ICP-AES法测定硼硅酸盐玻璃中的常量及微量元素

应用电感耦合等离子体原子发射光谱(ICP-AES)法,对硼硅酸盐玻璃中的常量元素Si、Ca、Al、B及微量元素Fe、Ti、Mg进行测定。在优化的工作条件下,各元素的检出限:SiO20.026μg/mL,Ca0.0002μg/mL,Al0.028μg/mL,B0.005μg/mL,Mg0.0002μg/mL,Fe0.006μg/mL,Ti0.005μg/mL。样品测定结果的相对标准偏差(n=6)在0.02%~1.47%之间,加入标准溶液的回收率为93.0%~103.2%。采用该方法对硼硅酸盐玻璃标准样品进行测定,测定值与标准值一致。     

980nm激光激发下Er3+和Yb3+共掺杂氟氧玻璃的上转换发光

制备了一种新型的上转换发光材料,它不仅具有较高的上转换发光效率,而且还避免了氟化物基质的缺点。其组分为58.52%PbF₂-34.43% GeO₂-3% Al₂O₃-0.05% Er₂O₃-4%Yb₂O₃,其中GeO₂为玻璃形成体氧化物,PbF₂和Al₂O₃为调整剂,以共掺杂Er³⁺和Yb³⁺离子为上转换研究的对象。测量了该玻璃系统在980nm半导体激光器激发下的上转换发光光谱,观察到很强的658nm的红光和548,526nm的绿光,而且红光的发射强度远远强于绿光。通过对上转换发光强度与激发强度关系曲线的拟合,表明此材料的绿光发射和红光发射都为双光子过程。研究了激发光的工作电流与上转换荧光强度的关系,讨论了其上转换发光特性。     

K9玻璃薄膜对离子交换磷酸盐玻璃波导表面保护的优化研究

采用镀K9玻璃薄膜方法来解决离子交换掺铒磷酸盐玻璃波导表面的侵蚀问题,对K9玻璃薄膜的厚度进行了优化研究。测量分析了样品的荧光光谱和荧光寿命,采用光学显微镜和棱镜耦合技术对不同K9玻璃薄膜厚度下制备波导的表面形貌和导光特性进行了表征和测试。结果表明,与掺铒磷酸盐玻璃原材料相比,镀K9玻璃薄膜后荧光光谱保持不变,荧光寿命稍有下降(约0.2 ms);K9玻璃薄膜的厚度在60~80 nm的范围内保护效果最佳。为下一步制备掺铒有源玻璃光波导器件奠定了良好的实验基础。     

808 nm LD激发下高折射率差光纤锥-硫卤微球耦合系统的荧光回廊模

用熔融淬冷法制备了0.5wt.%掺杂Nd3+:75GeS2-15Ga2S3-0CsI(0.5wt.%Nd-GGSI)硫卤玻璃.在此基础上以玻璃粉料漂浮熔融法制备出粒径为50~300μm高折射率(n≈2.1)玻璃微球,并在显微镜下选出表面质量高的硫卤微球用于后续实验.将火焰法拉制出的直径1~2μm间的双锥形石英微纳光纤与硫系微球进行近场耦合.相位匹配条件下测试结果表明光纤锥倏逝场将激发球内径向高阶回音壁模式.实验测量了在808nm LD激光泵浦下直径110μm微球的荧光光谱特性,结果表明:掺Nd3+硫卤微球在输出端1 075nm波段附近产生了等间距分布的荧光回音壁模式的光学谐振,共振峰间隔为1.80nm.实验结果与微球腔回音壁模式谐振的理论模型有较高的符合度.     

大气气溶胶消光系数测量新方法

利用光在镀膜玻璃管中传输的特点,介绍了一种测量大气气溶胶消光系数的新方法。该方法将某一波长的光以一定角度入射到充满气溶胶的玻璃管中,经管壁的多次折返大大增加了光程,气溶胶对光的衰减信息可以通过玻璃管两端的探测器测量得到,利用比值计算方法消除光电转换过程中因光强波动、管壁不均匀以及分子散射等带来的测量误差,提高了气溶胶消光系数测量的灵敏度。将用该方法测量气溶胶在波长550nm上的消光系数,与能见度仪测量结果对比表明此方法测量结果是合理的,且该方法具有原理简单、操作方便等特点。     

