Hydrodynamics of a particle impact on a wall

The problem of a particle impacting on a wall, a common phenomenon in particle-laden flows in the minerals and process industries, is investigated computationally using a spectral-element method with the grid adjusting to the movement of the particle towards the wall. Remeshing is required at regular intervals to avoid problems associated with mesh distortion and the constantly reducing maximum time-step associated with integration of the non-linear convective terms of the Navier–Stokes equations. Accurate interpolation between meshes is achieved using the same high-order interpolation employed by the spectral-element flow solver. This approach allows the full flow evolution to be followed from the initial approach, through impact and afterwards as the flow relaxes. The method is applied to the generic two-dimensional and three-dimensional bluff body geometries, the circular cylinder and the sphere. The principal case reported here is that of a particle colliding normally with a wall and sticking. For the circular cylinder, non-normal collisions are also considered. The impacts are studied for moderate Reynolds numbers up to approximately 1200. A cylindrical body impacting on a wall produces two vortices from its wake that convect away from the cylinder along the wall before stalling while lifting induced wall vorticity into the main flow. The situation for a sphere impact is similar, except in this case a vortex ring is formed from the wake vorticity. Again, secondary vorticity from the wall and particle plays a role. At higher Reynolds number, the secondary vorticity tends to form a semi-annular structure encircling the primary vortex core. At even higher Reynolds numbers, the secondary annular structure fragments into semi-discrete structures, which again encircle and orbit the primary core. Vorticity fields and passive tracer particles are used to characterize the interaction of the vortical structures. The evolution of the pressure and viscous drag coefficients during a collision are provided for a typical sphere impact. For a Reynolds number greater than approximately 1000 for a sphere and 400 for a cylinder, the primary vortex core produced by the impacting body undergoes a short-wavelength instability in the azimuthal/spanwise direction. Experimental visualisation using dye carried out in water is presented to validate the predictions.     

Study of Hopficity in Certain Classes of Rings

The main results proved in this paper are:

1. For any non-zero vector space V _Dover a division ring D, the ring R= End(V _D) is hopfian as a ring

2. Let Rbe a reduced π-regular ring &; B(R) the boolean ring of idempotents of R. If B(R) is hopfian so is R.The converse is not true even when Ris strongly regular.

3. Let Xbe a completely regular spaceC(X) (resp. C ^?(X)) the ring of real valued (resp. bounded real valued) continuous functions on X. Let Rbe any one of C(X) or C ^?(X). Then Ris an exchange ring if &; only if Xis zero dimensional in the sense of Katetov. for any infinite compact totally disconnected space X C(X) is an exchange ring which is not von Neumann regular.

4. Let Rbe a reduced commutative exchange ring. If Ris hopfian so is the polynomial ring R[T ₁,…,T _n] in ncommuting indeterminates over Rwhere nis any integer ≥ 1.

5. Let Rbe a reduced exchange ring. If Ris hopfian so is the polynomial ring R[T].     

On finitely embedded rings

A result of Ginn and Moss asserts that a left and right noetherian ring with essential right socle is left and right artinian. There are examples of right finitely embedded rings with ACC on left and right annihilators which are not artinian. Motivated by this, it was shown by Faith that a commutative, finitely embedded ring with ACC on annihilators (and square-free socle) is artinian (quasi-Frobenius). A ring R is called right minsymmetric if, whenever k R is a simple right ideal of R, then R k is also simple. In this paper we show that a right noetherian right minsymmetric ring with essential right socle is right artinian. As a consequence we show that a ring is quasi-Frobenius if and only if it is a right and left mininjective, right finitely embedded ring with ACC on right annihilators. This extends the known work in the artinian case, and also extends Faith's result to the non-commutative case.     

On Chow Groups of G-Graded Rings

Abstract

Let A be a Noetherian ring graded by a finitely generated Abelian group G. It is shown that a Chow group A _?(A) of A is determined by cycles and a rational equivalence with respect to certain G-graded ideals of A. In particular, A _?(A) is isomorphic to the equivariant Chow group of A if G is torsion free.     

多级离心泵内叶轮出口压力脉动研究

为研究瞬态工况下离心泵叶轮出口处的压力脉动情况,为离心泵泄漏流道流动提供边界条件,建立了包含叶轮和导叶流道的离心泵模型,基于CFD方法计算得到了其在不同工况下的性能参数,利用测试数据对结果进行了验证。分析了瞬态工况下叶轮出口处压力的变化趋势,比较了不同工况对叶轮出口压力脉动的影响,发现叶轮出口压力随叶轮旋转呈周期性变化,压力脉动频率与转速及叶轮数量有关;偏工况时叶轮出口压力脉动趋势与额定工况基本一致,但脉动频率及脉动幅值有较大区别;随离心泵转速增加,叶轮出口处压力脉动的最大值和最小值均呈减小趋势,但幅值随转速增加而增加,且增幅明显。     

Catalytic Borylative Opening of Propargyl Cyclopropane,Epoxide, Aziridine,and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates

A new copper‐catalyzed reaction for the stereo‐ and regioselective synthesis of alkenyl diboronates and allenyl boronates is presented. In this process propargyl derivatives of strained three/four‐membered rings were employed as substrates and B₂pin₂ was used as the boronate source. Selective formation of the alkenyl diboronate versus the allenyl boronate products was controlled by the choice of phosphine ligand.     

三元硼氮环的电子结构与成键

用从头算ＳＣＦ－ ＭＯ法对三元硼氮环２ 个系列８ 个分子的电子结构进行了研究．根据计算结果,由原子的轨道布居以及σ和π电子的分布,讨论了硼原子与氮原子间的成键情况．结果表明,硼原子和氮原子上加Ｈ 有利于环的稳定,同时削弱了Ｂ—Ｎ 键而增强了Ｂ—Ｂ键和Ｎ—Ｎ 键,对Ｂ２Ｎ 系列和ＢＮ２ 系列中的Ｂ原子和Ｎ 原子的净电荷的影响恰好相反．     

Multicomponent Reactions of Furan‐2,3‐diones: Synthesis and Characterizations of Furo[3,2‐c]pyran‐4‐ones

Furo[3,2‐c]pyran‐4‐ones, which possess a natural‐product skeleton, are synthesized via a simple, one‐pot, three‐component reaction of furan‐2,3‐diones with dialkyl acetylenedicarboxylates and Ph₃P.