荆芥中微量元素的初级形态分析

对荆芥中微量元素铁、铜、锰、锌的初级形态进行了研究,采用火焰原子吸收光谱法（FAAS）测定了各微量元素的含量。结果表明,以HNO3和H2O2混合液作为消解剂能彻底消解样品。各元素在水提液中的含量均低于原药材中的含量,微量元素铁、铜、锰、锌的提取率分别为：19.7%,20.5%,38.6%和34.5%,大部分微量元素仍残留在残渣中。     

微波腔内波混沌散射的初步研究

 通过建立的微波腔模拟产生大量腔体散射矩阵和辐射散射矩阵,并转化得到归一化散射矩阵和阻抗矩阵。利用戴桑环系综对归一化散射矩阵的本征值和本征相位进行了统计分析,其本征值的模和本征相位具有统计独立性,且本征相位近似均一分布,验证了腔体中波混沌散射的存在。对数值模拟和随机矩阵理论预测得到的归一化阻抗的统计特性进行了比较,其结果基本一致,说明随机矩阵理论对归一化阻抗具有一定的预测功能。     

Blends of Aromatic Polyethers Bearing Polar Pyridine Units and Their Evaluation as High Temperature Polymer Electrolytes

Aromatic polyethers containing polar pyridine units in the main chain have been synthesized using different difluoride monomers. Copolymers of 2,5-(4′,4″dihydroxy biphenyl)-pyridine and 3,3′,5,5′-tetramethyl-[1,1′-biphenyl]-4,4′-diol with bis(4-fluorophenyl) sulfone or phenyl phosphine oxide difluoride or decafluorobiphenyl (PTMPySF, PTMPyPO, PTMPyDF) were synthesized. These polymeric structures despite their common structural characteristics, showed totally different behavior in terms of solubility and acid doping ability. Blends of these copolymers have been prepared in order to be evaluated in terms of fuel cell relevant parameters like acid doping ability and conductivity. In most cases flexible membranes were obtained by solution casting. The acid doping ability was controlled based on the blend constituents and composition. The doped membranes exhibited high conductivity values, in the range of 10⁻³ S/cm at room temperature which is increased at 2.5 × 10⁻² S/cm at temperatures up to 180 °C.     

斯特林制冷机驱动控制源电磁兼容分析与改进

介绍了斯特林制冷机驱动控制源的分类,讨论了不同的驱动方式对探测芯片产生的干扰形式,并给出了驱动控制源采取的改进措施.并对驱动控制源与斯特林制冷机联机实验所产生的干扰情况进行了分析,介绍了驱动控制源采取的有效改进措施.     

不同表面性质聚电解质多层膜的制备及蛋白质吸附和血液相容性能

利用层层自组装方法制备了聚烯丙基铵盐酸盐(PAH)/聚苯乙烯磺酸钠(PSS)多层膜. 通过吸附或共价偶联, 在多层膜表面修饰了聚乙二醇(PEG)、牛血清白蛋白(BSA)或肝素, 通过石英晶体微天平(QCM)、椭圆偏振光谱和原子力显微镜(AFM)研究了多层膜的表面形貌及修饰方法对各种蛋白的吸附性能. 经修饰后的多层膜较基底膜的厚度均有所增大; 最外层经修饰后的多层膜吸附的BSA、纤维蛋白原及血浆蛋白的量较未修饰多层膜均有所减少. 采用SEM观察了血小板在多层膜上的黏附情况和形态变化, 计算了血小板的黏附率. 比较各多层膜的凝血酶原时间(PT), 发现修饰后的多层膜的凝血酶原时间均有所延长, 但各组间无显著性差异.     

Relative Stability of closo‐closo,closo‐nido,and nido‐nido Macropolyhedral Boranes: The Role of Orbital Compatibility

The concept of orbital compatibility is used to explain the relative energies of different macropolyhedral structural patterns such as closo‐closo, closo‐nido, and nido‐nido. A large polyhedral borane condenses preferentially with a smaller polyhedron owing to orbital compatibility. Calculations carried out at the B3LYP/6‐31G* level show that the macropolyhedron closo(12)‐closo(6) is the most preferred structural pattern among the face‐sharing closo‐closo systems. The relative stabilities of four‐shared‐atom closo‐closo, three‐shared‐atom closo‐closo, three‐shared‐atom closo‐nido, edge‐sharing closo‐nido, and edge‐sharing nido‐nido structures are in accordance with the difference in the number of vertices of the individual polyhedra of the macropolyhedra. When the difference in the number of vertices of the individual polyhedra is large, the stability of the macropolyhedra is also large. Calculations further show that the orbital compatibility plays an important role in deciding the stability of the macropolyhedral boranes with more than two polyhedral units. The dependence of the orbital compatibility on the relative stability of the macropolyhedron varies with other factors such as inherent stability of the individual polyhedron and steric factors.     

Nonclassical Symmetries for Nonlinear Partial Differential Equations via Compatibility

The determining equations for the nonclassical symmetry reductions of nonlinear partial differential equations with arbitrary order can be obtained by requiring the compatibility between the original equations and the invariant surface conditions. The (2+1)-dimensional shallow water wave equation,
Boussinesq equation, and the dispersive wave equations in shallow water serve as examples illustrating how compatibility leads quickly and easily to the determining equations for their nonclassical symmetries.     

多阶段应急决策的方案链选择方法

针对多阶段不同情景下多指标多任务的应急决策问题,提出了一种方案链选择方法。在该方法中,首先给出了决策方案链的概念,并对多阶段多指标多任务的应急决策问题进行了描述;然后根据相邻阶段的子方案之间的相容性,构建了相容性关系矩阵;进一步地,在考虑相邻阶段子方案之间相容性的情形下,以各阶段的子方案的综合评价值最大为目标,建立了应急决策的方案链选择的优化模型。通过求解模型,得到应急决策的最优方案链。最后,通过一个算例说明了该方法的可行性和有效性。     

基于CdSe@ZnS量子点水溶性纳米粒子的制备及荧光性能

作为一种新型的荧光探针,量子点（QD）已经受到越来越多的重视,制备工艺也显得格外重要。水相中合成的量子点效率低,油相中的量子点经过转相以后效率也大大衰减。本论文利用再沉淀包覆的方法制备了具有良好的水溶性的掺杂绿光CdSe@ZnS的纳米颗粒G-NPs（534 nm）和掺杂红光CdSe@ZnS的纳米颗粒R-NPs（610 nm）,具有窄的半峰宽（G-NPs~29 nm,R-NPs~31 nm）,较小的粒径（45 nm）,并在此基础上通过发射光谱与荧光衰减研究了量子点之间的能量传递现象。该方法保留了量子点原来的性质,基于其优良的光学性质,对人类肝细胞肝癌细胞株（HepG2）进行了荧光标记,从共聚焦成像实验结果看出,纳米颗粒得到了良好的吞噬效果。     

内部窗口结构对开孔矩形腔体近场屏蔽效能的影响

针对开孔屏蔽腔体内置窗口的结构特点,采用扩展的传输线方法理论,建立了电偶极子天线照射下计算近场屏蔽效能的等效电路模型,推导了近似计算解析式,并计算分析了内部窗口结构对开孔腔体近场屏蔽效能的影响.结果表明:含内置窗口结构腔体的近场电场屏蔽效能小于远场屏蔽效能,腔体屏蔽效能随窗口宽度的减小而增大,电感窗口使得腔体谐振频率向上偏移,电容窗口使其谐振频率向下偏移.分析结果与CST仿真结果进行了对比,证实本文采用的等效电路方法是有效的.