全文获取类型
收费全文 | 579篇 |
免费 | 4篇 |
国内免费 | 57篇 |
专业分类
化学 | 619篇 |
晶体学 | 1篇 |
物理学 | 20篇 |
出版年
2023年 | 7篇 |
2022年 | 4篇 |
2021年 | 4篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 13篇 |
2017年 | 15篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 11篇 |
2013年 | 29篇 |
2012年 | 16篇 |
2011年 | 56篇 |
2010年 | 43篇 |
2009年 | 63篇 |
2008年 | 56篇 |
2007年 | 65篇 |
2006年 | 60篇 |
2005年 | 44篇 |
2004年 | 50篇 |
2003年 | 29篇 |
2002年 | 25篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1988年 | 2篇 |
1981年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有640条查询结果,搜索用时 31 毫秒
41.
42.
Christopher M. Timperley Matthew J. Waters 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):423-430
The synthesis and physical properties of the first fluorinated dialkyl phosphoramidates of structure (RCH 2 O) 2 P(O)NHCH 2 R F , where R = CH 3 , CF 3 or CCl 3 and R F = CF 3 or C 2 F 5 , are described. They were obtained by treatment of the respective dialkyl phosphorochloridates with trifluoroethylamine or pentafluoropropylamine in ether in the presence of triethylamine. 相似文献
43.
Several new random and block copoly(imide siloxane)s have been prepared by the solution polycondensation of commercially available 4,4′-oxydianiline (ODA) and amino-propyl terminated polydimethylsiloxane (APPS) with 4,4′-(hexafluoro-isopropylidene)diphthalic anhydride (6FDA). The siloxane loading was kept to 10, 20, 30, 40 and 50 wt% in the copolymers. The random copolymers were prepared by a one pot solution imidization technique, and two pot solution imidization technique was adopted for the synthesis of the block copolymers. The diamine ODA and the dianhydride 6FDA composed the hard block segment, while APPS and 6FDA composed the soft block segment. The hard block length was kept constant while the soft block lengths were varied by varying the siloxane loading. Accordingly, block copoly(imide siloxane)s were prepared on increasing the soft block lengths (DP) from 3 to 6, 10, 18 and 36 for fixed hard block length of 22. The resulting polymers have been well characterized by IR, NMR and GPC techniques. Thermal and mechanical properties of the random and block copolymers were compared with the already reported homopolyimide without siloxane moiety. 相似文献
44.
Tomáš Bříza Martin Havlík Bohumil Dolenský Zdeněk Kejík Pavel Martásek 《Supramolecular chemistry》2013,25(3):237-242
Highly functionalized fluorinated porphyrins were synthesized by a convergent strategy. Nucleophilic substitution using fluorinated branched unit and 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin afforded highly functionalized fluorinated porphyrin 8 containing 24 fluorinated chains in the peripheral region. 相似文献
45.
《合成通讯》2013,43(24):3779-3790
ABSTRACT Polyhydroxamate chelators containing fluoro substituents are of interest as potential extractants for actinides in separations involving supercritical carbon dioxide. In this context, we have developed three new reagents 1, 2, and 3, that allow the efficient incorporation of an N-fluoroalkyl hydroxamate moiety onto a variety of substrates using acylation, alkylation, and Michael addition strategies. 相似文献
46.
Synthesis of new fluorinated tertiary malonamides (F-malonamides) was accomplished, and their liquid/liquid (L/L) extraction properties with f-elements were investigated. These molecules are fluorinated analogues of well known extractants used in several processes designed towards the treatment of nuclear wastes, and the efficient separation of lanthanides from minor actinides; however, the synthesis of F-malonamides deserved a modification of the general synthetic route commonly employed to prepare H-malonamides. Extraction of neodymium from various aqueous media into both fluorous and classical solvents was studied, which revealed an opposite trend between F-malonamides and H-malonamides: L/L extraction ability is very sensitive to the nitrogen atoms substitution pattern, and the most efficient F-malonamide is compound 3 (R1 = Me), whereas the best H-malonamide is compound 5 (R1 = Bu, DMDBTDMA). 相似文献
47.
Xia-Li Yue Hu Li Shuang-Shuang Liu Qing-Ye Zhang Jing-Jing Yao Fei-Yan Wang 《中国化学快报》2014,25(7):1069-1072
With the increase of herbicide-resistant weeds, novel, more selective and even more potent herbicides to control weeds are needed. In this paper, a series of N-fluorinated phenyl-N'-pyrimidyl urea derivatives were synthesized and screened for their herbicidal activities against Amaranthus retroflexus (AR) and Setaria viridis ( SV). Compound 2S (N-(3-trifluoromethylphenyl)-N'-(2-amino-4-chloro-6-methylpyr- imidyl) urea) exhibited marked herbicidal activity against SV(IC50 =11.67 mg/L) and is more potent than bensulfuron (IC50= 27.45 mg/L), a commercially available herbicide. A statistically significant CoMFA model with high prediction abilities (q2 = 0.869, r2 = 0.989) was obtained. 相似文献
48.
《Arabian Journal of Chemistry》2020,13(2):3801-3816
Due to intermediate hydrophobicity of methyl methacrylate (MMA) monomer in water, it is difficult to prepare its stable water in oil high internal phase emulsion (HIPE). Moreover, the addition of fully hydrophilic co-monomer such as 2-hydroxyethyl methacrylate (HEMA) in MMA monomer makes it further troublesome to stabilize these emulsions. This paper addresses the preparation of such type of difficult to prepare emulsions via addition of an amphiphilic fluorinated di-block copolymer (FDB), poly(2-dimethylamino)ethylmethacrylate-b-poly(trifluoroethyl methacrylate) (PDMAEMA-b-PTFEMA) as stabilizer. Interestingly, HEMA and/or HFBA (hexa fluorobutyl acrylate) as co-monomers were successfully added to impart some special properties such as thermodynamic stability, desired amphiphilicity to the final polyHIPEs. Fluorinated blocks in FDB anchored well at oil/water interface of HIPE, offering enough hydrophobicity to the comparatively hydrophilic monomers and in turn providing resistance against coalescence. MMA polyHIPEs were found to be fully hydrophobic just by replacing HEMA co-monomer with HFBA. Due to superb inherent hydrophobic nature of fluorine atoms, MMA-HFBA polyHIPEs showed remarkable water contact angle of 139°. Furthermore, the addition of fluorinated co-monomer in MMA based HIPEs significantly improved thermal stabilities of these materials with improvement in degradation temperature from 305 °C to 360 °C. 相似文献
49.
在微波作用下,采用高效催化剂体系,于中等极性非质子溶剂中经卤素交换氟化高效制备了系列含氟芳香醛(酮)类化合物,产品收率53·3%~92·6%,反应时间较常规加热最多可缩短80%以上。采用中等极性反应溶剂,还可突出表现出微波对反应促进的“非热效应”,从而大大拓宽了氟化反应溶剂的选择范围。 相似文献
50.
Xin Jian SONG Xiao Hong TAN Yan Gang WANG 《中国化学快报》2006,17(11):1443-1446
In order to find new urea cytokinins, a series of novel fluorinated heteroaromatic ureas have been designed and synthesized. The crystal structure of 3g was further determined by single crystal X-ray diffraction to obtain the structural feature of this class of urea compounds. The preliminary bioassay showed that some title compounds have good cytokinin activity. 相似文献