全文获取类型
收费全文 | 156篇 |
免费 | 7篇 |
国内免费 | 19篇 |
专业分类
化学 | 170篇 |
数学 | 2篇 |
物理学 | 10篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 18篇 |
2012年 | 8篇 |
2011年 | 6篇 |
2010年 | 7篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 15篇 |
2006年 | 10篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 3篇 |
2000年 | 10篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 8篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
排序方式: 共有182条查询结果,搜索用时 16 毫秒
131.
132.
133.
While the developments of additive manufacturing (AM) techniques have been remarkable thus far, they are still significantly limited by the range of printable, functional material systems that meet the requirements of a broad range of industries; including the health care, manufacturing, packaging, aerospace, and automotive industries. Furthermore, with the rising demand for sustainable developments, this review broadly gives the reader a good overview of existing AM techniques; with more focus on the extrusion-based technologies (fused deposition modeling and direct ink writing) due to their scalability, cost efficiency and wider range of material processability. It then goes on to identify the innovative materials and recent research activities that may support the sustainable development of extrusion-based techniques for functional and multifunctional (4D printing) part and product fabrication. 相似文献
134.
《中国化学会会志》2003,50(2):273-278
Spiro[indole‐pyranoimidazoles] ( 5 ) and spiro[indole‐pyranobenzopyrans] ( 6 ) are readily synthesized in one step in 86–92 and 91–97% yields by the Michael condensation of 3‐dicyanomethylene‐2H‐indol‐2‐ones ( 2 ) with 1‐phenyl‐2‐thiohydantoin ( 3 ) and 4‐hydroxy‐2H‐1‐benzopyran‐2‐one ( 4 ), respectively, without using any catalyst under different reaction conditions (conventional heating and microwave irradiation using (a) polar solvents (b) neutral alumina/silica gel as inorganic solid support in solvent free conditions). 2 was synthesized in situ by the Knoevenagel condensation of indole‐2,3‐dione ( 1 ) and malononitrile in the absence of any catalyst. 100% conversion was observed in most cases on TLC which also showed the formation of a single product. The comparison between the various methods is established. 相似文献
135.
The Suzuki reaction of both (E)- and (Z)-α-chloro-γ-hydroxyenamides with benzeneboronic acid by using Pd2(dba)3, tBu3P, and Cs2CO3 proceeded stereoselectively to afford only (E)-trisubstituted enamides. Also, palladium-catalyzed intramolecular cyclization of (E)- and (Z)-α-chloro-γ-hydroxyenamides bearing an N-arylsulfonyl group took place stereoselectively to give the corresponding (E)-2,3-dihydrobenzoisothiazole 1,1-dioxides. The γ-hyroxy group in α-chloroenamides was found to accelerate the present palladium-catalyzed carbon-carbon bond forming reactions. 相似文献
136.
QIU Pei hong 《高等学校化学研究》1997,(1)
DeterminationofAminoAcidsasTheirN┐Hydroxy┐succinimidyl┐3┐indolylacetateDerivativesbyReversed┐phaseHPLC*QIUPei-hong**(Departme... 相似文献
137.
3‐Arylsydnone‐4‐carbohydroximic acid chlorides ( 1 ) could react with sodium azide to produce the corresponding 3‐arylsydnone‐4‐carbazidoximes ( 2 ), but not 1‐hydroxytetrazoles 3 . Treatment of 3‐arylsydnone‐4‐carbazidoximes ( 2 ) with acid chlorides such as acetyl chloride ( 4a ), propionyl chloride ( 4b ) and benzoyl chloride ( 4c ) in the presence of excess triethylamine generated the derivatives of the azidoximes 5 . To obtain the desired tetrazoles, the azidoximes 2 should first cyclize directly with acetyl chloride ( 4a ) or propionyl chloride ( 4b ) to afford the acetyl or propionyl derivatives 6 . The cyclized tetrazole derivatives 6 underwent deacylation upon heating in ethanol to give 1‐hydroxy‐5‐(3‐arylsydnon‐4‐yl)tetrazoles ( 3 ). 相似文献
138.
从鳙鱼(Aristichthysnobilis)的心脏肌肉中分离得到一种带长链的六环内酯化合物,熔点62.3~62.8℃,由1HNMR,13CNMR,IR,MS等波谱数据推导其化学结构为4羟基2羟甲基2十七烷基1,5戊内酯,文献检索表明为新化合物。 相似文献
139.
Murat Acemoglu Andre Brodbeck Angel Garcia Dominique Grimler Marc Hassel Bernhard Riss Robert Schreiber 《Helvetica chimica acta》2007,90(6):1069-1081
A new synthetic method for the preparation of pitavastatin is described. The approach circumvents various synthetic problems associated with the buildup of the 3,5‐dihydroxy‐C7 acid side chain of HMG‐CoA reductase inhibitors (statins). The use of the C6‐amide derivative 5 instead of ester derivatives in the coupling reaction with carboxaldehyde 8 (Scheme 3) prevents undesired side reactions, such as eliminations and retro‐aldol reactions. The method provides synthetic statins, such as pitavastatin, in >99% ee and exceptionally high overall yield. The enantiomerically pure starting material, (3S)‐3‐{[(tert‐butyl)dimethylsilyl]oxy}‐5‐oxo‐5‐{[(1S)‐1‐phenylethyl]amino}pentanoic acid ( 3c ), is prepared by an improved procedure from 3‐{[(tert‐butyl)dimethylsilyl]oxy}glutaric anhydride ( 1 ) and (1S)‐1‐phenylethylamine ( 2c ; Scheme 1). 相似文献
140.