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41.
42.
E. Lancry E. Levi A. Mitelman S. Malovany D. Aurbach 《Journal of solid state chemistry》2006,179(6):1879-1882
The Chevrel phase (CP), Mo6S8, was found to be an excellent cathode material for rechargeable magnesium batteries. Mo6S8 is obtained by a leaching process of Cu2Mo6S8, which removes the copper. A new method of Cu2Mo6S8 production was developed. In contrast to the well-known solid-state synthesis of CP, the method is based on the reaction in a molten salt media (KCl). A fast kinetics of this reaction allows using less active, but more convenient precursors (sulfides instead of sulfur), decreasing temperature and synthesis duration, as well as operation in the inert atmosphere instead of dynamic evacuated systems. It was shown that the composition and the electrochemical behavior of the products obtained by MSS and by the solid-state synthesis are identical. Thus, the molten salt method is extremely attractive for the large-scale production of the active materials for Mg batteries. 相似文献
43.
Structures of Charge-Perturbed or Sterically Overcrowded Molecules. 16. Tetracyanoethylene Sodium Dimethoxyethane The Single crystal structure of [(NC)2C? C(CN)2?·Na⊕(H3CO? CH2CH2? OCH3)]∞ reveals two formula units within the triclinic (P1 ) unit cell. The tetracyanoethylene radical anions are arranged along parallel double layers, which are shifted relative to each other, and in between which are interspersed the sodium counter cations and their dimethoxyethane ligands. The distances within the double layers amount to 300 pm and the ones between them to 385 pm. The six-fold coordinated Na⊕ centers are surrounded by four radical anions with contact distances Na…?N between 250 and 254 pm as well as by a twofold solvent ligand with Na…?O of 238 and 241 pm. Due to the electron transfer to the acceptor molecule, its (NC)2C-halves twist by 8° and the bond lengths of the N?C? C subunits, bent by each 3°, are shortened up to 2 pm. The structural parameters are compared to those of the analogous potassium salt [TCNE?K⊕DME], of the dianion , of the sodium salts [(NC)3C?Na⊕]∞ as well as [(NC)2C? C(CHCH)2? C(CN)2?Na⊕]∞ and, in addition, are discussed based on geometry-optimized MNDO calculations. 相似文献
44.
45.
功能性超薄有序分子沉积膜的制备及其结构研究 总被引:14,自引:4,他引:14
1991年G.Decher等首次探讨了阴阳离子与聚电解质交替沉积制备有机超薄膜的方法。我们在完善成膜技术和发展成膜基质的基础上,详细研究了其成膜过程与膜的结构,并定义这种新的自组装超薄有序膜为分子沉积膜——MD膜。MD膜是利用阴阳离子的静电吸附反应特性,通过相反离子体系的交替分子沉积制备的层状有序自组装多层超薄膜。需要指出的是,分子沉积既是有机超薄膜的制备技术,本身又是一种自组装超薄有序膜。MD膜制备工艺简单,热稳定性和长期稳定性好,不受基体形状与面积限制。 相似文献
46.
V. R. Kartashov T. N. Sokolova I. V. Timofeev E. V. Skorobogatova N. S. Zefirov 《Russian Chemical Bulletin》1994,43(5):760-768
The kinetics of mercuration of bornylene and cyclohexene in different solvents in the presence of NaOAc and LiClO4 has been investigated. Addition of NaOAc sharply decreases the rate of addition reactions of mercuric acetate to bornylene and cyclohexene in alcohols; the main direction of the mercuration of bornylene is the formation of acetoxy-adducts, and the yield of solvo-adducts decreases from 76 % in the absence of NaOAc, to 19 % in the presence of the salt (4·10–3 mol L–1). A reaction scheme involving the participation of intermediate ion pairs and a solvated mercurinium ion is suggested and confirmed by a steady-state concentration method. The influence of NaOAc on the rate of the reaction and on product formation is realized through the common ion effect.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 819–826, May, 1994. 相似文献
47.
本文合成了一些季铵盐聚合物试剂,研究了这些试剂对三氯乙酸分解生成三氯乙酰氯的催化作用。不同季铵盐聚合物催化剂对三氯乙酸分解的催化活性顺序如下: (?) (?) 聚合物催化剂经重复使用后,活性并无明显降低。 相似文献
48.
具有优良NLO性质的芪唑盐(记为S)已被用于制备LB薄膜,但其成膜性不好,稳定性差;S和花生酸镉(记为A)的混合系虽可改善成膜性,但在此混合膜系中,S相的稳定性仍然不佳。应用SAXS和微机模型拟合(MCMI)研究了上述两类LB薄膜的凝聚态结构,结果指出:在LB薄膜的二维类晶系结构中,S分子中呈哑铃形的芪唑基倾向于作倾斜状的密堆砌,S分子中的丙条脂肪链则倾向于采取全反式燕尾式构象,而且脂肪链只占S分子长的2/3,这就导致了S分子在二维类晶系结构中凝聚力的下降,以及造成LB薄膜层状超分子结构的破坏和崩塌。 相似文献
49.
Summary. The regioselectivity of 1,3-dipolar cycloaddition reactions of 1-aza-2-azoniaallene salts with ,-unsaturated nitriles such as acrylonitrile or cyclohexylidene acetonitrile afforded only 1,2,4-triazolium salts via addition to the nitrile group, while the other expected pyrazolium salts were not observed. Moreover, 1-aza-2-azonia-allene salts reacted with other competitive systems such as -iminonitrile derivatives yielding only triazolium salts via addition to the nitrile and not to the imino group. Treatment of cumulene with 3-pyridylnitrile afforded the pyridinium salt. However, 2,3-dimethyl-5-(2,6-dimethoxyphenyl)-[1,2,4]triazole could be prepared from cumulene and 2,6-dimethoxybenzonitrile. Some reactions of nitriles with 1-aza-2-azonia-allene salts prepared from 1,2,3-indantrione and 9-acetylphenanthrene are discussed. 相似文献
50.
吗啡烷型生物碱类药物的化学发光分析法研究 总被引:2,自引:0,他引:2
雷氏盐(NH4Cr(NH3)2(SCN)4).H2O)是生物碱类物质的沉淀剂,经研究发现,雷氏盐可以催化鲁米诺与过氧化氢的化学发光反应,而吗啡烷型生物碱能沉淀雷氏盐,可导致鲁米诺-过氧化氢-雷氏盐体系化学发光强度的降低,根据这一发现,本文建立了吗啡烷型生物碱类药物(吗啡,青藤碱,可待因)的流动注射化学发光分析方法,方法有较低的检出限,较宽的线性范围和较好精密度用于一些药物的测定,结果较为满意。 相似文献