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21.
G. Lligadas J. C. Ronda M. Gali V. Cdiz 《Journal of polymer science. Part A, Polymer chemistry》2006,44(19):5630-5644
A new phosphorous‐containing fatty acid diepoxide was obtained from 10‐undecenoyl chloride and 10‐(2′,5′‐dihydroxyphenyl)‐9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide and crosslinked with 4,4′‐diaminodiphenylmethane and bis(m‐aminophenyl)methylphosphine oxide. The properties of the thermosetting materials were evaluated by differential scanning calorimetry, dynamic mechanical thermal analysis, thermogravimetric analysis, and limiting oxygen index (LOI). Thermal and thermooxidative degradation was studied by gas chromatography/mass spectrometry, FTIR, 31P magic angle spinning NMR spectroscopy, and scanning electron microscopy. LOI values indicate good flame‐retardant properties that are related to the formation of a protective phosphorous‐rich layer that slowed down the degradation and prevented it from being total. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5630–5644, 2006 相似文献
22.
脉冲离散效应对光纤中基于交叉相位调制的脉冲压缩的影响 总被引:4,自引:1,他引:3
通过数值模拟,分析了脉冲离散效应对单模光纤正群速色区基于暗孤子交叉不相位调制的脉冲压缩的影响,并提出了减轻这种影响的办法,作者发现,即使暗孤子与被压缩脉冲的中心波长相差很小,离散效应对脉冲压缩的影响也很大,离散效应不仅导致脉冲压缩比的减小和压缩后脉冲峰值功率的降低,而且还导致脉冲压缩所需最佳光纤长度的增加以及压缩后的脉冲呈现不对称性,还发现,若采取本文提出了的非同步耦合法,则可以明显地弥补离散效应 相似文献
23.
激光感生碰撞能量转移的四能级理论模型 总被引:6,自引:2,他引:4
首次考虑了两个中间态对激光感生碰撞能量转移的影响,发展了激光感生碰撞能量转移的四能级理论模型,推导出态振幅的运动方程,并给出碰撞截面的近似表达式,通过对Eu-Sr和Cs-Sr系统的数值计算表明,当频率差│ω21│大小和│ω43│可以相比时,利用三能级近似理论就难以获得令人满意的计算结果,而四能级理论模型则适合于任何情况下的激光感生碰能量转移。 相似文献
24.
Let (
t
)
t0 be a -semistable convolution semigroup of probability measures on a Lie groupG whose idempotent
0 is the Haar measure on some compact subgroupK. Then all the measures
1
are supported by theK-contraction groupC
K() of the topological automorphism ofG. We prove here the structure theoremC
K()=C()K, whereC() is the contraction group of . Then it turns out that it is sufficient to study semistable convolution semigroups on simply connected nilpotent Lie groups that have Lie algebras with a positive graduation. 相似文献
25.
26.
A three-dimensional pharmacophore model was developed from a series of inhibitors of Aurora A kinase to discover new potent anti-cancer agents using the HypoGen module in the Catalyst software. The pharmacophore model was developed based on the structure of 20 currently available inhibitors, which were carefully selected from the literature. The best hypothesis (Hypo 1) was defined by four features: one hydrogen-bond donor and three hy- drophobic points, with the best correlation coefficient of 0.909, the lowest rms deviation of 1.563, and the highest cost difference of 99.075. The Hypo 1 was then validated by a test set consisting of 24 compounds and by a cross-validation of 95% confidence level through randomizing the data using the CatScramble program, which suggested that a predictive pharmacophore model had been successfully obtained. 相似文献
27.
New spin-state-selective (S3) NMR pulse sequences exclusively applying cross-polarization schemes to achieve optimum homonuclear and heteronuclear 1H-X coherence transfer are reported for the simple and accurate measurement of the magnitude and sign of heteronuclear coupling constants for samples at natural abundance. The proposed spin-edited HCP-TOCSY experiments are based on clean heteronuclear S3 excitation, generated by simultaneous co-addition of two independent in-phase and anti-phase components created during the mixing heteronuclear J-cross-polarization (HCP) step, which is finally transferred to other protons by a conventional homonuclear TOCSY mechanism. Selective 1D and non-selective 2D approaches for the easy determination of long-range proton-carbon and proton-nitrogen coupling constants on any protonated and non-protonated heteronuclei are presented and discussed for several organic molecules. 相似文献
28.
用准经典轨线方法研究了处于振动激发态的硅原子团簇与硅原子团簇碰撞的反应动力学,计算表明,对于Si4+Si3反应,当反应物团簇处于振动激发态时,有利于生成更小团簇的碎片,而对生成Si6+Si及Si5+Si2的影响不大。 相似文献
29.
A systematic quantum chemical characterization of intrinsic structure, energies and spectral properties of all the studied cross-link adducts formed by the novel trans platinum with thiazole ligand has been carried out at B3LYP/6-31G^* level of theory with the Lanl2dz pseudo potential basis set for the Pt atom. Special attention has been paid to the relative stability of these complexes and the factors that probably alter the order of the relative stability. The important influence of hydrogen bond on the structures, the energies and the spectral property was revealed. Other factors that contribute to relative stability including solvation effect, entropy and electronic delocalization energy were taken into account. The stability energy of the whole complex, and the interaction energy between two purine bases and the [Pt-(NH3)thiazole]^2+ group were adopted to study the interplay among subsystems and their contribution to relative stability of all the studied cross-link model. Finally, basic spectral properties of these complexes including H(8) chemical shifts of all the studied complexes and the VCD (vibrational circular dichroism) spectra of two pairs of GG chelate enantiomers, were provided in order to define the structure of the most possible duplex bearing novel trans platinum drug lesions. 相似文献
30.