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81.
Manganese (Mn), iron (Fe), copper (Cu), and zinc (Zn) concentrations were determined in the brain regions of normal 1-, 3-, 5-, 7-, 14-, 21-, 42-, 77-, and 147-day-old Wistar rats using inductively coupled plasma mass spectrometry (ICP-MS), and their maps were illustrated in color to visually compare the distribution of the elements at various stages of the growth process. Sagittal slices (1-mm thickness) sectioned at the level of the substantia nigra were divided into 18 regions, and the small slice samples were digested in microwave-assisted closed vessels for ICP-MS measurement. Mn, Fe, Cu, and Zn concentrations increased region-specifically with age, and their distributional maps showed some characteristics. These findings are discussed in terms of needs for these trace elements in the normal brain. Among new findings about their brain distribution, it is especially noteworthy that higher concentrations of Mn, Fe, and Zn were observed in the substantia nigra compared with those in neighboring regions. The mapping method in this work is expected to open up possibilities for screening of the in vivo element–element interrelationships among these essential elements. 相似文献
82.
83.
甲壳素色谱柱富集—快速吸光光度法测定环境试样中痕量铁 总被引:1,自引:0,他引:1
研究了甲壳素色谱柱富集Fe(Ⅱ)-磺基水杨酸-十八烷基二甲基氨基乙酸的红紫色缔合物,用磺基水杨酸洗脱后,在分光光度计上直接测定洗脱液的吸光度,方法快速,简单、富集倍数高,用于环境水样中痕量铁的测定,结果令人满意。 相似文献
84.
尾式苯丙氨酸卟啉铁(Ⅲ)配合物的合成及性质研究 总被引:1,自引:0,他引:1
尾式苯丙氨酸卟啉铁(Ⅲ)配合物的合成及性质研究*倪春林(湖北三峡师范学院化学系宜昌443000)王静秋秦子斌(武汉大学化学系武汉430072)关键词苯丙氨酸卟啉铁配合物中图分类号O626.329取代四苯基卟啉铁(Ⅲ)由于合成方法简单,催化活性好等优点... 相似文献
85.
Photocatalysis has been extensively studied due to its potential ability to avoid the excessive use of chemical reagents and reduce the energy consumption by employing solar energy. Moreover, to alleviate the reduction in the membrane permeation selectivity, separation efficiency, and membrane service life caused by the emerging micro-pollutants and membrane fouling, membrane technology is often coupled with microbial, electrochemical, and catalytic processes. However, although physical/chemical cleaning and membrane module replacement can overcome the inherent limitations caused by membrane fouling and other membrane separation processes, high operating costs limit their practical applications. In this review, common preparation methods for TiO2 photocatalytic membranes are described in detail, and the main approaches to enhancing their photocatalytic performance are discussed. More importantly, the mechanism of the TiO2 photocatalytic membrane antifouling process is elucidated, and some applications of photocatalytic membranes in other areas are described. This review systematically outlines future research directions in the field of photocatalytic membrane modification, including metal and non-metal doping, fabrication of heterojunction structures, control over reaction conditions, increase in hydrophilicity, and increase in membrane porosity. 相似文献
86.
87.
Summary The electrochemical reduction of the Fe(III) complexes with a series of substituted N,N-Ethylenebisacetonimines was investigated by cyclic voltammetry in acetonitrile solution at a platinum electrode. The substituent does not significantly influence the redox properties of the studied complexes. The symmetry of the redox orbital is responsible for the observed behaviour of the complexes.
Elektrochemisches Verhalten einer Reihe von Fe(III)-Komplexen mit vierzähnigen Schiffschen Basen als Liganden
Zusammenfassung Die elektrochemische Reduktion der Fe(III)-Komplexe einer Reihe von substituierten N,N-Ethylenbisacetoniminen wurde mittels cyclischer Voltammetrie in Acetonitril an einer Platinelektrode untersucht. Der Substituent beeinflußt die Redoxeigenschaften der untersuchten Komplexe nicht signifikant. Das beobachtete Verhalten der Komplexe wird von der Symmetrie des Redoxorbitals bestimmt.相似文献
88.
