Synthesis,characterization and magnetic properties of cyanide bridged 1-D metal-coordination polymers based on [FeIII(s-bqdi)2(CN)2]−

A new series of transition metal complexes K[M^II(s-bqdi)₂][Fe^III(s-bqdi)₂(CN)₂]?·?10H₂O (s-bqdi?=?semibenzoquinonediiminate, M^II?=?Co (2), Ni (3), and Cu (4)) have been synthesized. These complexes have been characterized by elemental analyses, FT IR, Far IR, FAB mass, UV-Vis, TGA, CV measurements, and powder XRD. The powder XRD patterns of 2, 3, and 4 show that they are isostructural with hexagonal primitive lattice structures. The coordination polymers display 1-D chain networks. Magnetic properties of the Co^IIFe^III complex studied by a SQUID magnetometer reveal low-temperature antiferromagnetic interaction.     

SERS activity of Au nanoparticles coated on an array of carbon nanotube nested into silicon nanoporous pillar

A novel composite structure, Au nanoparticles coated on a nest-shaped array of carbon nanotube nested into a silicon nanoporous pillar array (Au/NACNT/Si-NPA), was fabricated for surface-enhanced Raman scattering (SERS). The morphology of the Au/NACNT/Si-NPA composite structure was characterized with the aid of scanning electron microscopy, X-ray diffraction instrumentation and Transmission electron microscopy. Compared with SERS of rhodamine 6G (R6G) adsorbed on SERS-active Au substrate reported, the SERS signals of R6G adsorbed on these gold nanoparticles were obviously improved. This was attributed to the enlarged specific surface area for adsorption of target molecules brought by the nest-shaped CNTs structure.     

强度m的对称正交表的递归构造

本文证明了Q~n空间的正交分划的存在性,对2水平正交表的递归构造方法进行了改进,通过对正交分划的构造提出了任意强度的高水平对称正交表的递归构造方法.     

Application of principal component analysis to gas sensing characteristics of Cr0.8Fe0.2NbO4 thick film array

The transient changes in resistances of Cr_0.8Fe_0.2NbO₄ thick film sensors towards specified concentrations of H₂, NH₃, acetonitrile, acetone, alcohol, cyclohexane and petroleum gas at different operating temperatures were recorded. The analyte-specific characteristics such as slopes of the response and retrace curves, area under the curve and sensitivity deduced from the transient curve of the respective analyte gas have been used to construct a data matrix. Principal component analysis (PCA) was applied to this data and the score plot was obtained. Distinguishing one reducing gas from the other is demonstrated based on this approach, which otherwise is not possible by measuring relative changes in conductivity. This methodology is extended for three Cr_0.8Fe_0.2NbO₄ thick film sensor array operated at different temperatures.     

Distinguishing the Topological Zero Mode and Tamm Mode in a Microwave Waveguide Array

The Su–Schrieffer–Heeger (SSH) model has been the subject of extensive experimental research in the context of topological photonics. Ideally, the on‐site potential and hopping strength are sufficiently accurate for implementation in photonic coupled waveguide arrays. Here, two localized edge modes, the topological zero mode and trivial Tamm mode, are proposed and demonstrated in the modified SSH model using a microwave photonic waveguide array. The system used is composed of an array of evanescently coupled ultrathin corrugated metallic “H‐bar” waveguides. Furthermore, the differences between the zero mode and Tamm mode are clearly demonstrated by microwave near‐field experiments on the coupling behavior along the propagation direction for 40 cm at the excitation frequency of 17 GHz. These findings should deepen the understanding of localized edge mode confinement mechanisms, both in coupled waveguide array systems and other topological or quantum systems.     

Constructions of pairs of orthogonal latin cubes

A pair of orthogonal latin cubes of order $q$ is equivalent to a maximum distance separable code with distance 3 or to an ${\mathit{OA}}_1\left(3,5,q\right)$ orthogonal array. We construct pairs of orthogonal latin cubes for sequences of previously unknown orders $q_i=16\left(18i?1\right)+4$ and $q_i^{\prime }=16\left(18i+5\right)+4$. The minimal new obtained parameters of orthogonal arrays are ${\mathit{OA}}_1\left(3,5,84\right)$.     