Mechanical Behavior of Unidirectional Curaua Fiber and Glass Fiber Composites

Summary: This work intends to promote the use of natural fibers by comparing the behavior of isophthalic polyester matrix composites reinforced with unidirectional curaua fibers with that of unidirectional glass fiber composites. The composites were produced varying the reinforcement angle (0°, 15°, 30°, 45°, 60°, 75° and 90°) with the aim of studying the fiber orientation effect on composite strength. Composites were also made varying the fiber volume fraction (10%, 20%, 30%, 40% and 50%). The efficiency of an alkaline (5% NaOH) surface treatment of the curaua fiber was also evaluated. The unidirectional composites were characterized using tensile, flexural and short beam tests as per ASTM standards. The properties of a lamina reinforced with either glass or curaua fibers were also studied using theoretical micromechanical approach available in commercial software. The curaua fiber alkaline treatment produced higher tensile strength results compared with untreated fibers. The increase in reinforcement angle significantly decreased strength and modulus of the composites, as expected, and the glass fiber composites showed a more pronounced dependence with fiber orientation. Although the glass fiber laminas showed the best mechanical performance, the results obtained with the curaua fibers were considered similar for angles greater than 45°.     

大口径激光玻璃光学加工的质量控制

大口径激光玻璃光学加工的特点是加工指标要求高、难度大,加工周期长,而质量控制是保障大口径激光玻璃光学加工质量满足要求和促进工艺进步的管理手段。从质量控制和质量管理的角度出发,阐述了在大口径激光玻璃光学加工中质量控制的特点和质量控制的方法,其目的是通过流程检验和控制,人员、设备、物料管理,环境管理,以及先进的质量控制和分析方法的应用来提高加工的质量稳定性和合格率。实践证明:在大口径激光玻璃光学加工中推行质量管理,产品的合格率和加工效率得到了较为显著的提高。     

Zr基大块非晶中添加元素对非晶形成能力及耐蚀性的影响

运用实空间递归方法研究了添加元素Nb,Ta,Y,La对Zr基非晶合金的非晶形成能力和耐腐蚀性能的影响.用计算机编程构造了Zr基非晶中初始晶化相Zr₂Ni的原子结构模型,用Zr₂Ni中的二十面体原子团簇模拟非晶中的二十面体团簇.计算了替代二十面体中心或顶角位置原子前后Ni,Zr及合金元素的局域态密度、团簇中心Ni与近邻Zr原子及Ni与替代元素Nb,Ta,Y,La间的键级积分,还计算了合金元素替代前后团簇的费米能级.局域态密度计算结果表明：合金元素Cu占据二十面体团 关键词： 电子结构 Zr基大块非晶 非晶形成能力 耐蚀性     

The relaxation of polymers with linear flexible chains of uniform length

The analysis of dynamic mechanical data indicates that linear flexible polymer chains of uniform length follow a scaling relation during their relaxation, having a linear viscoelastic relaxation spectrum of the formH() = n ₁ G _N ⁰ × (/ _max) ⁿ¹ for _max. Data are well represented with a scaling exponent of about 0.22 for polystyrene and 0.42 for polybutadiene. The plateau modulusG _N ⁰ is a material-specific constant and the longest relaxation time depends on the molecular weight in the expected way. At high frequencies, the scaling behavior is masked by the transition to the glassy response. Surprisingly, this transition seems to follow a Chambon-Winter spectrumH() = C^–n2, which was previously adopted for describing other liquid/solid transitions. The analysis shows that the Rouse spectrum is most suitable for low molecular-weight polymersM M _c , and that the de Gennes-Doi-Edwards spectrum clearly predicts terminal relaxation, but deviates from the observed behavior in the plateau region.Dedicated to Prof. Richard S. Stein on the occasion of his 65th birthday.On sabbatical leave from the University of Linz, Austria.     

氟锆酸盐玻璃中Tm^3＋离子的红外光谱性质

根据Ｔｍ＾３＋离子有吸收光谱，计算在氟锆酸盐玻璃中的＾Ｔｍ＾３＋的Ｊｕｄｄ－Ｏｆｅｌｔ参数和工外跃迁＾３Ｆｉ→＾３Ｈ４，＾３Ｈ４→＾３Ｈ６和３Ｆ４→＾３Ｈ５ 发跃迁几率，研究了Ｔｍ＾３＋的红外发射光谱的交叉驰豫过程，讨论了离子浓度对红外发光强度的影响，并讨论了这些跃迁的发射截面。