The equilibrium geometrical structures of small AlmFen clusters have been determined through ab initio calculation of the cluster total energy at the UB3LYP/Lanl2dz level. For dimers of iron and aluminum, the dissociation energies,
the equilibrium atomic distances, and the vibrational frequencies were calculated. The agreement between calculations and
experiments is reasonable. The ground stable geometrical structures of Fe4, FeAl3, Fe3Al and Fe2Al2 clusters favor three-dimension configurations, but Al4 tetramers are planar structures. The Al-rich tetramers are more stable than the other two composition tetramers. This is
different from that of bulk alloys. 相似文献
89.
Ntaoleng M. Makunya Reinout Meijboom Alfred Muller 《Journal of organometallic chemistry》2005,690(18):4159-4167
Cyclopentadienyldicarbonylmethyliron, [CpFe(CO)2Me] (1), undergoes migratory carbonyl insertion under the influence of isosteric phosphine ligands P(4-FC6H4)3 and P(4-MeC6H4)3. The products of the reaction, [CpFe(CO)(COMe)P(4-FC6H4)3] (2a) and [CpFe(CO)(COMe)P(4-MeC6H4)3] (2b), were characterised by X-ray crystallography. In both structures, the iron atom adopts a pseudo octahedral coordination geometry. Fe-P bond distances are the same at 2.1932(8) Å in 2a and 2b, respectively. Thus, contrary to what was expected, X-ray data could not be used to quantitatively differentiate between the two phosphine ligands in 2a and 2b. Therefore, additional spectroscopic techniques such as IR and NMR were employed. Similarly, the Fe-C bond lengths of the carbonyl (Fe-CO) and acetyl (Fe-COMe) are 1.748(3) and 1.955(3) in 2a, and 1.744(3) and 1.951(3) Å in 2b, respectively.The migratory carbonyl insertion was studied by NMR, IR, and UV-vis spectroscopies to determine the mechanism and the rate law. Results from NMR spectroscopy show that the formation of the product is accompanied by oxidation of the corresponding phosphine ligand. An increase in the reactivity of migratory carbonyl insertion for P(4-MeC6H4)3 was observed when the solvent was changed from CH2Cl2 to MeCN. The kinetic data showed that P(4-MeC6H4)3 reacts faster than P(4-FC6H4)3. 相似文献
90.
Identification of selenium species in urine by ion-pairing HPLC–ICP–MS using laboratory-synthesized standards 总被引:1,自引:0,他引:1
Wrobel K Wrobel K Kannamkumarath SS Caruso JA 《Analytical and bioanalytical chemistry》2003,377(4):670-674
This study focused on the detection/identification of possible selenium metabolites in human urine. Organoselenium compounds not commercially unavailable were synthesized and characterized by electrospray mass spectrometry. Separation of selenomethionine, methylselenomethionine, trimethylselonium, selenoethionine, and selenoadenosylmethionine was achieved by ion-pairing HPLC with a mobile phase of 2 mmol L–1 hexanesulfonic acid, 0.4% acetic acid, 0.2% triethanolamine (pH 2.5), and 5% methanol. The column effluent was introduced on-line to inductively coupled plasma–mass spectrometry for selenium-specific detection (77Se and 78Se). For selenium speciation in urine, solid-phase extraction was carried out using C18 cartridges modified with hexanesulfonic acid. Selective retention of cationic species was observed from acidified urine (perchloric acid, pH 2.0). After elution with methanol, evaporation, and dissolution in the mobile phase, the sample was introduced to the HPLC–ICP–MS system and the chromatographic peaks were assigned by adding standards. The species identified in urine were selenomethionine, trimethylselonium ion, and selenoadenosylmethionine. The last species was detected for the first time and our results suggest that selenomethionine might enter the metabolic pathway of its sulfur analog in the activated methylation cycle.Kazimierz Wrobel and Katarzyna Wrobel are on the leave from the Institute of Scientific Research, University of Guanajuato, L. de Retana No. 5, 36000 Guanajuato, Gto., Mexico 相似文献