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71.
We present results from a computational study of 4-[4-(dimethylamino)-phenylazo] benzene boronic acid (DABBA) (the 4'-boronic acid isomer of the aminoazobenzene dye N,N-dimethylaminoazobenzene) and its associated anion, as well as, several cyclic esters formed from these azoborates and various conformers of D-glucose. Azo dyes that also contain one or more boronic acid functional groups are of practical importance in the development of chemical sensors for saccharide recognition because of their ability to induce a visible color change upon binding. The lowest-energy DABBA:D-glucose esters found in this investigation consistently involved at least one of the exocyclic hydroxymethyl groups on the D-glucose moiety rather than vicinal cis or trans diol arrangements of hydroxyl groups on the ring. 相似文献
72.
The one-electron oxidation of toluidine blue by specific oxidising radicals such as Cl
2
−
, Tl(II), N3, Br
2
−
etc. has been studied by employing the pulse radiolysis technique. The Br
2
−
radical was found to be less efficient in oxidising toluidine blue as compared to Cl
2
−
., Tl+2 and N3. The semioxidised species exhibited only onepK
a indicating the presence of two conjugate acid-base forms whose spectral and kinetic features were evaluated. Reaction of
OH radicals with the dye gave rise to a transient species which exhibited spectral and kinetic features different from that
of the semioxidised species indicating that the mode of reaction of OH is different. 相似文献
73.
Low‐Symmetry Ω‐Shaped Zinc Phthalocyanine Sensitizers with Panchromatic Light‐Harvesting Properties for Dye‐Sensitized Solar Cells
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Satoshi Yamamoto Angel Zhang Prof. Dr. Martin J. Stillman Prof. Dr. Nagao Kobayashi Prof. Dr. Mutsumi Kimura 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18760-18768
Two low‐symmetry phthalocyanines (Pcs) substituted with thiophene units at the non‐peripheral (α) and peripheral (β) positions were synthesized and their optical, electronic‐structure, and electrochemical properties were investigated. The substitution of thiophene units at the α positions of the phthalocyanine skeleton resulted in a red shift of the Q band and significantly modified the molecular‐orbital electronic distributions just below the HOMO and just above the LUMO, with distortion of the typical Gouterman four‐orbital arrangement of MOs. Two amphiphilic Ω‐shaped ZnPcs ( αPcS1 and αPcS2 ) bearing a π‐conjugated side chain with an adsorption site at an α position of the Pc macrocycle were synthesized as sensitizers for dye‐sensitized solar cells (DSSCs). The absorption spectra of αPcS1 and αPcS2 showed red shifted Q bands and a broad band from 350 to 550 nm assignable to the intramolecular charge‐transfer transition from the ZnPc core to the side chains. Time‐dependent DFT calculations provided a clear interpretation of the effect of the thiophene conjugation on the typical phthalocyanine core π MOs. Compound αPcS1 was used as a light‐harvesting dye on a TiO2 electrode for a DSSC, which showed a panchromatic response in the range 400–800 nm with a power conversion efficiency of 5.5 % under one‐sun conditions. 相似文献
74.
Frontispiece: Glycoluril‐Derived Molecular Clips are Potent and Selective Receptors for Cationic Dyes in Water
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75.
Vincent Martinez Prof. Dr. Maged Henary 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(39):13764-13782
Nile red and Nile blue are highly fluorescent and photostable organic dyes from the benzo[a]phenoxazine family. They have been used as histological stains for imaging lysosomes and lipids in vitro. The dyes’ high quantum yields and solvent‐dependent optical properties make them ideal scaffolds for the development of pH probes and local polarity indicators. Reviews of the literature in this area are scarce with only one review ever published in 2006. It has been 10 years since and the field has evolved. This review aims to expand upon topics covered by the previous reviewers and to report on recent advances in the literature. As authors, we hope to convey a sense of scope and to spark renewed interest in this useful niche of dye chemistry. 相似文献
76.
Dr. Vladimir Stepanenko Dr. Xue‐Qing Li Jana Gershberg Prof. Dr. Frank Würthner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(13):4176-4183
The self‐assembly behavior of an achiral perylene bisimide (PBI) organogelator that bears two 3,4,5‐tridodecyloxybenzoylaminoethyl substituents at the imide positions has been investigated in chiral solvents (R)‐ and (S)‐limonene in great detail by circular dichroism (CD) spectroscopy and atomic force microscopy (AFM). CD spectroscopic studies on dilute solutions revealed a preferential population of one‐handed helical assemblies in chiral solvent with an enantiomeric excess close to 100 %, whereas AFM images of more than 100 nanofibers of the organogel obtained from more concentrated solutions were found to consist of both handed helices with an enantiomeric excess of only 20 %. This discrepancy is attributed to the fast gelation process at high dye concentration that evidently proceeds through non‐equilibrated nuclei in a kinetic rather than thermodynamic self‐assembly process. Under these conditions the chiral induction from the homochiral solvent may not be adequate in effectively populating only one‐handed helices. 相似文献
77.
