全文获取类型
收费全文 | 1677篇 |
免费 | 202篇 |
国内免费 | 310篇 |
专业分类
化学 | 1538篇 |
晶体学 | 92篇 |
力学 | 38篇 |
综合类 | 9篇 |
数学 | 3篇 |
物理学 | 509篇 |
出版年
2024年 | 3篇 |
2023年 | 16篇 |
2022年 | 39篇 |
2021年 | 36篇 |
2020年 | 43篇 |
2019年 | 56篇 |
2018年 | 46篇 |
2017年 | 58篇 |
2016年 | 66篇 |
2015年 | 52篇 |
2014年 | 75篇 |
2013年 | 173篇 |
2012年 | 121篇 |
2011年 | 105篇 |
2010年 | 108篇 |
2009年 | 105篇 |
2008年 | 113篇 |
2007年 | 131篇 |
2006年 | 110篇 |
2005年 | 87篇 |
2004年 | 100篇 |
2003年 | 86篇 |
2002年 | 45篇 |
2001年 | 34篇 |
2000年 | 36篇 |
1999年 | 38篇 |
1998年 | 44篇 |
1997年 | 37篇 |
1996年 | 43篇 |
1995年 | 34篇 |
1994年 | 22篇 |
1993年 | 27篇 |
1992年 | 19篇 |
1991年 | 16篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 2篇 |
排序方式: 共有2189条查询结果,搜索用时 15 毫秒
61.
An improved, mild procedure for the CuI‐catalyzed coupling reactions of aryl iodides with aliphatic and aromatic thiols, using L ‐proline as the ligand, is reported. This procedure is noteworthy given its high generality and exceptional level of functional group toleration. 相似文献
62.
Rahman Hosseinzadeh Mahmood Tajbakhsh Maryam Mohadjerani Parizad Rezaei Mohammad Alikarami 《合成通讯》2013,43(17):3023-3031
An efficient synthesis of diaryl ethers by the copper-catalyzed arylation of phenols with a variety of aryl iodide susing KF/Al2O3 as a suitable base and CuI and 1,3 diphenyl-1,3 propandione as the catalyst is described. 相似文献
63.
An ultrasound‐accelerated fast and efficient three‐component reaction for the regioselective synthesis of l,4‐disubstituted 1,2,3‐triazoles using different alkyl and allyl halides, terminal alkynes, and sodium azide in water at room temperature has been developed using CuI as catalyst. Ultrasonication dramatically decreases the reaction times. 相似文献
64.
The reaction of 2-amino-1-(2-propynyl)pyridinium bromide with various iodobenzenes, catalyzed by Pd-Cu, in the presence of sodium lauryl sulfate as the surfactant and cesium carbonate as the base, in water, leads to the formation of 2-substituted imidazo[1,2-α]pyridines. 相似文献
65.
Easily prepared choline iodide is an active catalyst for the synthesis of cyclic carbonates through the coupling reaction of CO2 and epoxides using low pressure (1 MPa), moderate temperature (85 ºC) and green solvents (ethanol and propan-2-ol). The effects of reaction temperature, pressure, reaction time and amount of catalyst used were also investigated. The results showed moderate to high yields and excellent selectivities of cyclic carbonates with vinyl or acrylate groups under mild reaction conditions. The heterogenization of choline over a Merrifield resin gives access to a supported catalyst with good recyclability and reactivity that can be extended to a variety of terminal epoxide substrates. 相似文献
66.
Dr. Benjamin Frank Dr. Thomas P. Cotter Dr. Manfred E. Schuster Prof. Dr. Robert Schlögl Dr. Annette Trunschke 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(50):16938-16945
The effect of the gas‐phase chemical potential on surface chemistry and reactivity of molybdenum carbide has been investigated in catalytic reactions of propane in oxidizing and reducing reactant mixtures by adding H2, O2, H2O, and CO2 to a C3H8/N2 feed. The balance between surface oxidation state, phase stability, carbon deposition, and the complex reaction network involving dehydrogenation reactions, hydrogenolysis, metathesis, water‐gas shift reaction, hydrogenation, and steam reforming is discussed. Raman spectroscopy and a surface‐sensitive study by means of in situ X‐ray photoelectron spectroscopy evidence that the dynamic formation of surface carbon species under a reducing atmosphere strongly shifts the product spectrum to the C3‐alkene at the expense of hydrogenolysis products. A similar response of selectivity, which is accompanied by a boost of activity, is observed by tuning the oxidation state of Mo in the presence of mild oxidants, such as H2O and CO2, in the feed as well as by V doping. The results obtained allow us to draw a picture of the active catalyst surface and to propose a structure–activity correlation as a map for catalyst optimization. 相似文献
67.
68.
One-pot synthetic strategy has been developed to access isoquinolines and its analogs via Cu-mediated tandem cross-coupling and cyclization in good yields under mild reaction conditions. A mixture of suitably substituted α-bromoaldehyde, terminal alkyne, and aq NH3 in CuI/1,10-phenanathroline catalytic system afforded the 3-substituted isoquinoline regio-selectively in good to excellent yields. 相似文献
69.
In the present work a modular pathway towards the synthesis of a new versatile MRI contrast agent is reported and its physico-chemical properties are described. Two different functional groups were attached on two arms of the gadolinium 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetate (DOTA) in order to get a platform able to bind one probe designed to target specific biological marker and a fluorescent molecule likely to be used for optical imaging. The nuclear magnetic relaxation dispersion (NMRD) profile, the oxygen-17 relaxometric NMR study and stability assessment versus transmetalation of the Gd-complex show that this new contrast agent has a relaxivity and transmetalation stability similar to Gd–DOTA. 相似文献
70.
Nickel(I) complexes were generated in situ from Ni (PPh3)2Cl2 using activated iron and the complexes combined with N,N′-bis(4-fluorobenzylidene) ethane-1,2-diamine (BFBED) were then used as a catalyst for the 1,4-addition reaction of arylboronic acids to α,β-unsaturated substrates. The reaction proceeded to completion and did not require the addition of a base but the addition of potassium iodide is crucial to this cross-coupling reaction. Moreover, experimental observations suggested a possible Ni(I)–Ni(III) catalytic cycle mechanism. 相似文献