全文获取类型
收费全文 | 40706篇 |
免费 | 2411篇 |
国内免费 | 2023篇 |
专业分类
化学 | 22668篇 |
晶体学 | 239篇 |
力学 | 4122篇 |
综合类 | 535篇 |
数学 | 8169篇 |
物理学 | 9407篇 |
出版年
2024年 | 77篇 |
2023年 | 434篇 |
2022年 | 1077篇 |
2021年 | 1084篇 |
2020年 | 1042篇 |
2019年 | 992篇 |
2018年 | 887篇 |
2017年 | 1123篇 |
2016年 | 1513篇 |
2015年 | 1166篇 |
2014年 | 1630篇 |
2013年 | 2823篇 |
2012年 | 2308篇 |
2011年 | 2114篇 |
2010年 | 1812篇 |
2009年 | 2317篇 |
2008年 | 2276篇 |
2007年 | 2583篇 |
2006年 | 2151篇 |
2005年 | 1923篇 |
2004年 | 1858篇 |
2003年 | 1562篇 |
2002年 | 1203篇 |
2001年 | 989篇 |
2000年 | 958篇 |
1999年 | 862篇 |
1998年 | 815篇 |
1997年 | 716篇 |
1996年 | 657篇 |
1995年 | 633篇 |
1994年 | 562篇 |
1993年 | 463篇 |
1992年 | 427篇 |
1991年 | 367篇 |
1990年 | 329篇 |
1989年 | 219篇 |
1988年 | 221篇 |
1987年 | 140篇 |
1986年 | 118篇 |
1985年 | 143篇 |
1984年 | 115篇 |
1983年 | 58篇 |
1982年 | 96篇 |
1981年 | 55篇 |
1980年 | 45篇 |
1979年 | 75篇 |
1978年 | 34篇 |
1977年 | 14篇 |
1976年 | 23篇 |
1974年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
121.
Orotic acid (vitamin B13) is a key intermediate in biosynthesis of the pyrimidine nucleotides in living organisms, moreover, it may serve as the biological carrier for some metal ions. cis-Diammine(orotato)platinum(II), cis-[Pt(C5H2N2O4)(NH3)2] can be considered as a new potential cisplatin analogue. The FT-Raman and FT-IR spectra of the title complex are reported, for the first time. The molecular structure, vibrational frequencies, and the theoretical infrared and Raman intensities have been calculated by the density functional mPW1PW91 method. The detailed vibrational assignment has been made on the basis of the calculated potential energy distribution. The theoretically predicted IR and Raman spectra show very good agreement with experiment. Natural bond orbital (NBO) analyses were performed for cisplatin, carboplatin and the title complex. The results provided new data on the nature of platinum–ligand bonding in these compounds. Strong intramolecular hydrogen bond between the orotate ligand and the coordinated ammonia group stabilizes the structure of the platinum(II) complex. Thus, it is suggested that the orotate ligand in the title complex is more inert to the substitution reactions than the chloride ligands in cisplatin. 相似文献
122.
H. Sakuma T. Taniyama K. Ishii Y. Kitamoto Y. Yamazaki 《Journal of magnetism and magnetic materials》2006,300(2):284-292
The order parameter S of Fe–Pt nanoparticles is estimated from X-ray diffraction (XRD) patterns. The total intensity of a diffraction peak is obtained by Rietveld analysis as well as simply integrating the intensity. The Rietveld analysis is found to provide a plausible value of S even for a sample showing an XRD pattern with broad and overlapped peaks. Another order parameter Q, which is obtained from Mössbauer spectra, is introduced, and it is confirmed that Q is equivalent to the probability of Fe atoms being in the L10-type atomic arrangement. The coercivity of Fe–Pt nanoparticles is directly proportional to Q, while it vanishes at S=0.4, indicating that the magnetic property of Fe–Pt nanoparticles has a closer relationship to Q than S. 相似文献
123.