Dr. Eduard Baal Marius Klein Dr. Klaus Harms Prof. Dr. Jörg Sundermeyer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(49):12610-12618
The synthesis of 2,9-diaza-1,3,8,10-tetratriflato-dibenzoperylene (DDP 3 a ) and corresponding 2,9-dimethyl-1,3,8,10-tetratriflato-dibenzoperylene (DBP 3 b ) has been developed at multigram scale via reduction of one of the industrially most important high-performance dyes, perylene-3,4,9,10-tetracarboxylic diimide (PTCDI), and of the corresponding dihydroxy peropyrenequinone precursor. The focus of this paper is on the reactivity pattern of 3 a as key intermediate towards highly functionalized 2,9-diazadibenzopyrelenes (DDPs) obtained via catalytic substitution of four triflate by aryl, heteroaryl, alkynyl, aminyl, and O-phosphanyl substituents. The influence of electron-donating substituents (OSiMe3, OPt-Bu2, N-piperidinyl), electron-withdrawing (OTf, 3,5-bis-trifluoromethyl-phenyl), and of electron-rich π-conjugated (2-thienyl, 4-tert-butylphenyl, trimethylsilyl-ethynyl) substituents on optoelectronic and structural properties of these functionalized DDPs has been investigated via XRD analyses, UV/Vis, PL spectroscopy, and by electroanalytical CV. These results were correlated to results of DFT and TD-DFT calculations. Thus, functionalized DPPs with easily tunable HOMO and LUMO energies and gap became available via a new and reliable synthetic strategy starting from readily available PTCDI. 相似文献
78.
Georgy M. Pavlov Anke Teichler Stephanie Höppener Christine Weber Jürgen Nowotny Lars Blankenburg Jürgen Popp Martin D. Hager Benjamin Dietzek Ulrich S. Schubert 《Journal of polymer science. Part A, Polymer chemistry》2012,50(15):3192-3205
In order to form suitable systems designed for resonance energy transfer, a series of monodisperse methacrylate‐based monomers containing rigid π‐conjugated oligo(phenylene ethynylenes) with different sizes of the conjugated systems ( M1 – M3 ), and therefore different optoelectronic properties, were synthesized and subsequently polymerized using the reversible addition–fragmentation chain transfer polymerization technique ( P1 – P3 ). In addition, these oligomers were also copolymerized with methyl methacrylate. The obtained polymers were characterized by 1H NMR spectroscopy, size exclusion chromatography, and analytical ultracentrifugation. The photophysical properties of the polymers were studied by UV–vis absorption and emission spectroscopy in diluted solutions as well as in thin films and compared to the photophysics of the corresponding monomers. Thereby, changes going from monomeric to polymeric systems could be detected in fluorescence quantum yields and lifetimes pointing to energy trapping, e.g., energy transfer. Donor–acceptor copolymers containing different numbers of monomeric units within the side chain exhibit differences in the emission spectra, indicating that energy trapping in polymers is very sensitive to structural properties such as the chain length. UV–vis absorption spectroscopy as well as time‐resolved lifetime studies indicate intrapolymer and interpolymer energy transfer. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
79.
Ultrasmall Superparamagnetic Iron Oxide Nanoparticles with Europium(III) DO3A as a Bimodal Imaging Probe
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Dr. Sophie Carron Dr. Maarten Bloemen Prof. Luce Vander Elst Prof. Sophie Laurent Prof. Thierry Verbiest Prof. Tatjana N. Parac‐Vogt 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(13):4521-4527
A new prototype consisting of ultrasmall superparamagnetic iron oxide (USPIO) nanoparticles decorated with europium(III) ions encapsulated in a DO3A organic scaffold was designed as a platform for further development of bimodal contrast agents for MRI and optical imaging. The USPIO nanoparticles act as negative MRI contrast agents, whereas the europium(III) ion is a luminophore that is suitable for use in optical imaging detection. The functionalized USPIO nanoparticles were characterized by TEM, DLS, XRD, FTIR, and TXRF analysis, and a full investigation of the relaxometric and optical properties was conducted. The typical luminescence emission of europium(III) was observed and the main red emission wavelength was found at 614 nm. The relaxometric study of these ultrasmall nanoparticles showed r2 values of 114.8 mm ?1Fes?1 at 60 MHz, which is nearly double the r2 relaxivity of Sinerem®. 相似文献
80.
LDH/Tris/Pd (CaAl‐layered double hydroxide/tris (hydroxymethyl)aminomethane/palladium) was synthesized and appraised for its catalytic activity towards the degradation of two selected azo dyes. The decolorization of azo dyes, acid red 18 (AR 18) and reactive yellow 15 (RY 15), requires considerably small amounts of synthesized catalyst. Kinetic studies show that the catalytic decolorization of these azo dyes follows the first order kinetic model. The reported method is simple and applicable; in addition, the stable catalyst can efficiently decolorize model azo dyes with good recyclability. Therefore, LDH/Tris/Pd can be accepted as the possible component for the utilization in wastewater treatment. 相似文献