入电流谐波并提高功率因素。分析了该拓扑结构下整流输出特性和所含的谐波分量,根据设计指标计算了整流变压器和平衡电抗器的相关参数,最后通过仿真和实验结果验证了这一拓扑结构的可行性。 相似文献
160.
Dr. Olaf Hübner Dr. Jean Thusek Prof. Hans-Jörg Himmel 《Angewandte Chemie (International ed. in English)》2023,62(11):e202218042
The bonding between two neutral aromatic compounds, especially small ones, has been controversially debated in the last decades, and terms like “π-stacking” had to be revised. Surprisingly, despite of many experimental and computational work, there is still no clear consensus about the structure of and the bonding in the pyridine dimer. In this work, for different isomeric forms of the pyridine dimer, the structures and bonding were elucidated by combining high-resolution matrix-isolation spectroscopic results with quantum-chemical calculations. High-resolution IR spectra of Ne matrices at 4 K containing pyridine were recorded for different concentrations and upon annealing to 10 and 12 K, relying on three isotopologues of pyridine. The spectra show the presence of hydrogen-bonded, T-shaped, and stacked forms of weakly-bound pyridine dimers. Among these, the hydrogen-bonded isomer is identified as the lowest-energy form. The results provide for the first time conclusive information about the interaction between two pyridine dimers. 相似文献