Scaling analysis of the magnitude series (volatile series) has been proposed recently to identify possible non-linear/multifractal signatures in the given data [Y. Ashkenazy, et al. Phys. Rev. Lett. 86 (2001) 1900; Y. Ashkenazy, et al. Physica A 323 (2003) 19; T. Kalisky, Y. Ashkenazy, S. Havlin. Phys. Rev. E 72 (2005) 011913]. In this article, correlations of volatile series generated from stationary first-order linear feedback process with Gaussian and non-Gaussian innovations are investigated. While volatile correlations corresponding to Gaussian innovations exhibited uncorrelated behavior across all time scales, those of non-Gaussian innovations showed significant deviation from uncorrelated behavior even at large time scales. The results presented raise the intriguing question whether non-Gaussian innovations can be sufficient to realize long-range volatile correlations. 相似文献
124.
In this note we study constant mean curvature surfaces in asymptotically flat 3-manifolds. We prove that, outside a given compact subset in an asymptotically flat 3-manifold with positive mass, stable spheres of given constant mean curvature are unique. Therefore we are able to conclude that the foliation of stable spheres of constant mean curvature in an asymptotically flat 3-manifold with positive mass outside a given compact subset is unique.
125.
126.
本文研究了一维模型分子离子(初态为基态和一个激发束缚态叠加的相干态)在超强超短激光脉冲作用下的谐波发射谱.我们发现在高次谐波谱平台区域出现了周期性的结构变化.我们利用小波变换对谐波谱进行了暂态时间频率分析,结果表明该谐波结构产生的原因是由电离电子返回母离子时与不同束缚态复合而产生的谐波光脉冲之间相干叠加.同时采用半经典计算,对所得到的计算结果进行了分析,验证了我们的结论. 相似文献
127.
Dimensional analysis is presented as a powerful tool in the study of the paste boriding process. In particular, a dimensional method is used to study the growth kinetics of the boride layers FeB and Fe2B. Experiments were performed in AISI 1045 steel and AISI M2 steel, to test the suggested model. Samples of 1045 steel were prepared and treated using boron paste thickness of 3-5 mm, at temperatures of 1193, 1223 and 1273 K, with 2, 4 and 6 h of treatment time. The M2 specimens had boron paste thickness of 3 and 4 mm and temperatures of 1223, 1253 and 1273 K for 2 and 6 h. Results indicate that the growth of boron layers obeys power laws of the form y = αxβ, where α and β constants are a function of the material and the interface of interest. Validation of the model was carried out using experimental data with an average error percentage of 7.6% for Fe2B in 1045 steel, 15.8% for FeB and 3.4% for Fe2B in M2 steel. 相似文献
128.
Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses 下载免费PDF全文
Er3+-doped tellurite glasses with molar compositions of
xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2--
60TeO2--0.3Er2O3
(x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm
fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability
and optical properties of Er3+-doped tellurite glasses have been discussed.
It is noted that the incorporation of Nb2O5 (x=5) increases the thermal
stability of tellurite glasses significantly. Er3+-doped niobium tellurite
glasses exhibit a large stimulated emission cross-section (7.2\times 10-21-
10.7×10-21~cm2 and the gain bandwidth, FWHM×\sigmae^{\rm peak} (274\times 10-28 - 480×10-28~cm3), which are
significantly higher than that of silicate and phosphate glasses. In addition, the
intensity of upconversion luminescence of the Er3+-doped niobium tellurite
glasses decreases rapidly with increasing Nb2O5 content. As a result,
Er3+-doped niobium tellurite glasses might be a potential candidate for
developing laser or optical amplifier devices. 相似文献
129.
130.
This paper examines the performance of Commodity Trading Advisors (CTAs) using fixed and variable benchmarking models. In
order to avoid the troublesome passive and active commodity and managed futures benchmarks (indices) when examining the performance
of CTAs, we innovate by using data envelopment analysis (DEA). Because this alternative class has non-linear returns due to
long/short positions, and derivatives (i.e., dynamic trading strategies), DEA can alleviate the problems usually associated
with these indices. The effectiveness of using benchmarking models in a DEA setting will provide investors with an alternative
technique in assessing the performance and identifying efficient CTAs. 相似文献