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141.
F. Le Normand C.S. Cojocaru O. Ersen L. Gangloff R. Alexandrescu I. Morjan 《Applied Surface Science》2007,254(4):1058-1066
Iron-based nanoparticles are prepared by a laser-induced chemical vapor deposition (CVD) process. They are characterized as body-centered Fe and Fe2O3 (maghemite/magnetite) particles with sizes ≤5 and 10 nm, respectively. The Fe particles are embedded in a protective carbon matrix. Both kind of particles are dispersed by spin-coating on SiO2/Si(1 0 0) flat substrates. They are used as catalyst to grow carbon nanotubes by a plasma- and filaments-assisted catalytic CVD process (PE-HF-CCVD). Vertically oriented and thin carbon nanotubes (CNTs) were grown with few differences between the two samples, except the diameter in relation to the initial size of the iron particles, and the density. The electron field emission of these samples exhibit quite interesting behavior with a low turn-on voltage at around 1 V/μm. 相似文献
142.
143.
Small bimetallic Pd-Fe particles supported on a well ordered alumina film grown on NiAl (1 1 0) were studied focusing on the geometric, electronic, adsorption, as well as magnetic properties. The morphology, growth mode and surface composition were investigated by combining scanning tunneling microscopy (STM), temperature-programmed desorption (TPD) and infrared spectroscopy (IRAS) using CO as a probe molecule. Information on the electronic properties of the bimetallic systems was obtained by means of X-ray photoelectron spectroscopy (XPS). These measurements were amended by in situ ferromagnetic resonance spectroscopy to address the magnetic properties of the bimetallic particles. The subsequent deposition of the metals at 300 K varying the order of metal deposition resulted in two distinct bimetallic systems. Pd deposited on existing Fe particles forms a shell, however, FMR and XPS suggest that intermixing of Pd and Fe occurs to some extent. For the reverse order, a larger amount of Fe is required to coat Pd particles, due to the strong tendency of Pd to segregate to the surface of the particles. 相似文献
144.
A program is modeled to describe nitriding depth by a new mixing laser and plasma beams nitriding (LPN) technique. The model extends the transport of ions in matter (TRIM) program by adding temperature and energy factors into the energy function. The nitriding depths and nitrogen distribution in substrate were calculated by Monte Carlo program. There is a good agreement between calculation and experiment results at different laser energy intensities, scanning velocities and nitrogen ion energies respectively. Moreover, the nitriding process diagrams by LPN technique are shown from calculation results. 相似文献
145.
146.
Christophe Dal Zotto Araceli Zarate-Ruiz David Virieux Vincent Terrasson Anne Gaucher 《Journal of organometallic chemistry》2011,696(1):296-304
A direct intermolecular addition of nitrogen and 1,3-dicarbonyl nucleophiles to stabilized double bonds (styrenes, 1,3-dienes, enol-ethers, sugars.) in the presence of green and inexpensive FeCl3 catalyst is described. 相似文献
147.
自行研制了一种凹面光栅整体组合狭缝五通道原子吸收式血液五元素分析仪,用于人全血中5种元素Ca,Cu,Mg,Fe和Zn的测定.采用1支五元素空心阴极灯作为光源,以单反射方式聚焦在火焰中心,以凹面光栅为色散元件.设计了五元素锐线通过的整体组合狭缝.采用顺序注射变速恒流在线稀释的溶液注入方式.为消除干扰谱线对钙的原子吸收的影... 相似文献
148.
Muhammad Akhyar Farrukh Noureen Siraj Iftikhar Imam Naqvi 《Journal of Saudi Chemical Society》2010,14(2):209-212
Iron has been determined in apple and vegetables spectrophotometrically, by complexing it with xylenol orange. 1:1 complex formed in a highly acidic medium is measured for its absorbance at its λmax of 585 nm. The results have been compared by employing atomic absorption technique. Apples and vegetable samples were collected from local markets of Pakistan. Statistical manipulations, t-test and F-test, were performed and it was found that the results from the two techniques have an excellent agreement. 相似文献
149.
Akihiro Furuta 《Tetrahedron letters》2008,49(1):110-113
A combination of a catalyst derived from ferrous acetate and sodium thiophene-2-carboxylate efficiently promoted hydrosilylation of aromatic and aliphatic ketones to give the corresponding secondary alcohols in high yields with extremely high selectivity. 相似文献
150.
John P. Boyd Maria Schlangen Andreas Grohmann Helmut Schwarz 《Helvetica chimica acta》2008,91(8):1430-1434
An unprecedented alkyne–nitrile metathesis takes place when the high‐valent iron‐nitrido dication [Fe(L)N]2+, with L=2,6‐bis(2‐methyl‐1,3‐diaminopropan‐2‐yl)pyridine, is reacted with alkynes in the gas phase under thermal conditions. While the detailed role of the alkyne substrate with respect to relative rates, regioselectivities, and branching ratios remains to be elucidated, the very existence of this novel metathesis reaction provides additional experimental evidence of a genuine, long‐lived, formal iron(V)‐nitrido dication. 相似文献