全文获取类型
收费全文 | 18158篇 |
免费 | 1549篇 |
国内免费 | 2561篇 |
专业分类
化学 | 19210篇 |
晶体学 | 55篇 |
力学 | 340篇 |
综合类 | 65篇 |
数学 | 998篇 |
物理学 | 1600篇 |
出版年
2024年 | 25篇 |
2023年 | 126篇 |
2022年 | 252篇 |
2021年 | 345篇 |
2020年 | 621篇 |
2019年 | 537篇 |
2018年 | 424篇 |
2017年 | 588篇 |
2016年 | 745篇 |
2015年 | 659篇 |
2014年 | 744篇 |
2013年 | 1583篇 |
2012年 | 965篇 |
2011年 | 1054篇 |
2010年 | 979篇 |
2009年 | 1086篇 |
2008年 | 1237篇 |
2007年 | 1304篇 |
2006年 | 1173篇 |
2005年 | 1052篇 |
2004年 | 1071篇 |
2003年 | 831篇 |
2002年 | 708篇 |
2001年 | 537篇 |
2000年 | 488篇 |
1999年 | 429篇 |
1998年 | 405篇 |
1997年 | 363篇 |
1996年 | 312篇 |
1995年 | 276篇 |
1994年 | 286篇 |
1993年 | 285篇 |
1992年 | 230篇 |
1991年 | 117篇 |
1990年 | 93篇 |
1989年 | 66篇 |
1988年 | 56篇 |
1987年 | 45篇 |
1986年 | 28篇 |
1985年 | 22篇 |
1984年 | 27篇 |
1983年 | 17篇 |
1982年 | 22篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 11篇 |
1978年 | 5篇 |
1973年 | 4篇 |
1972年 | 3篇 |
1970年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
A. Y. M. Chin 《Acta Mathematica Hungarica》2004,102(4):337-342
Let R be an associative ring with unit and let N(R) denote the set of nilpotent elements of R. R is said to be stronglyπ-regular if for each x∈R, there exist a positive integer n and an element y∈R such that x
n=x
n
+1
y and xy=yx. R is said to be periodic if for each x∈R there are integers m,n≥ 1 such that m≠n and x
m=x
n. Assume that the idempotents in R are central. It is shown in this paper that R is a strongly π-regular ring if and only if N(R) coincides with the Jacobson radical of R and R/N(R) is regular. Some similar conditions for periodic rings are also obtained.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
82.
利用传统自由基聚合法,在四氢呋喃溶液中自由基引发聚合甲基丙烯酸丁酯单体而得到ω-羧基-甲基丙烯酸丁酯低聚物(CTBMA)(分子量在1500左右);利用CTBMA末端酯基的反应特性,在二氧六环/水/KOH混合溶液中皂化CTBMA,使之转化为α,ω-羧基甲基丙烯酸丁酯低聚物(di-CTBMA);研究了溶剂的类别、反应时间等反应条件对皂化产物结构的影响;利用MALDI-TOF-MS及LSIMS对皂化各阶段产物进行了分析监测.实验表明,在适当的皂化条件下,CTBMA皂化时主要为末端酯基转化为羧基,相应得到的产物di-CTMBA具有很好的结构特性,其官能团度(functionality)接近2. 相似文献
83.
A. V. Pastukhov V. A. Davankov E. V. Sidorova E. I. Shkol’nikov V. V. Volkov 《Russian Chemical Bulletin》2007,56(3):484-493
An automated procedure was developed for monitoring fast changes in the size of spherical samples of polymers during their
contact with a solvent or drying. The kinetics of bulk deformation in these processes was studied for a series of cross-linked
polymers, viz., gel-type and porous styrene—divinylbenzene copolymers and poly(divinylbenzenes), and hypercrosslinked polystyrenes. Gel,
macroporous, and hypercrosslinked polystyrenes are substantially different in the rate, mechanism, and degree of swelling,
which is associated with the principal differences in their physical structures. An unusual effect of a sharp decrease followed
by a temporary increase in the volume of porous polystyrene and poly(divinylbenzene) materials were observed during desorption
(evaporation) of organic solvents. Water desorption is accompanied by an excessive bulk compression of porous granules giving
rise to negative deformations, which gradually relax to the state equilibrium for the dry polymer. The results of dynamic
desorption porometry (for water desorption) are indicative of a bimodal size distribution of micropores in hypercrosslinked
polystyrene.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 467–476, March, 2007. 相似文献
84.
We prove that three automorphisms of the rooted binary tree defined by a certain 3-state automaton generate a free non-Abelian
group of rank 3.
Both authors are supported by the NSF grants DMS-0308985 and DMS-0456185. Yaroslav Vorobets is supported by a Clay Research
Scholarship. 相似文献
85.
ADegenerateStefanProblemwithTwoFreeBoundaries¥(李辉来)LiHuilai(DepartmentofMathematics,JilinUniversity,Changchun,130023)Abstract... 相似文献
86.
E. Sh. Finkel'shtein N. V. Ushakov N. A. Pritula E. A. Andreev N. A. Platé 《Russian Chemical Bulletin》1992,41(1):185-187
The thermally initiated and platinum-catalyzed polymerization of 1-silacyclobutanes with substitutents containing a trimethylsilyl group was carried out. Soluble, high-molecular-weight, heterochain siltrimethylene polymers were obtained, containing trimethylsilyl groups removed from the main chain by various bridges.A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 223–225, January, 1992. 相似文献
87.
88.
Two types of optical current transducers (OCTs) have a bulk Faraday sensor inserted into the gap of an iron core and a porcelain
insulator with optical fiber. The sensor consists of Bi12SiO20 (BSO) single crystal, a polarizer, and an analyzer. The OCTs satisfied the target performance requirement for fault location
and metering and demonstrated maintained performance at some power utilities in Japan and the US. We have developed a fault
location system that immediately detects the fault current with the OCTs, there by locating the fault section. The OCT can
easily replace the existing support insulators for the disconnecting switch without any modifications to structure height
or bus-bar. For metering requiring 0.3% class accuracy, use of a BSO with right optical rotatory power combined with BSO with
left optical rotatory power results in a Faraday sensor with improved temperature characteristics. The OCT demonstrated 0.3%
class accuracy for metering described in the current transformer Specifications of IEEE C57–13, 1993. 相似文献
89.
A. Gorban' 《Mathematical and Computer Modelling》2002,35(13):7047-1370
An explicitly solvable Riabouchinsky model with a partially penetrable obstacle is introduced. This model applied to the estimation of the efficiency of free flow turbines allows us to take into account the pressure drop past the lamina. 相似文献
90.
Hiroshi Ito Masaki Okazaki Dolores C. Miller 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1478-1505
Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with 1H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004 相似文献