光机械式红外探测器中镜面弯曲对探测灵敏度的影响

光学读出式红外成像技术是近年来研究的热点，本文讨论了镜面弯曲对光学检测灵敏度的影响。由双材料微悬臂梁组成的非致冷焦平面阵列通过体刻蚀工艺加工而成，由于残余应力的影响，制成的焦平面阵列将会发生弯曲，应力导致的镜面弯曲将会降低光学探测灵敏度。本文通过傅立叶光学模拟了镜面弯曲对光学探测灵敏度的影响，并通过实验验证了该模型。实验和模拟结果表明，在镜面曲率为0．1mm-1时，光学探测灵敏度将会降低到理想情况的40％。最后我们用这个模型评价了通过表面修饰来提高光学性能的效果。     

基于MEMS线阵的便携式中红外水中油浓度速测仪

针对传统光谱测油仪存在的环境适应能力弱、分析速度慢、测量重复性差等问题,研制了一种便携式中红外水中油浓度速测仪。其核心光路采用典型的非对称折叠式M型Czerny-Turner光学结构,有效缩小仪器体积;使用周期性转动的斩光器调制红外光源,并对斩光器转速进行数字PID控制,调制精度达到±0.5%;采用固定光栅作为分光元件,无需光栅扫描装置且不存在转动误差;利用新型MEMS红外线传感器阵列探测调制后的光谱信号,显著提高光谱采集速度。光学仿真及实验结果表明仪器光谱范围为2 800~3 200cm-1,光谱分辨率达到6cm-1(@3 130cm-1),信噪比达到5 200∶1,谱图采集速度为13ms·幅-1,吸光度标准偏差优于3×10-3,满足了水中油测定国家标准要求。与已有红外光谱测油仪相比,该仪器小型便携,分析速度快,测量精度高,抗震防潮性能好,特别适用于环境监测部门对水中油浓度的现场实时测量,因此在水质监测领域具有广阔的应用前景。     

Uncertainty of array-based measurement of radiated and absorbed sound intensity

Patch near-field acoustic holography (NAH) coupled with an array of sound intensity probes allows separating the sound field incident on a surface from the one radiated by the surface itself. Although the measurement principle has been successfully used to separate the noise source contribution from disturbing sources and/or noise reflections, the method accuracy has not been investigated in the literature. We describe the results of experiments meant to evaluate the uncertainty in the identification of noise radiated by vibrating panels with different absorption characteristics in presence of an incident acoustic radiation using the statistically optimized near-field acoustic holography. Measurement errors were evaluated through tests performed in controlled acoustic conditions. Results evidenced that the measurement uncertainty depends on the accuracy of the microphone array positioning and on the incident sound field. These conclusions were in agreement with the results obtained by simulations in the phase of instrument optimization.     

Automatic 3D scanning surface generation for microphone array acoustic imaging

This work presents a new technique for automatically generating the 3D scanning surface for acoustic imaging using microphone arrays. Acoustic images, or maps, of sound coming from spatially distributed sources, may be generated from microphone array data using algorithms such as beamforming. Traditional 2D acoustic maps can contain errors in the near-field if the object being imaged has a 3D shape. It has been shown that using the 3D surface geometry of an object as a scanning surface for beamforming can provide more accurate results. The methods used previously to generate this 3D scanning surface have either required existing CAD (Computer-Aided Design) models of the object being acoustically imaged or have required separate equipment which is generally bulky and expensive. The new method uses one or more cameras in the array, a data projector, and structured light code to automatically generate the 3D scanning surface. This has the advantage that it is inexpensive, can be incorporated as an add-onto existing microphone arrays, has short scan time, and is capable of being extended to imaging dynamic scenes. This technique is tested using beamforming and CLEAN-SC (CLEAN based on spatial Source Coherence) algorithms for a spherical array and an Underbrink multi-arm spiral array. For sound sources located about 1.2 m from the array, the mean position errors obtained are 6 mm. This is a quarter of the diameter of the mini-speakers being used as a sound sources.