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101.
使用X射线荧光光谱仪,采用人工合成标样,设计合成了一套标准样品,采用数学校正法中的经验系数法校正元素间的互相干扰,样品不经任何处理,粉末直接压片,经验系数法校正基体效应,建立了分析测定增产丙烯助剂中磷和铁含量的方法。讨论了样品制作方法,合适的测量条件,探讨了试样中元素间的相互影响。实验结果表明,该方法重现性好,准确度和精密度较高,测定磷和铁的相对标准偏差为:0.34%和0.59%;测定范围磷为0.01%~2.5%,铁为0.01%~2.5%。分析结果与化学法、等离子发射光谱法测定结果吻合。该方法快速、简便,样品处理简单,可以不分解;分析速度远快于其他分析方法,结果准确,单次测量一个样品只需要5 min,适用范围广,满足了科研和工业生产的需要。 相似文献
102.
空气中痕量铀的现场光度法测定 总被引:1,自引:0,他引:1
作为一种天然放射性金属元素,铀及其化合物可以地气为分散系,以气溶胶形式稳定存在并随空气迁移。气相中铀可经多种途径对人体造成放射性危害,而其浓度变化与该区域核能开发与利用有关。因此,对空气中铀的快速现场检测具有现实意义。采用普通气泵对低品位铀矿石上方的空气进行采样,并以2.0 mol·L-1硝酸溶液对气体进行吸收,向溶液中添加固体试剂包,对溶液中微量铀进行显色后以手持式光度计进行现场光度分析。结果表明:对于普通低品位铀矿石样品,空气中铀含量可用本方法检出,该方法多次测定的RSD为1.72%,其结果与ICP-MS分析结果一致。将该方法用于区分铀矿石和其他矿石,具有成本低廉,操作方便,结果准确可靠等优点。 相似文献
103.
The rare isotope 236U has a half-life of 2.342(3)×107 years,and is produced principally by thermal neutron capture on 235U.The isotopic atom ratio of 236U/238U depends on the integral thermal neutron flux received by the material of interest.236U is potentially useful as a fingerprint for indicating the presence of neutron-irradiated uranium usually originating from nuclear activity.By extracting negative molecular ion UO- from the uranium oxide target,simulating the 236U16O- beam transport with 238U16O- an... 相似文献
104.
105.
Yong Woon Parc Duk-Su Koh Wokyung Sung 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,69(1):127-131
Stochastic resonance (SR) is a novel cooperative phenomenon occurring in
nonlinear systems due to coupling of an ambient noise and an external
signal. Biological systems may use SR mechanism to detect the signal
efficiently from an external environment. A number of studies have addressed
the SR in artificial ion channels considering external voltages as noises.
More important than these external noises is the internal, thermal noise
which changes the channel conformations essential for biological functions.
In this work, we consider that the channel gating rates follow a
non-Arrhenius temperature dependence derived from experimental data of a
real biological channel. Using the Monte-Carlo simulations, we find that in
this channel SR occurs near a physiological temperature in a very
distinctive manner compared with that for the Arrhenius gating model. 相似文献
106.
利用20 keV的He离子注入表面蒸镀了Au薄膜的尖晶石(MgAl2O4)样品, 随后对注入样品进行了退火处理。 在紫外可见光谱上观察到了由于金属纳米颗粒的存在而引起的较强的表面等离子体共振吸收峰, 提供了材料中金属纳米颗粒形成的光谱证据。 并对形成的Au纳米颗粒的尺寸随退火温度以及He注入剂量的变化进行了研究。 Spinel deposited with a thin Au film was implanted with helium ions, and annealed in vacuum condition subsequently. The surface Plasmon resonance absorbance peak due to the existence of metallic nanoparticles in the dielectric matrix was observed on the Ultraviolet Visible Spectrometry, indicating the formation of metallic nanoparticles in spinel. The dependence of Au particles size with annealing temperature and implantation doses was also investigated. 相似文献
107.
108.
P. Schroll A.P. Wandel R.S. Cant E. Mastorakos 《Proceedings of the Combustion Institute》2009,32(2):2275-2282
Three-dimensional direct numerical simulations (DNS) were carried out to investigate the impact of evaporation of droplets on the autoignition process under decaying turbulence. The droplets were taken as point sources and were tracked in a Lagrangian manner. Three cases with the same initial equivalence ratio but different initial droplet size were simulated and the focus was to examine the influence of the droplet evaporation process on the location of autoignition. It was found that an increase in the initial droplet size results in an increase in the autoignition time, that highest reaction rates always occur at a specific mixture fraction ξMR, as in purely gaseous flows, and that changes in the initial droplet size did not affect the value of ξMR. The conditional correlation coefficient between scalar dissipation rate and reaction rates was only mildly negative, contrary to the strongly negative values for purely gaseous autoigniting flows, possibly due to the continuous generation of mixture fraction by the droplet evaporation process that randomizes both the mixture fraction and the scalar dissipation fields. 相似文献
109.
The present study was conducted to investigate the molecular absorption by AlCl in a carbon rod furnace for determination of chlorine in organic compounds, by using the lead atomic line at 261.418 nm emitted from a Pb-hollow cathode lamp. A deuterium lamp was used for the simultaneous background correction. The method enables rapid and accurate determination of trace chlorine in varying organic samples with good precision. The method was tested on different organic chloro-coumpounds and α-pinene products. 相似文献
110.
Abstract: Periodic publications have been published that address advances in evolved gas analysis techniques, because the correct interpretation for the mechanism of a thermally induced reaction, involving the formation of gaseous species, is strongly dependent on the characterization of the evolved products.When the nature of volatile products released by a substance subjected to a controlled-temperature program are online determined, the results allow one to prove a supposed reaction, either under isothermal or under heating conditions.Very recent analytical applications of evolved gas analysis performed by mass spectrometry, selected among those published in 2012 and 2013, are collected in this review. 相似文献