2-乙酰氨基-3-苯基-N-苯基-丙烯酰胺衍生物的电子轰击质谱研究

本文报道了6种新的丙烯酰胺衍生物的EI谱。在精确质量测量和B/E,B~2/E联动扫描亚稳离子测定的基础上,着重讨论了该类化合物的共同质谱特征:如分子离子失去H_2O的成环反应;产物离子的开环反应;分子内的氢重排反应等。同时,利用Hammett方程讨论了化合物中N-苯基端苯环上不同取代基对特定碎片离子强度的影响     

基于软件接收机的卫星导航信号模拟器性能指标测试

针对卫星导航信号模拟器的性能指标测试评估问题,提出了基于软件接收机的性能指标测试方法;通过分析模拟器性能,包括对动态性能、相位噪声、通道间时延一致性和静态定位精度的综合分析,给出了相应的测试方法和测试流程,并结合卫星导航信号模拟器产生的实际信号对各项性能指标的测试结果进行分析;经测试结果表明,软件接收机可以有效地对卫星导航信号模拟器各项性能指标进行测试,测试结果符合理论预期,满足模拟器性能指标测试评估的需求。     

Representations of Some Hopf Algebras Associated to the Symmetric Group S n

We prove that all irreducible representations of the bismash product have Frobenius–Schur indicator +1, where k is an algebraically closed field of characteristic 0. If n = p, a prime, we find all indicators for . We also study more general bismash products. Both authors were supported by NSF grants DMS-07-01291 and DMS-04-01399.     

Fluorescent pH Indicator. Spectral Changes of 4-Methylumbelliferone

Abstract

4-Methylumbelliferone is a useful acid-base fluorescent indicator with a midpoint of its transition interval at pH 7.6. Both anionic and neutral forms fluoresce in the blue with high quantum yield (70%). The indicator properties are based on a blue shift of the absorption spectrum in acid. Depending on the excitation wavelength employed, one has the option of following either an increase or a decrease in fluorescence as the pH changes.     

Versatile reactions of a para-bromophenylacetylide iron(II) derivative and X-ray structure of the fluoro analogue. Synthesis of new redox-active organoiron(II) synthons

The synthesis of the new (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,3-(C₆H₄X) (m-2a/2b; X=F/Br) and (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄I) (2c) complexes, as well as the solid-state structure of the known (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄F) (2a) complex are described. The catalytic coupling reactions of the bromo complexes with various alkynes were next investigated. Starting from the known (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄Br) complex (2b), the synthesis of the (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄)---CC---H complex (6d) and of the corresponding silyl-protected precursors (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄)CC---SiR₃ (6b/6c; R=ⁱPr/Me) are reported. By use of lithium---bromine exchange reactions on 2b, the silyl- (7a; E=Si; R=Me) and tin- (7b–7d; E=Sn; R=Me, Bu, Ph) substituted analogues (η²-dppe)(η⁵-C₅Me₅)Fe---CC---1,4-(C₆H₄)ER₃ are also isolated. The spectroscopic and electrochemical characterisations of all these new Fe(II)/Fe(III) redox-active building blocks are presented and the electronic substituent parameters for the “(η²-dppe)(η⁵-C₅Me₅)Fe---CC” group are determined by means of ¹⁹F-NMR.     

电化学DNA传感器的研制及其医学应用

对近几年发展起来的电化学DNA传感器的研究工作进行了讨沦,详细论述了该类传感器的工作原理、探针固定化技术、杂交指示剂的类型以及在基因诊断、药物分析等方面的医学应用,并展望了应用前景和发展方向。     

基于支持向量回归的豆油期货数据分析

随着期货市场在经济中的影响逐渐增强,对期货市场的研究具有实际意义.选取豆油期货指数进行研究,首先将数据进行归一化处理,然后选用支持向量回归方法建模分析.分析结果表明该方法对短期内的数据预测具有较好的效果,对了解期货市场的近期走势提供一些借鉴.