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81.
Summary First we give a construction of bridges derived from a general Markov process using only its transition densities. We give sufficient conditions for their existence and uniqueness (in law). Then we prove that the law of the radial part of the bridge with endpoints zero derived from a special multidimensional Ornstein--Uhlenbeck process equals the law of the bridge with endpoints zero derived from the radial part of the same Ornstein--Uhlenbeck process. We also construct bridges derived from general multidimensional Ornstein--Uhlenbeck processes.  相似文献   
82.
The chemistry of the gaseous halide complexes which have been observed in large numbers in recent years is discussed for the example of chlorides. Homo-complexes—dimeric or polymeric chloride molecules containing chlorine-bridge linkages [e.g.(NaCl)n, n = 2—4; (CuCl)n, n = 2—5; (BeCl2)n, n = 2—4; Pd6Cl12]—occur through broad areas of the Periodic Table. Comparison of the dissociation enthalpy of such molecules with the vaporization enthalpy of the liquid chlorides is particularly informative. Hetero-complexes are formed from different chloride molecules by linkage through Cl bridges. Not only 1:1 complexes (e.g. NaAlCl4, TIPbCl3, KThCl5, CdPbCl4, AlUCl8) but also larger molecules (e.g. CoAl2Cl8, CrAl3Cl12, Cu2UCl6, In2UCl10) are known. Types of formulas, structures, and above all the formation enthalpies of such complexes are discussed critically. Hetero-complexes are useful in chemical transport reactions, as aids in syntheses, and in gas-chromatographic separations (lanthanoids, actinoids). They also play a part in many industrial processes (chlorination of ores) and in recently developed types of high-pressure discharge tubes.  相似文献   
83.
We prove the existence of weak T-periodic solutions for a nonlinear mathematical model associated with suspension bridges. Under further assumptions a regularity result is also given.  相似文献   
84.
Nonlinear variational equations describing one type of suspension bridges are proposed and studied. The variational equations describe the behaviour of road bed, main cables and cable stays. The road bed is described by two functions connected with vertical and horizontal deformation of any cross section. The main cable is considered to be perfectly flexible and inextensible. The cable stays only resist tensile forces. The variational equations are derived from the principle of minimum potential energy. The existence of solution is based on the Brouwer Fixed Point Theorem. The local uniqueness and continuous dependence on the data represented by gravitational forces acting on the road bed are studied. The local results are based on the Implicit Function Theorem for Banach spaces. A certain stability criterion for suspension bridges is formulated and this criterion indicates how to influence the stability of suspension bridges.  相似文献   
85.
The possibilities of computational methods for assessing the response of cable supported bridges under wind action are considered in this work. The main objective is to study the possibilities of substituting wind tunnel campaigns by computer based analyses, particularly at the early design stage. The preliminary proposed design for a continuous cable-stayed bridge with two main spans of 650 m and a single box girder deck has been considered as a case study. The force coefficients of the deck cross-section have been computed and the unsteady response associated to vortex-shedding has been simulated using CFD commercial software. Furthermore, an in-house piece of software has been employed to obtain the response for flutter and buffeting phenomena adopting the hybrid approach; with that purpose the experimental flutter functions of a similar box girder deck were adopted. The computational results have been validated by comparison with similar experimental results published by other researchers. It has been verified that the set of adopted methods offers reliable results with moderate costs; therefore, the proposed approach is very suitable at the early design stage of long span bridges or at conceptual design works.  相似文献   
86.
87.
    
Recent innovations highlight the great potential of two‐dimensional graphene oxide (GO) films in water‐related applications. However, undesirable water‐induced effects, such as the redispersion and peeling of stacked GO laminates, greatly limit their performance and impact their practical application. It remains a great challenge to stabilize GO membranes in water. A molecular bridge strategy is reported in which an interlaminar short‐chain molecular bridge generates a robust GO laminate that resists the tendency to swell. Furthermore, an interfacial long‐chain molecular bridge adheres the GO laminate to a porous substrate to increase the mechanical strength of the membrane. By rationally creating and tuning the molecular bridges, the stabilized GO membranes can exhibit outstanding durability in harsh operating conditions, such as cross‐flow, high‐pressure, and long‐term filtration. This general and scalable stabilizing approach for GO membranes provides new opportunities for reliable two‐dimensional laminar films used in aqueous environments.  相似文献   
88.
89.
    
The calculated structures of several known and hypothetical cyclophanes with ethylene bridges (cyclophenes) are reported together with experimental and calculated values of their NMR parameters. Of the exchange‐correlation functionals and basis sets used in this work, only the ωB97X‐D/6‐311++G(2d,2p) and ωB97X‐D/cc‐pVQZ yielded values of the Csp3–Csp3 bond length close to the experimental data, although significant differences still remain. As far as the NMR parameters are concerned, except for close‐lying signals, chemical shifts and coupling constants calculated at the ωB97X‐D/cc‐pVQZ level reproduce in most cases the experimental trends. Contrary to the calculations of geometries, an agreement between the values of the NMR parameters obtained at ωB97X‐D/cc‐pVQZ level and the experimental ones is the poorest compared with that of the ωB97X‐D/6‐311++G(2d,2p) one. Taking into account that the results of the different calculations show the same qualitative trends in most cases, we believe that they correctly describe the structure and properties of the hypothetical molecules studied here. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
90.
    
The reactions of Cp*M(PMe3)Cl2 (M = Rh ( 1a ), Ir ( 1b )) with (NEt4)2[WS4] led to the heterodimetallic sulfido‐bridged complexes Cp*M(PMe3)[(μ‐S)2WS2] (M = Rh ( 2a ), Ir ( 2b )), whereas the dimers [Cp*MCl(μ‐Cl)]2 (M = Rh ( 4a ), Ir ( 4b )) reacted with (NEt4)2[WS4) to give the known trinuclear compounds [Cp*M(Cl)]2(μ‐WS4) (M = Rh ( 5a ), Ir ( 5b )). Hydrolysis of the terminal W=S bonds converts 2a, b into Cp*M(PMe3)[(μ‐S)2WO2] (M = Rh ( 3a ), Ir ( 3b )). Salts of a heterodimetallic anion, A[CpMo(I)(NO)(WS4)] ( 6 ) (A+ = NEt4+, NPh4+) were obtained by reactions of [CpMo(NO)I2]2 with tetrathiotungstates, A2[WS4]. The complexes were characterized by IR and NMR (1H, 13C, 31P) spectroscopy, and the X‐ray crystallographic structure of Cp*Rh(PMe3)[(μ‐S)2WS2] ( 2a ) has been determined. The bond lengths and angles in the coordinations spheres of Rh and W in 2a (Rh···W 288.5(1) pm) are compared with related complexes containing terminal [WS42—] chelate ligands.  相似文献   
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