全文获取类型
收费全文 | 1504篇 |
免费 | 71篇 |
国内免费 | 335篇 |
专业分类
化学 | 1809篇 |
晶体学 | 21篇 |
力学 | 5篇 |
综合类 | 8篇 |
数学 | 1篇 |
物理学 | 66篇 |
出版年
2024年 | 6篇 |
2023年 | 13篇 |
2022年 | 21篇 |
2021年 | 31篇 |
2020年 | 60篇 |
2019年 | 47篇 |
2018年 | 38篇 |
2017年 | 46篇 |
2016年 | 42篇 |
2015年 | 46篇 |
2014年 | 93篇 |
2013年 | 140篇 |
2012年 | 104篇 |
2011年 | 91篇 |
2010年 | 83篇 |
2009年 | 98篇 |
2008年 | 108篇 |
2007年 | 93篇 |
2006年 | 94篇 |
2005年 | 74篇 |
2004年 | 80篇 |
2003年 | 67篇 |
2002年 | 53篇 |
2001年 | 40篇 |
2000年 | 42篇 |
1999年 | 36篇 |
1998年 | 26篇 |
1997年 | 19篇 |
1996年 | 25篇 |
1995年 | 20篇 |
1994年 | 18篇 |
1993年 | 26篇 |
1992年 | 17篇 |
1991年 | 14篇 |
1990年 | 13篇 |
1989年 | 14篇 |
1988年 | 19篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1910条查询结果,搜索用时 0 毫秒
21.
22.
AbstractChemists often use an amine group as an intermediate in syntheses of imines, amides and ureas; however, in the case of syntheses of p-aminophenol type compounds, several problems might occur. In this article, we prepared p-aminocalix[5]arene-pentaol by reduction of both nitro and azo derivatives, and compared four methods of the amine preparation, focusing mainly on its gramme scale and time-consuming issues. 相似文献
23.
采用Pd(OAc)2/[mmim]I催化体系,在不同反应条件下可以将烷基胺、芳香胺及氨基醇(酚)一步转化为氨基甲酸酯、脲和2-噁唑啉酮.N-苯基氨基甲酸甲酯、二苯基脲及苯并-2-噁唑酮的催化转化频率分别为12417,17638和4114h-1. 相似文献
24.
Starting from 1-tert-butyloxycarbonyl-3-methyl-4-ethoxycarbonyl-1,2-diaza-1,3-diene and β,β,β and α,β-substituted enamines a careful choice of solvents and temperatures allows the divergent synthesis of 5,6-dihydro-4H-pyridazines, 2-(1-N-boc-hydrazono-ethyl)-4-pyrrolidin-1-yl-but-3-enoic acid ethyl ester, and 1-amino-pyrroles. Moreover, some interesting conclusions about the mechanism(s) of the reaction have been drawn by careful analysis of products' structure and distribution. Thus, the reaction may proceed through a stereospecific [4+2] cycloaddition mechanism giving rise to 5,6-dihydro-4H-pyridazines or by simple addition or domino addition/cyclization pathways affording, respectively, 2-(1-N-boc-hydrazono-ethyl)-4-pyrrolidin-1-yl-but-3-enoic acid ethyl ester and 1-amino-pyrroles (formally the [3+2] cycloaddition product). 相似文献
25.
Two mononuclear Co(II) complexes based upon 2-(1H-benzimidazol-2-yl)phenol, abbreviation Hsalbim ligand, have been prepared and studied. The structure of Hsalbim and [Co(salbim)2] have been confirmed by X-ray structure analysis. The second cobalt(II) complex matches the formula [Co(salbim)2]·(Hsalbim)·MeOH assuming a co-crystallization of one neutral ligand. The electronic spectra are consistent with the tetrahedral pattern. Magnetic susceptibility measurements down to T = 2 K along with the magnetization data until B = 7 T show that the Co(II) complexes are high-spin with a considerable zero-field splitting of the 4B1(D2d) term: D/hc = 67 and 55 cm−1, respectively. 相似文献
26.
《Journal of Coordination Chemistry》2012,65(13):1115-1125
In a search for environmentally friendly metal chelating ligands for industrial applications, the protonation and complex formation equilibria of N-tris[(1,2-dicarboxyethoxy)ethyl]amine (TCA6) with Ca(II), Mn(II), Cu(II) and Zn(II) ions in aqueous 0.1?M NaCl solution were studied at 25°C by potentiometric titration. A model for complexation and stability constants of the complexes were determined. With all of the metals, complex formation was dominated by ML4?. Comparison of TCA6 and six other chelating agents showed TCA6 to be suitable for applications where strong calcium binding is essential. 相似文献
27.
28.
29.
30.
A new heterocyclic Schiff bases, 6‐methyl/8methyl‐2‐oxo‐1,2‐dihydroquinoline‐3‐carboxaldehyde semicarbazones (H2‐6MOQsc‐H) ( H 2 L 1 ) and (H2‐8MOQsc‐H) ( H 2 L 2 ) and their corresponding copper(II) complexes [CuCl2(H2‐6MOQsc‐H)].3H2O ( 1 ), [CuCl2(H2‐8MOQsc‐H)].3H2O ( 2 ), [CuNO3(H2‐6MOQsc‐H)(H2O)].NO3 ( 3 ) and [CuNO3(H2‐8MOQsc‐H)(H2O)].NO3 ( 4 ) have been synthesized and characterized by various physicochemical techniques. The single crystal X‐ray diffraction and spectral data revealed that all of the complexes ( 1‐4 ), the ligands coordinated to the Cu(II) ion in a neutral manner via ONO donor atoms and all the complexes exhibited distorted squarepyramidal geometry. The consequence of electronegativity and ring size of nitrogen heterocyclic moiety of ONO donor type of copper(II) chelates on nucleic acid interaction and albumin binding was investigated by in vitro experiments. The interaction of compounds with calf‐thymus DNA (CT‐DNA) has been explored by absorption and emission titration, which exposed those ligands/complexes, could bind with CT‐DNA through electrostatic interaction. The results of gel electrophoresis proved the ability of complexes ( 1‐4 ) to cleave the pBR322 plasmid DNA. The interaction of serum albumin (BSA) was investigated by UV‐Vis, fluorescence, synchronous and three dimensional fluorescence spectra. In addition, radical scavenging activity, antifungal activity and cytotoxicity of the newly synthesized compounds were also evaluated. From the results of in vitro studies, it is seen that complex 3 has more potential as compared with other complexes and ligands. 相似文献