全文获取类型
收费全文 | 91783篇 |
免费 | 7164篇 |
国内免费 | 11402篇 |
专业分类
化学 | 52879篇 |
晶体学 | 426篇 |
力学 | 6691篇 |
综合类 | 1334篇 |
数学 | 25436篇 |
物理学 | 23583篇 |
出版年
2024年 | 152篇 |
2023年 | 956篇 |
2022年 | 1862篇 |
2021年 | 2125篇 |
2020年 | 2583篇 |
2019年 | 2649篇 |
2018年 | 2335篇 |
2017年 | 2481篇 |
2016年 | 2820篇 |
2015年 | 2591篇 |
2014年 | 3796篇 |
2013年 | 6666篇 |
2012年 | 3969篇 |
2011年 | 4606篇 |
2010年 | 3791篇 |
2009年 | 4999篇 |
2008年 | 5519篇 |
2007年 | 5841篇 |
2006年 | 5473篇 |
2005年 | 4747篇 |
2004年 | 4465篇 |
2003年 | 4216篇 |
2002年 | 3534篇 |
2001年 | 2978篇 |
2000年 | 2952篇 |
1999年 | 2606篇 |
1998年 | 2433篇 |
1997年 | 2031篇 |
1996年 | 1811篇 |
1995年 | 1646篇 |
1994年 | 1507篇 |
1993年 | 1266篇 |
1992年 | 1234篇 |
1991年 | 946篇 |
1990年 | 781篇 |
1989年 | 687篇 |
1988年 | 608篇 |
1987年 | 472篇 |
1986年 | 407篇 |
1985年 | 479篇 |
1984年 | 472篇 |
1983年 | 233篇 |
1982年 | 373篇 |
1981年 | 430篇 |
1980年 | 326篇 |
1979年 | 310篇 |
1978年 | 246篇 |
1977年 | 232篇 |
1976年 | 189篇 |
1974年 | 147篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
911.
对经典一维受迫谐振子量子化,求解量子化后体系的时间演化算符.应用相空间准概率分布函数,研究了体系的量子特性.研究结果表明,初始为真空态,经过时间演化,系统波函数是一个二维高斯波包;波包中心的振幅和相位受到作用力的调制,成为调幅、调相波,波包中心的运动与经典受迫谐振子的运动形式相同. 相似文献
912.
Hongyan Liu Riguang ZhangFangyuan Ding Ruixia YanBaojun Wang Kechang Xie 《Applied Surface Science》2011,257(22):9455-9460
A density-functional theory method has been conducted to investigate the association of C + O on (1 1 1) facets of ordered NiCo alloy and the results have been compared with those obtained on pure Ni(1 1 1) surface. In reaction of C + O, the favorable reaction path is that C adsorbed on HCP-1 site moves to the nearest Ni-Co bridge site, and associates with O migrating from FCC-1 site to result in CO adsorbed on the bridge site of Ni-Co. However, the reaction barrier is higher by 0.35 eV than that on pure Ni(1 1 1), which indicates that the incorporation of Co into the Ni crystal is not in favor of the reaction of carbon delimination. 相似文献
913.
Freudenthal duality, introduced in Borsten et al. (2009) [1] and defined as an anti-involution on the dyonic charge vector in d=4 space-time dimensions for those dualities admitting a quartic invariant, is proved to be a symmetry not only of the classical Bekenstein-Hawking entropy but also of the critical points of the black hole potential.Furthermore, Freudenthal duality is extended to any generalized special geometry, thus encompassing all N>2 supergravities, as well as N=2 generic special geometry, not necessarily having a coset space structure. 相似文献
914.
Jinying XuXiangdong Zhang 《Physics letters. A》2011,375(13):1524-1527
We present a rigorous multiple-scattering method to calculate the interaction energies due to electromagnetic field fluctuations in a cluster of parallel cylinders. Various kinds of cluster structure with both isotropic and anisotropic materials are considered. It is shown that Casimir interactions are sensitive to the positions of the cylinders in the cluster or the structure of the system. The sign of the interaction energy cannot only be changed by tuning the parameters of anisotropic materials, it can also be caused by changing the cylinders configuration of the system. 相似文献
915.
Trivalent dysprosium ions (Dy3+) doped strontium molybdate (SrMoO4) phosphors were synthesized by solid-state reaction and their photoluminescence (PL) properties were investigated. X-ray powder diffraction (XRD) analysis confirmed the formation of SrMoO4:Dy3+. PL measurements indicated that the phosphor exhibited intense emission at 482, 490 (4F9/2→6H15/2) and 575 nm (4F9/2→6H13/2) under UV excitation. The effect of the doping concentration of Dy3+in SrMoO4:Dy3+ on the PL was investigated in detail. Na+ ion was a good charge compensator for SrMoO4:Dy3+. 相似文献
916.
The synthesis and optical properties of a novel family of 5-substituted-1,10-phenanthroline derivatives are reported herein. One carbon-carbon triple-bond function was introduced using a Sonogashira cross-coupling reaction. The effects on optical properties, of the substitution with electro-withdrawing or -donating substituents in the 5th position of the 1,10-phenanthroline are investigated. Experimental chemical structure-polarisability relationship is analyzed according to the Lippert-Mataga correlation and compared to a theoretical study carried out with DFT calculations. These compounds are promising candidates for a fine-tuning of the internal charge-transfers but also as potential nonlinear chromophores and ligands within multifunctional coordination complexes. 相似文献
917.
In this study we introduced dialdehyde groups to a commercial regenerated cellulose (RC) ultrafiltration membrane by periodate oxidation. They were further converted to nitrogen-containing derivatives by Schiff base reaction with diethylenetriamine (DETA). The modified membrane was challenged with aqueous solution containing Pb(II) metal ions. The different variables affecting the rejection of lead ion by membrane including oxidization time, concentration of DETA, initial metal ion concentration and pH of the solution were elucidated. The membranes were characterized by FTIR-ATR, SEM, EDAX and elemental analyses. The process efficiency was enhanced by improving the oxidization time up to a certain period. In our case this was diminished after 9 h due to deterioration in the membrane integrity. The Pb2+ removal was facilitated by increasing feed pH and DETA concentration. This was diminished for more concentrated metal ion in the feed. Membrane regeneration was successfully utilized using 0.1 M HNO3 solution. The removal capability of the regenerated membranes was maintained even after four cycles. 相似文献
918.
919.
从实验与理论两方面研究NaOH在水凝胶体模中的二维扩散特性.引入化学反应项,建立了刻画NaOH在蛋白质中渗透的反应扩散方程,继而对OH-在凝胶中的时空分布及不同注射浓度、不同反应速率常数下OH-的浓度分布进行了定量研究.实验利用加入酚酞指示剂的水凝胶对NaOH的扩散范围进行了刻画,与计算结果较为一致.该方法为预测NaO... 相似文献
920.