全文获取类型
收费全文 | 2439篇 |
免费 | 37篇 |
国内免费 | 175篇 |
专业分类
化学 | 2003篇 |
晶体学 | 15篇 |
力学 | 24篇 |
综合类 | 2篇 |
数学 | 4篇 |
物理学 | 603篇 |
出版年
2024年 | 2篇 |
2023年 | 59篇 |
2022年 | 25篇 |
2021年 | 33篇 |
2020年 | 35篇 |
2019年 | 56篇 |
2018年 | 42篇 |
2017年 | 42篇 |
2016年 | 35篇 |
2015年 | 43篇 |
2014年 | 64篇 |
2013年 | 101篇 |
2012年 | 172篇 |
2011年 | 138篇 |
2010年 | 113篇 |
2009年 | 158篇 |
2008年 | 149篇 |
2007年 | 187篇 |
2006年 | 151篇 |
2005年 | 127篇 |
2004年 | 115篇 |
2003年 | 96篇 |
2002年 | 61篇 |
2001年 | 71篇 |
2000年 | 82篇 |
1999年 | 80篇 |
1998年 | 68篇 |
1997年 | 57篇 |
1996年 | 52篇 |
1995年 | 45篇 |
1994年 | 32篇 |
1993年 | 33篇 |
1992年 | 28篇 |
1991年 | 31篇 |
1990年 | 22篇 |
1989年 | 17篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1973年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有2651条查询结果,搜索用时 31 毫秒
51.
本文用热处理法成功地制备了性能稳定的Eastman-Kodak AQ/GC修饰电极,对Fe~(3+)/Fe~(2+)及其络合阳离子在该电极上的行为进行了研究。表明AQ膜对Fe~(3+)和Fe~(2+)具有相近的交换能力,可用于Fe~(3+)或Fe~(2+)及其总量的阴极溶出伏安法测定。线性范围分别为2.0×10~(-7)~2.2×10~(-5)mol/L(Fe~(3+))和5.0×10~(-7)~2.0×10~(-5)mol/L(Fe~(2+)),检出限为1.0×10~(-7)mol/L(Fe~(3+))。文中对电极反应和再生进行了探讨。 相似文献
52.
一阶导数停流法测定药物和饮用水中的铁 总被引:3,自引:0,他引:3
本文利用Fe^3+离子催化H2O2氧化四甲基对苯二胺的反应,将采用停流技术获得的动力学曲线转换成一阶导数曲线,根据导数峰高值与Fe^3+离子浓度的线性关系测定药物和自来水中的含量,本方法的线性范围为4.0-40.0ngFe^3+/ml,相对标准偏差小于2.5%,标准加入回收率在98.7%-101%之间,检测限为1.92ngFe^3+/ml。对照实验结果表明,导数动力学法比一般非导数动力学法具有线关 相似文献
53.
Chemical species obtained by reaction of 5-amino-1, 10-phenanthroline with ethanedial (glyoxal) are reported with regard to their preparation, chemical composition and spectrometric characterization (UV-visible, infrared and liquid secondary ion mass spectrometry). Products of the reaction are postulated to be a mixture of species with molecular weights of 339, 371,480 and 524 u. Chemical reactions leading to these products and possible structural formulas for each of these species are presented. The iron complexes of these ligands, because of their extremely low solubility in most solvents, find application as redox mediators when incorporated in carbon paste electrodes, particularly for sensing in continuous-flow systems. 相似文献
54.
A simple and versatile protocol, based on use of solid phase extraction on strong ion exchangers and off-line detection by flame atomic absorption spectrometry, was devised to fractionate iron and zinc in common dietary food and beverages products, i.e., bee honeys, fruit juices and tea infusions. In the procedure proposed, cation exchanger Dowex 50Wx4 and anion exchanger Dowex 1x4 were used separately for distinguishing broadly meant the cationic metal fraction and the fraction of stable anionic metal complexes, respectively, after retention of metal species and their exhaustive elution by means of a 4.0 mol l−1 HCl solution. The third fraction, referred to the residual metal species, was retrieved by difference between total soluble metal contents and sum of metal quantities in separated cationic and anionic fractions. The fractionation pattern observed for both metals was described and discussed. 相似文献
55.
