The effect of alkanolamide loading on properties of carbon black-filled natural rubber (SMR-L), epoxidised natural rubber (ENR), and styrene-butadiene rubber (SBR) compounds

The effect of Alkanolamide (ALK) loading on properties on three different types of carbon black (CB)-filled rubbers (SMR-L, ENR-25, and SBR) was investigated. The ALK loadings were 1.0, 3.0, 5.0 and 7.0 phr. It was found that ALK gave cure enhancement, better filler dispersion and greater rubber–filler interaction. ALK also enhanced modulus, hardness, resilience and tensile strength, especially up to 5.0 phr of loading in SMR-L and SBR compounds, and at 1.0 phr in ENR-25 compound. Scanning electron microscopy (SEM) proved that each optimum ALK loading exhibited the greatest matrix tearing line and surface roughness due to better rubber - filler interaction.     

醚化PBS与CMC液体复合材料的相互作用

采用聚乙二醇(PEG)对聚丁二酸丁二醇酯(PBS)进行醚化改性,得到醚化PBS(PEG/PBS),PEG/PBS与羧甲基纤维素(CMC)共混制备了在水相均匀分散的新型(PEG/PBS)-CMC液体复合材料.结合分子模拟技术对PEG/PBS与CMC复合材料的相互作用机理进行了研究.结果表明,PEG/PBS具有预期的化学结构和优异的水润湿性;含醚链段PEG的引入有效提高了PBS分子链的极性和柔顺性,PEG/PBS与CMC之间存在氢键作用、范德华力作用、疏水作用和吸附作用.红外光谱(FTIR)中官能团(如—OH,—OCO—,—COOH,—C—O—C—等)的吸收峰频率发生偏移;光电子能谱(XPS)中C和O元素的结合能分布转移,表明PBS及PEG/PBS与CMC的官能团之间发生了相互作用;偏光显微镜(POM)和X射线衍射(XRD)结果表明,复合材料之间的相互作用为非共价键的结合;扫描电子显微镜(SEM)结果表明醚化改性后(PEG/PBS)-CMC复合材料间的相互作用增强,表面结合更紧密,相容性得到提高.     

Measurement and modeling on hydrodynamic forces and deformation of an air bubble approaching a solid sphere in liquids

The interaction between bubbles and solid surfaces is central to a broad range of industrial and biological processes. Various experimental techniques have been developed to measure the interactions of bubbles approaching solids in a liquid. A main challenge is to accurately and reliably control the relative motion over a wide range of hydrodynamic conditions and at the same time to determine the interaction forces, bubble–solid separation and bubble deformation. Existing experimental methods are able to focus only on one of the aspects of this problem, mostly for bubbles and particles with characteristic dimensions either below 100 μm or above 1 cm. As a result, either the interfacial deformations are measured directly with the forces being inferred from a model, or the forces are measured directly with the deformations to be deduced from the theory. The recently developed integrated thin film drainage apparatus (ITFDA) filled the gap of intermediate bubble/particle size ranges that are commonly encountered in mineral and oil recovery applications. Equipped with side-view digital cameras along with a bimorph cantilever as force sensor and speaker diaphragm as the driver for bubble to approach a solid sphere, the ITFDA has the capacity to measure simultaneously and independently the forces and interfacial deformations as a bubble approaches a solid sphere in a liquid. Coupled with the thin liquid film drainage modeling, the ITFDA measurement allows the critical role of surface tension, fluid viscosity and bubble approach speed in determining bubble deformation (profile) and hydrodynamic forces to be elucidated. Here we compare the available methods of studying bubble–solid interactions and demonstrate unique features and advantages of the ITFDA for measuring both forces and bubble deformations in systems of Reynolds numbers as high as 10. The consistency and accuracy of such measurement are tested against the well established Stokes–Reynolds–Young–Laplace model. The potential to use the design principles of the ITFDA for fundamental and developmental research is demonstrated.     

伪可变体系的几何构造分析

伪可变体系几何可变性的研究，对轻型结构的设计分析已变得十分重要。本文先分析能量与平衡之间的普遍关系，进而得出判定体系可变性的能量准则。通过拉格朗日乘子的引入，建立能量泛函，得出判定极值的二次型。然后证明了乘积力法与能量法的一致性，并讨论了宜于计算机分析实现的矩阵表示方法。结果表明，若二次型确定，则体系伪可变；当半确定时，体系部分伪可变部分可变；否则体系含二阶以上的无穷小机构。     

Extraction-condensation method for solving large sets of equations in FE analysis

In static and dynamic analysis of a large complex structure, one may merely be interested in the stresses and displacements at some important locations. A new solution technique for structural analysis with FEM is proposed in this paper by which those important unknowns are separated from the rest. In static analysis the important unknows can be found directly. In dynamic analysis all mass and exciting forces can be condensed onto a small number of predetermined points in order to make the dynamic analysis much simplified. A large scale problem can be solved with a small capacity computer quickly.     

