钯与希夫碱类配合物的合成与表征

合成了把(I)与五个希夫碱的七个新配合物:(L1-H)护d, 相似文献   

非线性复杂系统的动力学问题

根据非线性动力学的研究现状和发展趋势,从六个方面去展望复杂系统的非线性动力学研究在21世纪的动向,探讨与其有关的动力系统理论和应用研究中面临的一些重大问题。     

有关力学谱和内耗工作的综合与回顾

本文广泛地收集了有关内耗，力学谱，超声衰减方面的专著及会议文集。反映了20世纪在此领域的英文，俄文出版的书籍。也列出了历次国际会议及前苏联，乌克兰，中国的国内会议。文中包括了点缺陷，电，声子，位错，晶界，电畴等诸方面在内的内耗与力学谱工作。     

微腔结构对铕配合物有机电致发光二极管(OLEDs)性能的提高

成功制备了铕配合物的微腔结构有机发光二极管(0LEDs),其发射层采用质量比为1：3的空穴传输材料(TPD)和电子传输材料(Eu(DBM)3bath)的混合层。该器件实现了Eu^3 高色纯度红光发射,其色坐标为(x=0．651,y=0．338);并克服了微腔器件的发光颜色随探测角度增大而变化的缺点。在微腔器件中,最大亮度在19V时达到1160cd／m^2;在高电流密度时的EL效率得到明显提高。     

利用钆配合物调节激基复合物发光颜色的一种有机发光二极管

报道一种可用钆配合物[Gd（DBM）3bath]调节电致发光（EL）颜色的有机发光二极管（OLED）。该有机发光二极管是在空穴传输层（m-MTDATA）和电子传输层（TPBI）之间插入-薄层Gd（DBM）3bath。随着Cd（DBM）3bath厚度增加,二极管的发光颜色呈现出绿色（主峰525nm）-黄色-橙色（主峰593rim）变化。该二极管的电致发光主要来自界面激基复合物的发射而不是来自各有机功能层;而发光颜色的变化是由于两种激基复合物发射的相对强度的改变。     

A mini-review on econophysics:Comparative study of Chinese and western financial markets

We present a review of our recent research in econophysics, and focus on the comparative study of Chinese and western financial markets. By virtue of concepts and methods in statistical physics, we investigate the time correlations and spatial structure of financial markets based on empirical high-frequency data. We discover that the Chinese stock market shares common basic properties with the western stock markets, such as the fat-tail probability distribution of price returns, the long-range auto-correlation of volatilities, and the persistence probability of volatilities, while it exhibits very different higher-order time correlations of price returns and volatilities, spatial correlations of individual stock prices, and large-fluctuation dynamic behaviors. Furthermore, multi-agent-based models are developed to simulate the microscopic interaction and dynamic evolution of the stock markets.     

基于光学传输矩阵的太赫兹时域光谱分析

提出了基于光学传输矩阵的提取太赫兹时域光谱光学参数的理论方法。相比于传统的提取主脉冲方法,该方法在未来可以推广用以分析主脉冲与次脉冲无法分辨的太赫兹时域光谱。利用该方法得到了蓝宝石(α-Al2O3)样品在0.3~1.0太赫兹频段的复折射率。通过与利用提取主脉冲方法得到的复折射率的结果比较,验证了基于光学传输矩阵的理论分析方法的可靠性和精确性。所提出的方法为今后主次脉冲无法分辨的太赫兹时域光谱的准确分析提供了坚实的理论基础。     

Theory of myelin coiling

A new model is proposed to explain coiling of myelins composed of fluid bilayers. This model allows the constituent bilayer cylinders of a myelin to be non-coaxial and the bilayer lateral tension to vary from bilayer to bilayer. The calculations show that a myelin would bend or coil to lower its free energy when the bilayer lateral tension is sufficiently large. From a mechanical point of view, the proposed coiling mechanism is analogous to the classical Euler buckling of a thin elastic rod under axial compression. The analysis of a simple two-bilayer case suggests that a bilayer lateral tension of about 1 dyne/cm can easily induce coiling of myelins of typical lipid bilayers. This model signifies the importance of bilayer lateral tension in determining the morphology of myelinic structures.     

两种铽配合物与PVK混合体系的发光机理研究

研究了稀土配合物Tb(p-MBA)₃phen(样品Ⅰ)和Tb(p-ClBA)₃phen(样品Ⅱ)与导电聚合物材料PVK掺杂体系的光致发光和电致发光特性。发现在样品Ⅰ与PVK混合薄膜的光致发光中,除了三价铽离子的发光外,还能看到明显的PVK的发光;而在电致发光中,PVK的发光完全被抑制,只能看到Tb3+的绿光发射。对样品Ⅱ与PVK的混合发光层,无论其光致发光谱还是电致发光谱,都没有看到410 nm处PVK的发射。进一步测量两种材料的激发光谱,初步探讨了器件的发光机理。样品Ⅰ的发光可能来源于两个方面,一是PVK到稀土配合物的不完全的能量传递,二是由于载流子俘获机理;样品Ⅱ的发光则是由于PVK到稀土配合物的完全的能量传递。     

Detecting community structure using label propagation with consensus weight in complex network

Community detection is a fundamental work to analyse the structural and functional properties of complex networks.The label propagation algorithm(LPA) is a near linear time algorithm to find a good community structure. Despite various ubsequent advances, an important issue of this algorithm has not yet been properly addressed. Random update orders within the algorithm severely hamper the stability of the identified community structure. In this paper, we executed the asic label propagation algorithm on networks multiple times, to obtain a set of consensus partitions. Based on these onsensus partitions, we created a consensus weighted graph. In this consensus weighted graph, the weight value of the dge was the proportion value that the number of node pairs allocated in the same cluster was divided by the total number f partitions. Then, we introduced consensus weight to indicate the direction of label propagation. In label update steps,y computing the mixing value of consensus weight and label frequency, a node adopted the label which has the maximum mixing value instead of the most frequent one. For extending to different networks, we introduced a proportion parameter o adjust the proportion of consensus weight and label frequency in computing mixing value. Finally, we proposed an pproach named the label propagation algorithm with consensus weight(LPAcw), and the experimental results showed that he LPAcw could enhance considerably both the stability and the accuracy of community partitions.