三磷酸胞苷在Duolite A-30树脂上的交换过程研究

根据CTP在离子交换树脂上的吸附容量和分离因数的大小,确定Duolite A-30树脂适合CTP与CDP,CMP之间的分离.对CTP在Duolite A-30树脂上的吸附动力学和热力学研究表明,在283.15K~303.15K之间,CTP的质量浓度在7.5g/L以上时,Duolite A-30树脂对CTP的吸附主要受颗粒扩散的控制,其有效扩散系数为D=3.47×10-7cm2/s,溶液的质量浓度≤1.0g/L时,CTP与Duolite A-30树脂之间的交换速率主要受液膜控制,其液膜扩散系数为Kf =4.112×10-4/s.同时测定了不同条件下三磷酸胞苷溶液在Duolite A-30树脂固定床离子交换柱中的穿透曲线,研究了进口浓度、进口流速、原料液温度、原料液的pH值及柱高对穿透曲线的影响.用二阶动力学推动力模型描述固定床动态过程,考察了轴向返混对穿透曲线的影响,并从穿透曲线回归得到总传质系数,模型计算值与实验数据符合良好.     

催化裂化汽油脱硫添加剂USY/ZnO/Al2O3的性能评价

 在固定流化床催化裂化装置上，以减压蜡油为原料，对制备的U\r\nSY／ZnO／Al2O3催化裂化汽油脱硫添加剂的性能进行了评价．结果表明\r\n，随着添加剂添加量和剂油比的增加，生成汽油的硫含量降低．在500\r\n℃和剂油比为5的条件下，在FCC平衡催化剂中添加30％的添加剂时，汽\r\n油的硫含量可由不加添加剂时的1230μg／g降低到770μg／g左右．添\r\n加剂的添加量（10％）较低时，对催化裂化产物的分布基本没有影响；\r\n添加30％的添加剂时，焦炭的产率有所增加，但汽油收率基本不变．X\r\nRD表征结果表明，USY／ZnO／Al2O3添加剂中的ZnO对USY的晶相结构有\r\n一定的破坏作用，但随着反应与再生次数的增多，ZnO与Al2O3之间形成\r\n较为稳定的锌铝尖晶石结构，使添加剂的性能趋于稳定．     

钾（Ⅰ）（苯并－15－冠－5）新型配合物的合成及性质

在非水溶剂中合成了苯并－１５－冠－５与碘化钾、硫氰化钾及苦味酸钾形成的三种新型固体配合物，并进行了有关物理、化学性质表征．结果表明，钾（Ⅰ）离子不仅易与苯并－１５－冠－５形成常见的１：２夹心式配合物，而且还能生成稳定的１：１型固体配合物．     

Equilibrium polymerization in a solvent: Solution on the Bethe lattice

The lattice model for equilibrium polymerization in a solvent proposed by Wheeler and Pfeuty is solved exactly on a Bethe lattice (core of a Caylay tree) with general coordination numberq. Earlier mean-field results are reobtained in the limitq, but the phase diagrams show deviations from them for finiteq. Whenq=2, our results turn into the solution of the one-dimensional problem. Although the model is solved directly, without the use of the correspondence between the equilibrium polymerization model and the diluten0 model, we verified that the latter model may also be solved on the Bethe lattice, its solution being identical to the direct solution in all parameter space. As observed in earlier studies of the puren0 vector model, the free energy is not always convex. We obtain the region of negative susceptibility for our solution and compare this result with mean field and renormalization group (-expansion) calculations.     

无机胺合成ZSM-5沸石的结构表征和催化作用

分别以氨水和正丙胺为模板剂 ,在 177℃温度下静止晶化 5 0小时 ,合成出ZSM - 5沸石分子筛 .经XRD和IR测试 ,两者具有基本相同的结构 ;TG -DSC分析证明 ,两者都具有优良的热稳定性 .由于有机胺易氧化分解 ,故使得后者的腔内包含物氧化放热峰前移约 4 0℃ .合成的ZSM - 5沸石经用不同离子交换后 ,用于催化己烷芳构化反应     

Evaluation of the stability and analysis of halogenated furanones in disinfected drinking waters

A refined method for the sub-nanomolar analysis of 13 halogenated furanones in chlorinated drinking water is proposed which uses liquid-liquid extraction, methylation where necessary, gas chromatographic separation, and either micro-electron capture or ion trap mass spectrometric detection. Liquid-liquid extraction with methyl tert-butyl ether was demonstrated to be effective for recovery of halogenated furanones. Confirmation of the halogenated furanones identity and reduction of natural organic matter interference were achieved by ion trap tandem mass spectrometry. Compound stabilities and procedural efficiencies were evaluated to permit optimization of the method for reasonable sample volumes and a 1000:1 pre-concentration factor that would permit feasible sample collection in the field. Both chlorinated and brominated analogues of MX (3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone) were included in a suite of compounds targeted in a national occurrence study of disinfection by-products.     

3,4—二乙酰基—2,5—己二酮与取代苯胺及水合肼的反应

以乙酰丙酮（１）的电氧化偶联产物３，４－二乙酰基－２，５－己二酮（２）为原料，在酸性介质中与取代苯胺（３ａ￣３ｇ）作用，得到１，４－二羰基的缩合产物２，５－二甲基－３，４－二乙酰基－１－芳基吡咯（４ａ￣４ｇ）。在相似的条件下，２与水合肼作用，则得到１，３－二羰基的缩合产物３，３＇，５，５＇－四甲基－１，１＇－二氢－４，４＇－联吡唑（５）。     

Electrochemical characteristics of Ce0.8Gd0.2O1.9|La0.6Sr0.4CoO3-δ + Ce0.8Gd0.2O1.9 half-cell

The analysis of the medium temperature half-cell Ce_0.8Gd_0.2O_1.9|70 wt% La_0.6Sr_0.4CoO_3- (LSCO) + 30 wt % Ce_0.8Gd_0.2O_1.9 (CGO) has been made by electrochemical impedance, cyclic voltammetry and chronoamperometry. The shape of complex impedance plots depends on temperature and cathodic polarisation of the electrode. Nyquist (Z, Z-) plots were fitted by equivalent circuit taking into account the electrolyte properties (at very high frequencies), charge transfer process at grain boundaries (at high frequencies), and medium and low frequency O₂ reduction process at the cathode surface and inside the porous cathode material. Two different time constants have been obtained for the cathode process, i.e. for electroreduction of oxygen. It was found that the addition of CGO into the cathode material (LSCO) only somewhat decreases the surface catalytic activity but the noticeably higher low-frequency resistance (i.e. mainly diffusion-like mass transfer resistance R_D) values at lower temperatures have been calculated. It was found that the mainly bulk diffusion-limited process at T773 K deviates toward the kinetically mixed process (diffusion + charge transfer) with increasing temperature.     

锆(Ⅳ)同7-碘-8-羟基喹啉-5-磺酸三元混配化合物的形成及其荧光光度研究

在 EDTA 存在下,Zr(Ⅵ)与 H_2QSI 在 pH6.0时形成三元荧光配合物。其组成为Zr:H_2QSI:EDTA=1:1:1。荧光强度与锆离子在0.1～1.0μg/10ml 范围内呈现线性关系。对EDTA 的作用机理作初步探讨。