Multi-Stage Upscaling: Selection of Suitable Methods

Reservoirs are often composed of an assortment of rock types giving rise to permeability heterogeneities at a variety of length-scales. To predict fluid flow at the full-field scale, it is necessary to be aware of these different types of heterogeneity, to recognise which are likely to have important effects on fluid flow, and to capture them by upscaling. In fact, we may require a series of stages of upscaling to go from small-scales (mm or cm) to a full-field model. When there are two (or more) phases present, we also need to know how these heterogeneities interact with fluid forces (capillary, viscous and gravity). We discuss how these effects may be taken into account by upscaling. This study focusses on the effects of steady-state upscaling for viscous-dominated floods and tests carried out on a range of 2D models are described. Upscaling errors are shown to be reduced slightly by the increase in numerical dispersion at the coarse scale. We select a combination of three different upscaling methods, and apply this approach to a model of a North Sea oil reservoir in a deep marine environment. Six different genetic units (rock types) were identified, including channel sandstone and inter-bedded sandstone and mudstone. These units were modelled using different approaches, depending on the nature of the heterogeneities. Our results show that the importance of small-scale heterogeneity depends on the large-scale distribution of the rock types. Upscaling may not be worthwhile in sparsely distributed genetic units. However, it is important in the dominant rock type, especially if there is good connectivity through the unit between the injector wells (or aquifer) and the producer wells.This revised version was published online in May 2005. In the previous version one of the authors name was missing.     

Strong explosion near a parallelepipedic structure

The purpose of this paper is to report the blast loading characteristics resulting from the detonation of a stoichiometric propane–oxygen mixture, and to validate the approach which relies on simulating TNT explosions at large scale by small-scale experiments of gaseous explosions. Several dimensionless correlations are obtained from experimental data. These relationships allow determination of the parameters of a blast wave interacting with a structure as a function of the positions of the explosive charge and the structure. Simulations carried out with the Autodyn code show good correlation with experimental results. The Hopkinson law is suggested to predict the blast wave’s parameters at large scale on the basis of small-scale experiments and simulations. This paper was based on work that was presented at the 20th International Colloquium on the Dynamics of Explosions and Reactive Systems, Montreal, Canada, July 31–August 5, 2005.     

求解弹性梁的普遍化方法

介绍了一种求解弹性梁的新方法．该方法利用奇异函数与拉普拉斯变换相结合的方法导出弹性梁弯曲变形的普遍表达式，并利用边界条件确定约束力，对具有任意支承形式、受力状况和阶梯形状的静定或超静定梁具有普适性．     

Dynamics of a Rigid Unbalanced Rotor with Nonlinear Elastic Restoring Forces. Part I: Theoretical Analysis

In a previous paper, the dynamic behaviour of a Jeffcott rotor was studied in the presence of pure static unbalance and nonlinear elastic restoring forces. The present paper extends the analysis to a rigid rotor with an axial length such as to make the transverse moment of inertia greater than the axial one. As in the previous investigation, the elastic restoring forces are assumed to be nonlinear and the effects of couple unbalance are also included but, unlike the Jeffcott rotor, the system exhibits six degrees-of-freedom. The Lagrangian coordinates were fixed so as to coincide with the three coordinates of the centre of mass of the rotor and the three angular coordinates needed in order to express the rotor's rotations with respect to a reference frame having its origin in the centre of mass. The precession motions of such a rotor turn out to be cylindrical at low angular speeds and exhibit a conical aspect when operating at higher speeds. The motion equations of the rotor were written with reference to a system that was subsequently adopted for the experimental analysis. The particular feature of this system was the use of a steel wire (piano wire) for the rotor shaft, suitably constrained and with the possibility of regulating the tension of the wire itself, in order to increase or reduce the nonlinear character of the system. The numerical analysis performed with integration of the motion equations made it possible to point out that chaotic solutions were manifested only when the tension in the wire was given the lowest values – i.e. when the system was strongly nonlinear – in the presence of considerable damping and rotor unbalance values that were so high as to lose any practical significance. Under conditions commonly shared by analogous real systems characterised by poor damping, where the contribution to nonlinearity is almost entirely due to elastic restoring forces, the analysis pointed out that precession motions may be manifested with a periodic character, whether synchronous or not, or a quasi-periodic character, but in no case is the solution chaotic.     

The interaction of doubly periodic cracks

In this paper, an extremely accurate and efficient method for computing the interaction of a set of or multiple sets of general doubly periodic cracks has been presented on the basis of superposition principle, pseudo-traction method, and isolating analysis technique. A great number of typical examples are given in this paper. The stress intensity factors (SIF), the minimum strain energy density factors (SED) of crack tip and the critical stress (CRS) of crack growth are calculated with the accuracy of six significant digits for the rectangularly distributed periodic cracks and five significant digits for the general doubly periodic cracks. The relation of the interaction effect of the double periodic cracks with the periods and the ratio of crack length to crack spacing is analyzed. Also in this paper, the key technique problems for this method are discussed.