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91.
A novel approach is described for the selection of optimal instrument parameters that yield a mass spectrum which best replicates the molecular mass distribution of a synthetic polymer. The application of implicit filtering algorithms is shown to be a viable method to find the best instrument settings while simultaneously minimizing the total number of experiments that need to be performed. This includes considerations of when to halt the iterative optimization process at a point when statistically-significant gains can no longer be expected. An algorithm to determine the confidence intervals for each parameter is also given. Details on sample preparation and data analysis that ensure stability of the measurement over the time scale of the optimization experiments are provided. This work represents part of an effort to develop an absolute molecular mass distribution polymer Standard Reference Material. 相似文献
92.
93.
In this paper we investigate traveling wave solutions of a non-linear differential equation describing the behaviour of one-dimensional viscoelastic medium with implicit constitutive relations. We focus on a subclass of such models known as the strain-limiting models introduced by Rajagopal. To describe the response of viscoelastic solids we assume a non-linear relationship among the linearized strain, the strain rate and the Cauchy stress. We then concentrate on traveling wave solutions that correspond to the heteroclinic connections between the two constant states. We establish conditions for the existence of such solutions, and find those solutions, explicitly, implicitly or numerically, for various forms of the non-linear constitutive relation. 相似文献
94.
There are many computational tasks, in which it is necessary to sample a given probability density function (or pdf for short), i.e., to use a computer to construct a sequence of independent random vectors x i (i = 1, 2, ··· ), whose histogram converges to the given pdf. This can be difficult because the sample space can be huge, and more importantly, because the portion of the space, where the density is significant, can be very small, so that one may miss it by an ill-designed sampling scheme. Indeed, Markovchain Monte Carlo, the most widely used sampling scheme, can be thought of as a search algorithm, where one starts at an arbitrary point and one advances step-by-step towards the high probability region of the space. This can be expensive, in particular because one is typically interested in independent samples, while the chain has a memory. The authors present an alternative, in which samples are found by solving an algebraic equation with a random right-hand side rather than by following a chain; each sample is independent of the previous samples. The construction in the context of numerical integration is explained, and then it is applied to data assimilation. 相似文献
95.
In this paper, we consider and study the implicit complementarity problem in the setting of a Hilbert lattice. It has been shown that this problem can be formulated as a fixed-point problem by using a suitable change of variables. Moreover, this formulation allows us to prove the existence and uniqueness of solutions of the implicit complementarity problem. 相似文献
96.
Introduced in the late eighties by Roe, fluctuation splitting (or residual distribution) schemes have recently emerged as a viable alternative to Finite Volume and Finite Element methods for PDE based, fluid dynamics simulations using unstructured meshes. Their application to the numerical approximation of the compressible and incompressible Euler and Navier-Stokes equations is described, emphasizing low Mach number and incompressible applications. The advantages provided by time-preconditioning techniques are discussed and details of the implementation are given. 相似文献
97.
We investigate a discretization of a class of stochastic heat equations on the unit sphere with multiplicative noise. A spectral method is used for the spatial discretization and the truncation of the Wiener process, while an implicit Euler scheme with non-uniform steps is used for the temporal discretization. Some numerical experiments inspired by Earth’s surface temperature data analysis GISTEMP provided by NASA are given. 相似文献
98.
99.
本文引入并研究了Hilbert空间中的一类广义多值拟变分包含问题.借助预解算子技巧构造了一个新的两步迭代算法来逼近广义多值拟变分包含的解,并且证明了其解的存在性以及迭代算法生成的迭代序列的收敛性. 相似文献
100.
In this paper, we are interested in the solution of nonlinear inverse problems of the form F(x)=y. We propose an implicit Landweber method, which is similar to the third-order midpoint Newton method in form, and consider the convergence behavior of the implicit Landweber method. Using the discrepancy principle as a stopping criterion, we obtain a regularization method for ill-posed problems. We conclude with numerical examples confirming the theoretical results, including comparisons with the classical Landweber iteration and presented modified Landweber methods. 相似文献