Ester van den Beuken Sylvie Samson Elizabeth J. Sandoe G. Richard Stephenson 《Journal of organometallic chemistry》1997,530(1-2):251-253
The first example of an alkyne-substituted tricarbonyl(η5-cyclohexadienyl)iron(1+) complex has been prepared and the ω directing effect of the phenylethynyl substituent has been demonstrated in nucleophile addition reactions. Addition of NC− also occurs at the a position to form an unusual η1, η3-structure. 相似文献
56.
微波溶样肉桂基荧光酮和表面活性剂连续荧光测定葡萄酒中铁和钴 总被引:2,自引:0,他引:2
观察到肉桂基荧光酮(略作CF)在pH≈8与Fc(Ⅲ)配位后荧光增强,CPB的加入使荧光更强,络合物与试剂荧光强度之比F_(FeR)/F_R随0~0.01μg/ml Fe(Ⅲ)线性变化,λ_(ex)=410nm,λ_(ex)=480nm;而CF在pH≈10与Co(Ⅲ)配位后荧光却减弱,乳化剂OP存在时使试剂荧光增强,若以荧光熄灭Co(Ⅲ)灵敏度便提高,试剂与络合物荧光强度之比F_R/F_(CoR)对0~0.016 μg/ml Co(Ⅲ)呈直线关系,λ_(ex)=300nm,L_(em)=352nm。控制化学条件和激发、发射波长,可不经分离测定葡萄酒(微波溶样)中铁和钴。 相似文献
57.
In this paper the formation mechanism of iron macro-spheres in
a plasma medium is dealt with, including the conditions under which such
spheres are formed. The geometry of the spheres referred to above
depends on the main technological parameters involved in the production
of pores. Conditions under which pores occur within macro-spheres are
also established. The radii of these pores are sensitive to the velocity
distribution within the plasma jet section 相似文献
58.
Syntheses, Structure Determination and Reactions of Phosphine Substituted Derivatives of Fe3(CO)9(μ3-CF)2 Photolysis of Fe3(CO)9(μ3-CF)2 1 in the presence of acetonitrile 2a or benzoenitrile 2b results in the substitution of a single carbonyl ligand by a nitrile ligand yielding Fe3(CO)8(CH3CN)(μ3-CF)2 3a and Fe3(CO)8(C6H5CN)(μ3-CF)2 3b, respectively. The acetonitrile ligand in 3a can be easily replaced by trimethyl-phosphine 4a or triphenylphosphine 4b . The monosubstituted compounds Fe3(CO)8(PR3)(μ3-CF)25, R = CH3 a, R = C6H5, b are obtained as major products besides a small amount of the disubsituted products Fe3(CO)7(PR3)2(μ3-CF)2 6. The structure of 5a has been elucidated by a single crystal X-ray structure determination. Thermal ligand substitution in 1, however, results in the formation of a mixture of mono-, disubstituted, and trisubstituted products, in which 6b is the major product for diphenylphosphine. 5a reacts with ethyne 7 forming a phosphine substituted diferra-allyl-cluster Fe3(CO)7(PR3)(μ3-CF)(μ3? CF? CH? CH) 8. The structure of one isomere of 8 has been determinated by X-ray crystallography. 相似文献
59.
根据Fe(Ⅲ)、Mo(Ⅵ)对H2O2氧化邻氨基酚的催化反应速率不同,结合流动注射停留技术,建立了同时测定Fe(Ⅲ)、Mo(Ⅵ)的速差动力学分光光度法.测定铁和钼的线性范围分别为0.1~2.5μg/mL和0.5~15μg/mL.除W(Ⅵ)的允许量较小外,其它离子不干扰测定.用本法测定了合成样液中铁和钼含量,结果满意. 相似文献
60.
一阶导数吸光光度法同时测定纯硅中铁和铝的研究 总被引:4,自引:0,他引:4
提出了用一阶导数光光度法同时测定铁和铝的方法,在pH6.5乙二胺缓冲溶液中,乳化剂OP存在下,Fe^3+Al^3+与络天青S形成Fe^3+,Al^3+-CAS-OP三元络合物,络合物一阶导数光谱等吸收点分别在606.2,638.0nm记录混合体系在两波长处一阶导数数值可以分别测定铝,铁含量,互不影响,铁,铝含量分别在1.0~16μg/25ml,0.3~10μg/25ml范围内呈良好线性,用于测定纯 相似文献