全文获取类型
收费全文 | 502篇 |
免费 | 101篇 |
国内免费 | 81篇 |
专业分类
化学 | 401篇 |
晶体学 | 22篇 |
力学 | 22篇 |
综合类 | 13篇 |
数学 | 87篇 |
物理学 | 139篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 5篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 25篇 |
2016年 | 25篇 |
2015年 | 36篇 |
2014年 | 35篇 |
2013年 | 52篇 |
2012年 | 35篇 |
2011年 | 37篇 |
2010年 | 43篇 |
2009年 | 25篇 |
2008年 | 35篇 |
2007年 | 20篇 |
2006年 | 28篇 |
2005年 | 30篇 |
2004年 | 20篇 |
2003年 | 20篇 |
2002年 | 27篇 |
2001年 | 25篇 |
2000年 | 29篇 |
1999年 | 20篇 |
1998年 | 18篇 |
1997年 | 12篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
排序方式: 共有684条查询结果,搜索用时 15 毫秒
51.
<正>4,6-Diarylpyrimidin-2(1H)-one derivatives have been synthesized from three-component one-pot condensation of acetophe-none derivatives,aldehydes and urea in the presence of trimethylsilyl chloride and a catalytic amount of H_3PMo_(12)O_(40)under solvent-free conditions. 相似文献
52.
53.
Ricardo M. Castro‐Acosta Alma L. Revilla Octavio T. Ramírez Laura A. Palomares 《Electrophoresis》2010,31(8):1376-1381
Virus‐like particles have been successfully used as safe vaccines, as their structure is identical to their native counterparts but devoid of the viral genetic material. However, production of these complex structures is not easy, as recombinant proteins must assemble into virus‐like particles. Techniques to differentiate assembled and soluble proteins, as well as assembly intermediaries often present in a sample, are required. An example of complex virus‐like particles mixture occurs when rotavirus proteins are recombinantly expressed. Rotavirus‐like particles (RLP) can be single (sl), double (dl), or triple layered (tl). The use of RLP preparations as vaccines requires their complete characterization, including separation and quantification of each RLP in a sample. In this work, CZE was evaluated for the separation and quantification of dl and triple‐layered rotavirus‐like particles (tlRLP). A fused‐silica capillary with a deoxycholate running buffer efficiently separated dl and tlRLP in RLP preparations, as they migrated in two discrete peaks with electrophoretic mobilities of 1.24±0.04 and 2.95±0.03 Ti, respectively. Standard curves for dl and tlRLP were generated, and the response was linearly proportional to analyte concentration. The methodology developed was quantitative, specific, accurate, precise, and reproducible. CZE allowed the quantitative characterization of RLP preparations, which is required for evaluation of immunogens, for process development, and for quality control protocols. 相似文献
54.
55.
SnO2 rods have been synthesized by using tin (II) chain‐like complexes as precursors in which oxalate and ethylene glycol act as co‐ligands. On the basis of experimental analysis, a reasonable formation mechanism of rods is discussed, which is further supported by Fourier transform infrared spectroscopy (FT‐IR). These results show that the synergistic effect of oxalate group and ethylene glycol plays an important role in the formation of long SnO2 rods. 相似文献
56.
Kai Zhang Xuefen Wang Yin Yang Lili Wang Meifang Zhu Benjamin S. Hsiao Benjamin Chu 《Journal of Polymer Science.Polymer Physics》2010,48(10):1118-1125
In this work, aligned and molecularly oriented bone‐like PLLA semihollow fiber yarns were manufactured continuously from an optimized homogeneous polymer‐solvent‐nonsolvent system [PLLA, CH2Cl2, and dimethyl formamide (DMF)] by a single capillary electrospinning via self‐bundling technique. Here, it should be emphasized that the self‐bundling electrospinning technique, a very facile electrospinning technique with a grounded needle (which is to induce the self‐bundling of polymer nanofibers at the beginning of electrospinning process), is used for the alignment and molecular orientation of the polymer fiber, and the take‐up speed of the rotating drum for the electrospun fiber yarn collection is very low (0.5 m/s). PLLA can be dissolved in DMF and CH2Cl2 mixed solvent with different ratios. By varying the ratios of mixed solvent system, PLLA electrospun semihollow fiber with the porous inner structure and compact shell wall could be formed, the thickness of the shell and the size of inner pores could be adjusted. The results of polarized FTIR and wide angle X‐ray diffraction investigations verified that as‐prepared PLLA semihollow fiber yarns were well‐aligned and molecularly oriented. Both the formation mechanism of semihollow fibers with core‐shell structure and the orientation mechanism of polymer chains within the polymer fibers were all discussed. The as‐prepared self‐bundling electrospun PLLA fiber yarns possessed enhanced mechanical performance compared with the corresponding conventional electrospun PLLA fibrous nonwoven membranes. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1118–1125, 2010 相似文献
57.
Yuan You Yi Chen Chong Hua Chang‐Ming Dong 《Journal of polymer science. Part A, Polymer chemistry》2010,48(3):709-718
Dendron‐like poly(γ‐benzyl‐L ‐glutamate)/linear poly(ε‐caprolactone)/dendron‐like poly(γ‐benzyl‐L ‐glutamate) triblock copolymers having 2m + 1 PBLG branches (denoted as PBLG‐Dm‐PCL‐Dm‐PBLG, m = 0, 1, 2, and 3) were for the first time synthesized by utilizing ring‐opening polymerization (ROP) and click chemistry. The bifunctional azide‐terminated PCL (N3‐PCL‐N3) was click conjugated with propargyl focal point PAMAM‐typed dendrons Dm to generate Dm‐PCL‐Dm, which was then used as macroinitiator for the ROP of BLG‐NCA monomer to produce the targeted PBLG‐Dm‐PCL‐Dm‐PBLG triblock copolymers. Their molecular structures and physical properties were characterized in detail by FTIR, NMR, gel permeation chromatography, differential scanning calorimetry, and wide angle X‐ray diffraction (WAXD). The crystallinity of the central PCL segment within these copolymers is increasingly suppressed by the flanking PBLG wedges, whereas the PBLG segments gradually changed from a β‐sheet conformation to an α‐helix conformation with the increasing PBLG branches. These triblock copolymers formed thermoreversible organogels in toluene, and the dendritic topology of PBLG wedges controlled their critical gelation concentrations. The self‐assembled structure of organogels was further characterized by means of transmission electron microscopy, WAXD, and small‐angle X‐ray scattering. The fibers with flat ribbon morphology were clearly shown, and the gelation occurred through a self‐assembled nanoribbon mechanism. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 709–718, 2010 相似文献
58.
In this paper, we study the convergence of Gauss-Newton's like method for nonlinear least squares problems. Under the hypothesis that derivative satisfies some kind of weak Lipschitz condition, we obtain the sharp estimates of the radii of convergence ball of Gauss-Newton's like method and the uniqueness ball of the solution. 相似文献
59.
V. Dzhunushaliev 《Annalen der Physik》2006,15(9):671-677
It is shown that in the standard vacuum 5D Kaluza‐Klein gravity there exist wormhole‐like solutions which look like strings attached to two D‐branes. The asymptotic behaviour of the corresponding metric is investigated. 相似文献
60.