全文获取类型
收费全文 | 542篇 |
免费 | 23篇 |
国内免费 | 79篇 |
专业分类
化学 | 311篇 |
晶体学 | 7篇 |
力学 | 66篇 |
综合类 | 1篇 |
数学 | 6篇 |
物理学 | 253篇 |
出版年
2024年 | 2篇 |
2023年 | 19篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 12篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 12篇 |
2016年 | 20篇 |
2015年 | 13篇 |
2014年 | 20篇 |
2013年 | 25篇 |
2012年 | 24篇 |
2011年 | 56篇 |
2010年 | 27篇 |
2009年 | 49篇 |
2008年 | 33篇 |
2007年 | 42篇 |
2006年 | 36篇 |
2005年 | 35篇 |
2004年 | 28篇 |
2003年 | 26篇 |
2002年 | 18篇 |
2001年 | 10篇 |
2000年 | 22篇 |
1999年 | 11篇 |
1998年 | 12篇 |
1997年 | 11篇 |
1996年 | 9篇 |
1995年 | 9篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有644条查询结果,搜索用时 15 毫秒
41.
通过气相沉积法, 在大气环境下退火, 制备了多孔ZnO薄膜. 这种多孔ZnO薄膜的制备方法具有成膜过程简单且工艺可精确控制等特点. 将多孔ZnO薄膜用胶体CdSe量子点来敏化获得太阳能电池, 具有1.01%的能量转换效率. 相似文献
42.
Dendrimers are three dimensional nanosized synthetic molecules that have internal cavities and numerous surface groups. In recent times they have received increased attention in sensing applications. For dendrimers to be used as sensors, they most commonly require functionalization at their surface. This is because the surface is generally the first point of contact between the dendrimer and the outside world, hence surface functionalization serves to selectively home in on the target analyte. Further, sensor signals may be transmitted through surface functionalities e.g. fluorochromic molecules. It is therefore important to document surface functionalization approaches. Dendrimers with amine surface groups have the advantage of being able to be conjugated to other molecules via an amide linkage, which is one of the most fundamental and widespread chemical bonds in nature. In this paper we demonstrate the properties of dendrimers that make them so applicable to sensing. We review several methods for functionalizing dendrimers via an amide linkage, as well as present a review of surface functionalized polyamidoamine, polyamine, and polypeptide dendrimers that have been employed for biological, chemical and molecular sensing. 相似文献
43.
不锈钢金属丝网上TiO2纳米薄膜光催化剂的研究 总被引:21,自引:0,他引:21
以钛酸正丁酯为原料,采用溶胶-凝胶法在金属丝网上制备了TiO2薄膜光催化剂.利用SEM,TEM,AES和Raman光谱研究了薄膜的表面及结构特性.以甲醛的光催化氧化反应为试验反应,考察了提拉次数、PEG浓度和焙烧温度对TiO2薄膜光催化剂活性的影响.将TiO2薄膜的结构特性与其光催化活性进行了关联.结果表明,在前驱体溶胶中加入10%PEG400,提拉3次并于400℃下焙烧可制得具有中孔结构和结晶完好的锐钛矿型TiO2薄膜,并具有最佳的光催化活性. 相似文献
44.
45.
对生长在Si和MgO单晶基片上的不同厚度的单层NbN薄膜、双层薄膜AlN/NbN以及三层薄膜NbN/AlN/NbN应用透射电子显微镜(Transmission Electron Microscope,TEM)技术进行了分析研究,对这几种薄膜样品的微观结构、薄膜厚度以及各个边界的一些直观细节给出了较为清晰的图像。由透射电子显微镜的电子衍射图案计算了薄膜和单晶衬底的晶格常数,并与我们以前采用X射线衍射技术分析的结果进行了比较,结果有很好的吻合。 相似文献
46.
47.
The properties of photonic band gap in one-dimensional photonic crystals composed of single-negative metamaterials are studied theoretically. Our study shows that the photonic gap will vanish at a certain incident angle when both the phase-match and impedance-match conditions are satisfied simultaneously, suggesting that the bandwidth and location of the photonic gap are strongly dependent on the incident angle and polarization. However, the photonic gap will not vanish and may become insensitive to the incident angle when the two match conditions cannot be met. Our study also shows that losses in metamaterials have little effect on the properties of the photonic gap. 相似文献
48.
In this paper, a new two-fluid two-component computational fluid dynamics (CFD) model is developed to simulate vertical upward two-phase annular flow. The two-phase VOF scheme is utilized to model the roll wave flow, and the gas core is described by a two-component phase consisting of liquid droplets and gas phase. The entrainment and deposition processes are taken into account by source terms of the governing equations. Unlike the previous models, the newly developed model includes the effect of liquid roll waves directly determined from the CFD code, which is able to provide more detailed and, the most important, more self-standing information for both the gas core flow and the film flow as well as their interactions. Predicted results are compared with experimental data, and a good agreement is achieved. 相似文献
49.
单纯形法计算薄膜常数 总被引:1,自引:0,他引:1
本文首次报道了用单纯形加速法计算正常兔IgG抗原与羊-抗兔抗体反应的抗体层厚度和光学常数,该方法假定抗体层厚度、光学常数均为时间的函数,避免了以往只假定厚度为时间函数所造成的误差。结果表明该方法计算抗体层薄膜常数是可行的。 相似文献
50.
This paper investigates the microscopic features which occur when a four-layered film is ablated using Q-switched Nd:YAG laser. The four-layered films consist of a vacuum-deposited aluminium layer (0.02 μm) upon an oriented polypropylene (OPP) film (30 μm) which has been laminated using an inert adhesive and a second OPP film. Laser radiation is absorbed principally by the aluminium layer, melting and/or vaporising it. Upon cooling, the aluminium layer is rearranged into discrete microscopic particles, which give laser-treated areas of the film a transparent appearance. Within the films are found microscopic features, which can be divided into three distinct types: aluminium demetallisation features, polymer distortion features and particle features. Features from each of these categories can exist within a single laser track depending upon the laser parameters used for transparentisation. 相似文献