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121.
《Analytical letters》2012,45(17):1497-1512
Abstract Hexamethylphosphoramide (HMPA) gives, in aqueous solutions in the presence of SCN? ions, complexes with many metal ions, which absorb in the visible region of spectrum. The spectra have been studied in function of ligand concentration and pH for Co, Ni and Fe complexes. For the Co complex an equation was found that describes the behaviour of the absorption vs. SCN? and HMPA concentration. Absorption follows Lambert-Beer law and can be used for analytical determinations. Analysis of solutions containing Ni and Co in various ratios of concentration has been performed and results are discussed. Co, Ni and Fe content of an alloy has been measured by this way. 相似文献
122.
Environmental Fenton chemistry has been poorly constrained within the marine environment at a multi-component level. A simple, unique, reconfiguration of a flow-injection analytical system combined with luminol chemiluminescence allows quasi-simultaneously the measurement, using a single load-inject valve and a single photon multiplier tube, of reduced iron, Fe(II), and hydrogen peroxide. The system enables rapid, every 22 s, measurements with good accuracy at environmentally relevant concentrations, less than 5% relative standard deviations on both a 5 nM Fe(II) standard and a 60 nM hydrogen peroxide standard. Limits of detection were as low as 40 pM Fe(II) and 100 pM hydrogen peroxide. The system showed excellent capability by measuring from within an organic rich seawater the photochemically induced production of Fe(II) and hydrogen peroxide and their subsequent cycling and Fenton like interactions. 相似文献
123.
《Tetrahedron letters》2014,55(52):7190-7193
An iron-catalyzed coupling reaction of methylarenes with thiols leading to thioesters has been developed. The reactions were carried out in water with tert-butyl hydroperoxide (TBHP) as the oxidant and polyoxyethanyl α-tocopheryl sebacate (PTS) as the surfactant. The reaction medium is compatible with a series of functional groups and can be reused. 相似文献
124.
《Tetrahedron》2019,75(43):130624
An Fe(III)-catalyzed efficient method has been developed for the synthesis of selenoester derivatives in high yields through the coupling of α-amino carbonyl/glycine derivatives and diselenides under ambient air. A library of benzoselenoate derivatives having a variety of substituents has been synthesized. A plausible reaction pathway has been predicted. Experimental results suggest that the reaction proceeds through a radical pathway. Operational simplicity, compatibility with various α-amino carbonyls and diselenides, high yields, fast reaction and mild reaction conditions are the notable advantages of this procedure. We have also shown the practical application of the synthesized selenoesters which is useful to generate peptide bonds in biological sciences. 相似文献
125.
126.
The reaction of hydroximoyl chlorides with acetylenes in the presence of a copper on iron bimetallic system leads to β-aminoenones via reductive ring opening of isoxazole intermediates. The valuable β-aminoenone building blocks can be isolated or transformed into pyrazoles with the addition of hydrazine in a straightforward one-pot procedure. 相似文献
127.
《Analytical letters》2012,45(4):314-329
In the last 10 years researchers have adapted a number of instrumental techniques for studying various aspects of historical inks that have been used in historical documents. In this paper, the applications of atomic spectroscopy such as GFAAS, ICP-MS, XRF, PIXE, and XANES are described for identifying and quantifying metals that are found in historical inks. Applications of vibrational spectroscopy, primarily Raman and near/mid-IR spectroscopy, are described for detecting organic and inorganic compounds in ink and paper. 相似文献
128.
S. Ravy P. A. Albouy S. Megtert R. Moret J. P. Pouget R. Comes 《Phase Transitions》2013,86(1-4):193-210
X-Ray diffuse scattering from a series of examples where the reason for the existence of incommensurable features is fairly well understood, is described. They include in particular non stoichiometric compounds such as [DIPS Φ4(l3)0.76] and such as intercalated graphite RbC24. and quasi one dimensional conductors. A particular emphasis is given on various 1 - D conductors and to the relation of the incommensurability to the characteristics of the electron conduction bands. 相似文献
129.
Abstract Broadband UV-irradiation of methylacetate isolated in argon matrices causes rather strong modifications to appear in the IR spectrum. Evidence was obtained for a photochemical interconversion of the stable Z-conformer into the less stable E-conformer followed by photolytic decomposition of the latter into stable products. Most of these products could be identified from their IR absorptions. The reverse E→Z interconversion is a thermal process with an activation energy of about 10 kJmole?1. A normal coordinate analysis based on a transferable valence force field obtained from the literature allowed to assign approximate IR frequencies of E-methylacetate. 相似文献
130.
《Journal of Coordination Chemistry》2012,65(18):3188-3204
Four organic–inorganic crystals, [(HL1)2(ZnCl4)]·H2O (1) (L1?=?2-methylquinoline), [(HL1)2(CuCl4)] (2), [(HL2)2SnCl6] (3) (L2?=?6-bromobenzo[d]thiazol-2-amine), and [(HL3)FeCl4] (4) (L3?=?5,7-dimethyl-1,8-naphthyridine-2-amine), derived from N-containing aromatic Brønsted bases and metal(II) chlorides (zinc(II) chloride, copper(II) chloride dihydrate, tin(II) chloride dihydrate, and iron(III) chloride hexahydrate) were prepared at room temperature and characterized by IR, X-ray structure analysis, elemental analysis, and TG analysis. The crystals are built up by perchlorometallates (Zn, Cu, Sn, and Fe) associated with organic cations through multiple non-covalent associations. X-ray diffraction analysis reveals that 1 and 2 have 3-D network structures built from hydrogen bonds between the cations and chlorometallates. Water molecules play an important role in structure extension in 1. Anhydrous 3 and 4 produced from 2-aminoheterocyclic derivatives display 2-D sheet structures. Arrangements of anions and cations are dominated by shape and size of cations, and also by the different structures of the chlorometallates as well as non-bonding interactions in the crystal structures. Except for 1, the other compounds are thermally stable below 240°C. 相似文献