全文获取类型
收费全文 | 12572篇 |
免费 | 1772篇 |
国内免费 | 1598篇 |
专业分类
化学 | 6927篇 |
晶体学 | 72篇 |
力学 | 752篇 |
综合类 | 79篇 |
数学 | 1577篇 |
物理学 | 6535篇 |
出版年
2024年 | 22篇 |
2023年 | 196篇 |
2022年 | 286篇 |
2021年 | 278篇 |
2020年 | 375篇 |
2019年 | 358篇 |
2018年 | 275篇 |
2017年 | 378篇 |
2016年 | 489篇 |
2015年 | 470篇 |
2014年 | 630篇 |
2013年 | 1154篇 |
2012年 | 751篇 |
2011年 | 901篇 |
2010年 | 692篇 |
2009年 | 838篇 |
2008年 | 836篇 |
2007年 | 910篇 |
2006年 | 864篇 |
2005年 | 718篇 |
2004年 | 627篇 |
2003年 | 553篇 |
2002年 | 436篇 |
2001年 | 331篇 |
2000年 | 351篇 |
1999年 | 278篇 |
1998年 | 282篇 |
1997年 | 260篇 |
1996年 | 193篇 |
1995年 | 158篇 |
1994年 | 152篇 |
1993年 | 103篇 |
1992年 | 109篇 |
1991年 | 91篇 |
1990年 | 77篇 |
1989年 | 82篇 |
1988年 | 84篇 |
1987年 | 68篇 |
1986年 | 41篇 |
1985年 | 37篇 |
1984年 | 26篇 |
1983年 | 19篇 |
1982年 | 38篇 |
1981年 | 25篇 |
1980年 | 28篇 |
1979年 | 20篇 |
1978年 | 14篇 |
1977年 | 12篇 |
1976年 | 8篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
71.
Takashi Nakamura 《Journal of Number Theory》2007,123(1):1-9
In this paper, we define λ-joint, a′-joint, (λ,λ)-joint, (λ,a′)-joint and (a′,a′)-joint t-universality of Lerch zeta functions and consider the relations among those. Next we show the existence of (λ,λ)-joint t-universality. Finally, we also show the existence of λ-joint, a′-joint, (λ,a′)-joint and (a′,a′)-joint t-universality by using inversion formulas. 相似文献
72.
V. S. Klimov 《Mathematical Notes》2007,81(1-2):61-71
We study homology characteristics of critical values and extremals of Lipschitz functionals defined on bounded closed convex subsets of a reflexive space that are invariant under deformations. Sufficient conditions for the existence of a bifurcation point of a multivalued potential operator (the switch principle for the typical number of an extremal) are established. 相似文献
73.
T. Rietmann S. Sohn M. Schröder D. Lipinsky H.F. Arlinghaus 《Applied Surface Science》2006,252(19):6640-6643
In order to improve quantification of high mass ions, the influence of cluster composition on detection efficiencies has been studied using a TOF-SIMS IV with the extended capability of postaccelerating ions up to 20 keV. In this experimental study, we focus on the comparison of detection efficiencies for three types of negatively charged secondary cluster ions: gold-alkanethiolate-clusters (AuxMy), gold-sulfur-clusters (AuxSy) and gold-clusters (Aux). The clusters were sputtered from self-assembled monolayers of hexadecanethiols on gold substrates using 10 keV Ar+ primary ions. The detection efficiencies were derived on the basis of a function for the secondary electron yield and a fourth-order approximated Poisson probability distribution for electron propagation and amplification within the microchannel plate.In addition to the well-known dependence of detection efficiencies on ion mass and energy, which has already been studied for positively charged ions, we were able to show a similar behaviour for the investigated negatively charged secondary ions. We have observed major variations among the three types of clusters at similar mass and energy as predicted in a theoretical approach. The observed differences are due to the different composition of the investigated clusters which has a major influence on the kinetic ion induced electron emission within the microchannel plate. For the first time it was possible to experimentally verify these predictions for detection efficiencies. 相似文献
74.
75.
