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961.
962.
Desislava Staneva 《International Journal of Polymer Analysis and Characterization》2013,18(5):390-397
Seven newly synthesized poly(propyleneamine) dendrimers, modified with 1,8-naphthalimides, have been investigated by infrared, UV-vis, and fluorescence spectroscopy. The influence of the nature of the substituents at the C-4 position of the naphthalene ring on the spectral properties of the dendrimers is discussed. 相似文献
963.
Infra-Red spectra of a series of substituted salicylaldehyde and 2-hydroxy-naphthaldehyde Schiff bases were used to investigate enol-keto tautomeric equilibrium. Two model compounds, namely, salicylidinaniline and naphthylidinequinolineamine Schiff bases were used to represent the enol and keto forms, respectively. From the IR spectra of the model compounds it was possible to assign the IR absorption for the C=O and the C=N groups in both the keto and the enol form. It was also possible to assign other absorptions which were either specific to the keto or the enol forms. Specific pattern were observed for all the studied compounds. 相似文献
964.
Dr. Matthieu Autillo Md. Ashraful Islam Julie Héron Laetitia Guérin Dr. Eleonor Acher Dr. Christelle Tamain Dr. Marie-Claire Illy Dr. Philippe Moisy Dr. Eric Colineau Dr. Jean-Christophe Griveau Dr. Claude Berthon Dr. Hélène Bolvin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(24):7138-7153
Actinide +VI complexes ( = , and ) with dipicolinic acid derivatives were synthesized and characterized by powder XRD, SQUID magnetometry and NMR spectroscopy. In addition, and complexes were described by first principles CAS based and two-component spin-restricted DFT methods. The analysis of the 1H paramagnetic NMR chemical shifts for all protons of the ligands according to the X-rays structures shows that the Fermi contact contribution is negligible in agreement with spin density determined by unrestricted DFT. The magnetic susceptibility tensor is determined by combining SQUID, pNMR shifts and Evans’ method. The SO-RASPT2 results fit well the experimental magnetic susceptibility and pNMR chemical shifts. The role of the counterions in the solid phase is pointed out; their presence impacts the magnetic properties of the complex. The temperature dependence of the pNMR chemical shifts has a strong contribution, contrarily to Bleaney's theory for lanthanide complexes. The fitting of the temperature dependence of the pNMR chemical shifts and SQUID magnetic susceptibility by a two-Kramers-doublet model for the complex and a non-Kramers-doublet model for the complex allows for the experimental evaluation of energy gaps and magnetic moments of the paramagnetic center. 相似文献
965.
Based on infrared absorption spectroscopy technique, a carbon monoxide sensor was developed using the fundamental absorption band of carbon monoxide molecule at the wavelength around 4.6 µm. The developed sensor consists of pulse-modulated wideband incandescence, open ellipsoid light-collector gas-cell, dual-channel detector, and control and signal-processing module. With the prepared standard carbon monoxide gas sample, sensing characteristics on carbon monoxide were investigated using the sensor. Experimental results reveal that the limit of detection is about 10 ppm, the relative error at the limit of detection point is less than 14%, and that is less than 7.8% within the low concentration range of 20~180 ppm. The maximum absolute errors of 50 min long-term measurement on the 0 and 14 ppm CO gas samples are about 3 and 3.17 ppm, respectively, and the standard deviations are as small as 0.18 and 1.25 ppm, respectively. Compared with the reported carbon monoxide detection systems utilizing quantum cascaded lasers and distributed feedback lasers, the proposed sensor shows potential applications in carbon monoxide detection under the circumstances of coal-mine and environmental protection, by virtue of high performance, low cost, simple optical structure, and so on. 相似文献
966.
967.
968.
Dr. Yan Peng Hagen Kaemmerer Prof. Annie K. Powell 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15044-15066
In this Review we discuss the tuning handles which can be used to steer the magnetic properties of FeIII-4 f “butterfly” compounds. The majority of presented compounds were produced in the context of project A3 “Di- to tetranuclear compounds incorporating highly anisotropic paramagnetic metal ions” within the SFB/TRR88 “3MET”. These contain {FeIII2Ln2} cores encapsulated in ligand shells which are easy to tune in a “test-bed” system. We identify the following advantages and variables in such systems: (i) the complexes are structurally simple usually with one crystallographically independent FeIII and LnIII, respectively. This simplifies theory and anaylsis; (ii) choosing Fe allows 57Fe Mössbauer spectroscopy to be used as an additional technique which can give information about oxidation levels and spin states, local moments at the iron nuclei and spin-relaxation and, more importantly, about the anisotropy not only of the studied isotope, but also of elements interacting with this isotope; (iii) isostructural analogues with all the available (i. e. not Pm) 4 f ions can be synthesised, enabling a systematic survey of the influence of the 4 f ion on the electronic structure; (iv) this cluster type is obtained by reacting [FeIII3O(O2CR)6(L)3](X) (X=anion, L=solvent such as H2O, py) with an ethanolamine-based ligand L′ and lanthanide salts. This allows to study analogues of [FeIII2Ln2(μ3-OH)2(L′)2(O2CR)6] using the appropriate iron trinuclear starting materials. (v) the organic main ligand can be readily functionalised, facilitating a systematic investigation of the effect of organic substituents on the ligands on the magnetic properties of the complexes. We describe and discuss 34 {MIII2Ln2} (M=Fe or in one case Al) butterfly compounds which have been reported up to 2020. The analysis of these gives perspectives for designing new SMM systems with specific electronic and magnetic signatures 相似文献
969.
Anomalous energy loss distributions of l48Gd alpha particles have been observed in heavily implanted thin aluminium films. It is surmised that thin film micro-wrinkling is responsible for the observed effect and that the novel technique of energy loss spectral analysis (ELSA) should be useful in studies of the topography of such films. 相似文献
970.