全文获取类型
收费全文 | 7267篇 |
免费 | 832篇 |
国内免费 | 253篇 |
专业分类
化学 | 5911篇 |
晶体学 | 90篇 |
力学 | 193篇 |
综合类 | 2篇 |
数学 | 107篇 |
物理学 | 2049篇 |
出版年
2024年 | 14篇 |
2023年 | 76篇 |
2022年 | 191篇 |
2021年 | 233篇 |
2020年 | 360篇 |
2019年 | 247篇 |
2018年 | 171篇 |
2017年 | 180篇 |
2016年 | 302篇 |
2015年 | 323篇 |
2014年 | 356篇 |
2013年 | 471篇 |
2012年 | 416篇 |
2011年 | 401篇 |
2010年 | 317篇 |
2009年 | 423篇 |
2008年 | 431篇 |
2007年 | 530篇 |
2006年 | 388篇 |
2005年 | 309篇 |
2004年 | 256篇 |
2003年 | 276篇 |
2002年 | 216篇 |
2001年 | 190篇 |
2000年 | 152篇 |
1999年 | 162篇 |
1998年 | 163篇 |
1997年 | 72篇 |
1996年 | 77篇 |
1995年 | 77篇 |
1994年 | 58篇 |
1993年 | 60篇 |
1992年 | 50篇 |
1991年 | 43篇 |
1990年 | 40篇 |
1989年 | 36篇 |
1988年 | 35篇 |
1987年 | 27篇 |
1986年 | 33篇 |
1985年 | 29篇 |
1984年 | 26篇 |
1983年 | 8篇 |
1982年 | 13篇 |
1981年 | 13篇 |
1980年 | 20篇 |
1979年 | 18篇 |
1978年 | 14篇 |
1977年 | 13篇 |
1976年 | 10篇 |
1974年 | 8篇 |
排序方式: 共有8352条查询结果,搜索用时 310 毫秒
11.
Jack Harrowfield Dominique Matt 《Journal of inclusion phenomena and macrocyclic chemistry》2004,50(3-4):133-150
The problems involved in identifying and quantifying labile interactions considered to influence complex compound structures are highlighted through the assessment of four different families of metal complexes for which extensive crystallographic data are available. Modification of the charge distribution within a ligand molecule as a result of coordination is one factor with a number of ramifications. A detailed analysis of evidence for both intra- and inter-molecular attractions in dimethylsulfoxide complexes of metal perchlorates is used to provide a basis for the consideration of weak interactions between complex ions involving forces including phenyl-group attractions, hydrogen bonding and cavity inclusion. 相似文献
12.
An effective residual interaction between particles and holes for shell model calculations around 208Pb, derived from the interaction between free nucleons, is compared with the measured properties of proton-hole neutron states
in 208Tl and the interaction between proton holes is adjusted to newly measured level energies in 206Hg. These interaction elements are particularly relevant for neutron-rich nuclei. The adjustment of two mixing elements reproduces
the known γ-decay data in 208Tl.
Received: 2 April 2002 / Accepted: 2 May 2002 相似文献
13.
F. Rubio F. García H. D. Burrows A. A. C. C. Pais A. J. M. Valente M. J. Tapia J. M. García 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1788-1799
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007 相似文献
14.
Alain Estve Adeline Bail Georges Landa Ahmed Dkhissi Marie Brut Mehdi Djafari Rouhani Jan Sudor Anne-Marie Gu 《Chemical physics》2007,340(1-3):12-16
Possible collapsed forms of poly(N-isopropylacrylamide) molecules are reviewed on the basis of first principle calculations. Various configurations and associated conformations are detailed. The calculated optimized structures exhibit different possibilities of creating networks of intra-molecular bonds of the hydrogen type. We show that the most remarkable one is able to form a local, self-saturated and well ordered helix. We also indicate in which direction the synthesis of the molecule should be oriented to improve its global behavior in term of hydrophobic/hydrophilic behavior. 相似文献
15.
T. Bernhard 《Surface science》2006,600(9):1877-1883
The structure and magnetism of thin epitaxial Fe layers grown on Cu(0 0 1) is investigated by grazing scattering of fast H and He atoms. Information on the atomic structure of the film and substrate surfaces is obtained by making use of ion beam triangulation with protons. The magnetic behavior is studied via the polarization of light emitted after capture of spin-polarized electrons into excited atomic terms during scattering of He atoms. For the formation of bcc(1 1 0)-like Fe films at higher coverages, we detect differences in structural and magnetic properties for room and low temperature growth. We suggest that the crystalline structure depends on the film morphology and that Cu impurities affect the magnetic properties. 相似文献
16.
We study the propagation of the light mesons σ,ω,ρ, and a0(980) in dense hadronic matter in an extended derivative scalar coupling model. Within the scheme proposed it is possible
to unambiguously define effective density-dependent couplings at the Lagrangian level. We first apply the model to study asymmetric
nuclear matter with fixed isospin asymmetry, and then we pay particular attention to hypermatter in β-equilibrium. The equation
of state and the potential contribution to the symmetry coefficient arising from the mean-field approximation are investigated.
Received: 16 October 2001 / Accepted: 10 January 2002 相似文献
17.
18.
The Monte Carlo ray-tracing method (MCRT) based on the concept of radiation distribution factor is extended to solve radiative heat transfer problem in turbulent fluctuating media under the optically thin fluctuation approximation. A one-dimensional non-scattering turbulent fluctuating media is considered, in which the mean temperature and absorption coefficient distribution are assumed and the shape of probability density function is given. The distribution of the time-averaged volume radiation heat source is solved by MCRT and direct integration method. It is shown that the results of MCRT based on the concept of radiation distribution factor agree with these of integration solution very well, but results of MCRT based on the concept of radiative transfer coefficient do not agree with these of integration solution. The solution of time-averaged radiative transfer equation by the concept of radiative transfer coefficient should be treated with caution. 相似文献
19.
Maria G. Semenova Larisa E. Belyakova Anna S. Antipova Yu. N. Polikarpov Lida Klouda Anna Markovic Michael M. Il'in 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):47-54
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed. 相似文献
20.
A. D. Krisch 《The European Physical Journal A - Hadrons and Nuclei》2007,31(4):417-423
There will be a review of the history of polarized proton beams, and a discussion of the unexpected and still unexplained
large transverse spin effects found in several high-energy proton-proton spin experiments at the ZGS, AGS and Fermilab. Next,
there will be a discussion of present and possible future experiments on the violent elastic collisions of polarized protons
at IHEP-Protvino's 70GeV U-70 accelerator in Russia and the new high-intensity 50GeV J-PARC facility being built at Tokai
in Japan. 相似文献