Mihai V. Putz 《International journal of quantum chemistry》2006,106(2):361-389
A unified Mulliken valence with Parr ground‐state electronegativity picture is presented. It provides a useful analytical tool on which the absolute hardness as well ionization potential and electron affinity functionals are based. For all these chemical reactivity indices, systematic approximate density functionals are formulated within density functional softness theory and are applied to atomic systems. For the absolute hardness, a special relationship with the new electronegativity ansatz and a particular atomic trend paralleling the absolute electron affinity are established that should complement and augment the earlier finite‐difference energetic approach. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
76.
用遗传算法结合Gupta紧束缚模型势研究了Irn(n=2-25)团簇的基态结构.分析了Irn(n=2-25)团簇的基态结构随团簇尺寸的变化规律.计算结果表明,Irn(n=2-25)团簇的每个原子的平均束缚能和平均第一近邻随团簇尺寸的增加而增大,以总束缚能的二阶差分为判据,Irn(n=2-25)团簇的幻数是4、7、9、13、15、19、23. 相似文献
77.
在研究大量实验曲线的基础上,指出势阱所有能级均有一定的宽度,电子或空穴在各能级中出现的概率符合正态分布,从理论上分析了I类超晶格和双势垒单势阱的发光光谱与吸收光谱·解释了GaAs/Ga1-xAlxAs多量子阱和超晶格吸收光谱吸收边及量子阱变窄时各吸收峰的“蓝移现象”及GaAs/Ga1-xAlxAs双势垒单量子阱样品的电流—电压特性曲线及电导—电压特性曲线的特征和出现的“负阻效应”· 相似文献
78.
使用“对称性匹配簇-组态相互作用”方法,对Li2分子三重态的第一激发态、LiH分子的基态、单重态的第一和第二激发态的几何构型与谐振频率进行了优化计算.利用“群操作求和”方法分别对这4个态进行单点能扫描计算,并拟合出了相应各态的Murrell-Sorbie势能函数.使用多种方法对Li2H分子的基态结构进行优化,并用优选出的密度泛函(B3P86)方法对该分子进行了进一步的频率计算.结果发现Li2H分子的基态稳态结构为C2v构型,在此基础上用多体项展式理论导出了它的解析势能函数,其等值势能图准确再现了Li2H分子的结构特征和离解能.首次报导了该分子对称伸缩振动等值势能图中存在的两个对称鞍点,对应于反应LiH Li→Li2H,活化能大约为18.7×4.184 KJ/mol. 相似文献
79.
The 11 800-14 380 cm−1 frequency range has been scanned for rotationally resolved rovibronic transitions in the A2B2-X2A1 electronic band system of the symmetric (C2v) 16O14N16O and 18O14N18O isotopologues and in the corresponding electronic band system of the asymmetric (Cs) 18O14N16O isotopologue. The rotational analysis—reflecting minor differences in mass—in combination with symmetry induced spectral differences allows an identification of 68 16O14N16O vibronic levels, 26 18O14N18O vibronic levels and 51 18O14N16O vibronic levels. The bands are recorded using near infrared fluorescence spectroscopy and a piezo valve based pulsed molecular beam expansion of premixed 18O2 and 14N16O in Ar. The majority of the observed bands is rotationally assigned and can be identified as transitions starting from the vibrational ground state of one of the isotopologues. Numerous hot bands have also been identified. A comparison of the overall spectroscopic features of C2v vs. Cs symmetric species provides qualitative information on symmetry dependence of vibronic couplings. 相似文献
80.
Raman spectra of ceramic Sr2Bi4Ti5O18 (SBTi5) are reported to consist of four different Raman bands. Temperature-dependent spectra reveal the relationship between the lattice vibration and the material's structure. There appears a relatively large change in structure of the material at about 273K, The anharmonic potential of the material has a great influence on its phonon mode full width at half maximum (FWHM), which can be expressed by a function of temperature. Theoretical fittings of the FWHMs for the two modes at around 312 cm^-1 and 464cm^-1 indicate that the latter phonon mode is more anharmonic than the former one. 相似文献