首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   20298篇
  免费   1542篇
  国内免费   1237篇
化学   19538篇
晶体学   25篇
力学   61篇
综合类   52篇
数学   285篇
物理学   3116篇
  2024年   40篇
  2023年   289篇
  2022年   516篇
  2021年   486篇
  2020年   636篇
  2019年   623篇
  2018年   572篇
  2017年   783篇
  2016年   946篇
  2015年   894篇
  2014年   881篇
  2013年   1312篇
  2012年   1379篇
  2011年   1301篇
  2010年   1100篇
  2009年   1340篇
  2008年   1126篇
  2007年   1354篇
  2006年   1118篇
  2005年   1007篇
  2004年   893篇
  2003年   762篇
  2002年   586篇
  2001年   366篇
  2000年   356篇
  1999年   333篇
  1998年   290篇
  1997年   259篇
  1996年   254篇
  1995年   216篇
  1994年   180篇
  1993年   152篇
  1992年   136篇
  1991年   181篇
  1990年   90篇
  1989年   72篇
  1988年   57篇
  1987年   33篇
  1986年   33篇
  1985年   29篇
  1984年   20篇
  1983年   11篇
  1982年   17篇
  1981年   8篇
  1980年   7篇
  1979年   6篇
  1976年   3篇
  1974年   4篇
  1973年   3篇
  1972年   4篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
We prove that there exists a maximal ideal of a BCI-algebra X in which each subalgebra is an ideal.AMS Subject Classification (1991): 06F35, 03G25.The second author was supported by the LG Yonam Foundation (1995).  相似文献   
102.
建立了流动注射氢化物发生-原子吸收光谱法测定富硒天麻、葡萄及大米中硒的方法。测定硒的线性范围为0.33μg/L-50μg/L,相对标准偏差小于3%,加标回收率为93%-106%。方法已广泛应用于实际样品中微量硒的测定。  相似文献   
103.
104.
Summary A new gas chromatographic method using an automatic purge-and-trap system coupled to a GC with mass selective detection to analyze styrene at the parts-per-trillions (ng kg–1) level is described. The method shows a good sensitivity and the detection limit is 10 ng kg–1 with a relative standard deviation (RSD) of 4.7% for 164 ng kg–1 styrene in olive oil. This analytical method has been successfully applied to the analysis of styrene in extra-virgin olive oil from the European market.  相似文献   
105.
在文(1),(2),(3)的基础上,我们首先在德摩根拓扑代数上用有限覆盖性质定义了紧性,并引入ω-元,ω-d-q-聚点等概念,并着重讨论了紧性与q-收敛性之间的关系。  相似文献   
106.
A basically new mechanism of the thermal decomposition of solids is proposed to explain the mass spectral observations of gaseous molecules of CoO, CuO, Cu2O, NiO, PbO and Mg(OH)2 during the low-temperature decomposition of the anhydrous and hydrated nitrates of these metals. The mechanism consists of two stages: congruent gasification of all reaction products irrespective of their saturated vapor pressure and subsequent condensation of the low-volatility species (oxides and hydroxides). The partial pressures of these species at the appearance temperatures calculated from this theory for the first stage of the process (1–50 mPa) are in agreement with the detection limits of the quadrupole mass spectrometers used in these experiments. The proposed mechanism is supported by other available data obtained by thermal analysis.  相似文献   
107.
The ability to quantitatively map the distribution of elements on the micrometer scale and smaller with high sensitivity and isotopic discrimination is unique to ion microscopy. The information contained in ion images can be crucial to the study of the solid state, where chemical heterogeneity is often directly related to observed behavior. The tools of digital image processing allow the extraction of quantitative information from the image data. These techniques coupled with improved instrumentation for the detection of ion images drastically increase the problem solving capabilities of the ion microscope. The use of such methods and instrumentation in the ion microscopic analyses of cell cultures and tissues of biological and biomedical relevance will be discussed.  相似文献   
108.
苯对N,N-二甲基甲酰胺化合物1H NMR的影响研究   总被引:1,自引:0,他引:1  
本文研究了N,N-二甲基甲酰胺(DMF)在四氯化碳和苯混合溶剂中的1H NMR。观察到N,N-二甲基甲酰胺(DMF)分子中两个甲基和混合溶剂中苯的共振吸收峰的化学位移随苯的摩尔分数增加而逐渐移向高场,而且两个甲基共振吸收峰向高场移动的程度不同,α甲基较β甲基为甚。DMF分子中两个甲基和混合溶剂中苯的化学位移可以用线性方程表示(δ=A+Bx),这里x是混合溶剂中苯的摩尔分数。相关系数R接近于-1。  相似文献   
109.
Atom transfer radical polymerization (ATRP) and single electron‐transfer living radical polymerization (SET‐LRP) both utilize copper complexes of various oxidation states with N‐ligands to perform their respective activation and deactivation steps. Herein, we utilize DFT (B3YLP) methods to determine the preferred ligand‐binding geometries for Cu/N‐ligand complexes related to ATRP and SET‐LRP. We find that those ligands capable of achieving tetrahedral complexes with CuI and trigonal bipyramidal with axial halide complexes with [CuIIX]+ have higher energies of stabilization. We were able to correlate calculated preferential stabilization of [CuIIX]+ with those ligands that perform best in SET‐LRP. A crude calculation of energy of disproportionation revealed that the same preferential binding of [CuIIX]+ results in increased propensity for disproportionation. Finally, by examining the relative energies of the basic steps of ATRP and SET‐LRP, we were able to rationalize the transition from the ATRP mechanism to the SET‐LRP mechanism as we transition from typical nonpolar ATRP solvents to polar SET‐LRP solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4950–4964, 2007  相似文献   
110.
Alexander  M. R.  Jones  F. R.  Short  R. D. 《Plasmas and Polymers》1997,2(4):277-300
This study reports on the effect of input power to hexamethyldisiloxane (HMDSO) plasmas. The power dependence of the plasma-phase species and of the surface chemistry (of the deposits) has been investigated. Neutral and positive molecular species were detected within the plasma using mass spectrometry (MS). Secondary ion mass spectrometry (SIMS) was used to probe the molecular structure of the deposits. The elemental composition of the surface was determined by XPS and the deposition rate was monitored using a vibrating quartz crystal microbalance. Neutral and cationic molecules of mass greater than HMDSO were detected in the plasma. Their formation through ion-molecule reactions is proposed. Changes in the relative concentration of plasma-phase species follow those seen in molecular species detected at the deposit surface. Thus, we believe that the molecular structure of the deposits can be related to the species present in the plasma. While traditionally the dominant mechanism in deposit formation is assumed to be free radical combinations, we propose other possibilities involving cations with the aim of putting forward a new perspective on plasma polymerization mechanisms and thereby stimulating discussion.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号