高纯氧化钆中14种稀土杂质元素的柱色谱分离ICP-AES法测定

用Ｐ５０７萃淋树脂柱色谱法分离高纯氧化钆基体与稀土杂质。用ＩＣＰ－ＡＥＳ法测定高纯氧化钆中微量稀土杂质。选择了柱色谱分离的合适条件。优化了仪器测定参数。使本方法测定稀土总量下限小于１×１０－５％。可以满足９９．９９９９％高纯氧化钆的测定。此方法回收率在８５％－１１０％之间。相对标准偏差小于１８％。     

噻胺酮麻醉剂对鼠S180肿瘤31P MRS的影响

对实验动物肿瘤进行活体³¹P MRS研究首要的是有效地固定动物.本文初步研究了用噻胺酮麻醉后的小鼠S180肿瘤在麻醉过程中³¹P MRS随时间的变异性.研究发现噻胺酮是一个安全系数高、起效快、麻醉过程适宜且对肿瘤的³¹P MRS无显著影响的麻醉药.因而噻胺酮适用于连续测定³¹P MRS的需要.     

锡(Ⅳ)-偶氮邻苯二酚苯基荧光酮-吐温-80体系分光光度法测定岩石中微量锡

pH值在7.0-8.5的范围内，锡与偶氮邻苯二酚苯基荧光酮、吐温－80形成络合物，其最大吸收峰556nm，摩尔吸光系数2.9×10^5L·mol^-1·cm^-1，锡的含量在0－6μg/25mL范围内遵守比耳定律，本方法对干扰离子的影响和消除进行了研究，本方法已被用于岩石样中锡的测定，结果满意。     

En">Characters and Composition Factor Multiplicities for the Lie Superalgebra $${\mathfrak{g}}{\mathfrak{l}}$$ ( m / n )

The multiplicities a of simple modules L in the composition series of Kac modules V lambda for the Lie superalgebra (m/n ) were described by Serganova, leading to her solution of the character problem for (m/n ). In Serganova's algorithm all with nonzero a are determined for a given this algorithm, turns out to be rather complicated. In this Letter, a simple rule is conjectured to find all nonzero a for any given weight . In particular, we claim that for an r-fold atypical weight there are 2r distinct weights such that a = 1, and a = 0 for all other weights . Some related properties on the multiplicities a are proved, and arguments in favour of our main conjecture are given. Finally, an extension of the conjecture describing the inverse of the matrix of Kazhdan–Lusztig polynomials is discussed.     

紫杉醇治疗小鼠S180肉瘤的体内31P MRS研究

为了研究紫杉醇治疗小鼠S180肉瘤的³¹P MRS参数的变化及这些参数的变化是否早于常规观察的瘤体积的变化.方法:利用表面线圈³¹P NMR方法,研究小鼠皮下接种的S180肉瘤.结果:用药48h后给药组的PCr/Pi、β-NTP/Pi、PME/β-NTP比值与对照组有显著性差别(P<0.05),而肿瘤体积在给药组和对照组之间无显著性差别,³¹P MRS参数的变化早于瘤体积变化.结论:小鼠S180肉瘤³¹P MRS不仅可以给出定量的结果,而且可以较早地显示出治疗的效果.     

级联二阶非线性法布里-珀罗谐振腔特性分析

在小信号近似下,得出了级联二阶过程的表达式。利用该式的有效三阶极化率的表达式,讨论了存在二阶非线性光学晶体的法－珀谐振腔的非线性光学特性。分析表明,由于谐振腔的存在,通过非线性晶体的功率密度超过入射功率密度几十倍以上,因而产生较大的、随相位失配变化的非线性相位漂移。当相位失配接近２π时,获得基叔光的最大相位漂移。该最大相位漂移对应的相位失配随着入射功率密度、非线性晶体的地阶极化率和晶体长度而变化。     

基于次谐波调制光注入半导体激光器获取窄线宽微波信号的实验研究

实验研究了处于单周期振荡的光注入半导体激光器在频率等于单周期振荡频率一半的1/2次谐波调制下所产生的微波信号的特性.实验结果显示:在合适的注入条件下,处于单周期(P1)振荡的光注入半导体激光器可输出频率可达26.5 GHz、光谱具有单边带结构的光生微波信号,但微波信号的线宽比较宽(MHz量级);通过采用频率为单周期振荡频率一半的次谐波信号调制光注入半导体激光器,可将微波线宽从十几MHz压缩到几十k Hz.进一步分析了次谐波调制信号的功率以及频率对微波信号的相位噪声的影响,并在由次谐波调制信号的功率和频率构成的参数空间绘制出了能实现次谐波频率锁定的分布区域.     

基于串联哑铃型微环谐振腔的二维相干光码分多址编解码器

利用微环谐振腔阵列进行光码分多址编解码过程中,微环谐振腔反射谱的自由频谱宽度(FSR)范围制约该系统用户容量的提升.本文提出了一种新型的基于游标效应的串联哑铃型微环谐振腔光编解码器.利用Matlab建立了半径分别为40μm-30μm-40μm的哑铃型微环谐振腔光编解码器模型.详细分析了光反射谱伪模抑制与耦合系数的关系,研究了耦合系数、码片速率对串联哑铃型微环谐振腔光编解码器性能的影响.结果表明,与半径分别为40μm-40μm-40μm的传统串联微环谐振腔编解码器相比,哑铃型微腔编解码器FSR值扩大了4倍.理想情况下,用户容量可呈指数增长.同时,互相关峰值比(P/W)与自相关峰值旁瓣比(P/C)分别提高了约33%和8%.     

Improved dielectric and AC conductivity properties of P(VDF-TrFE)-Nafion blends for high-temperature flexible capacitor applications

The free-standing poly (vinylidene fluoride-trifluoroethylene) [P(VDF-TrFe)] and P(VDF-TrFe)-Nafion blended films were fabricated using the casting method. The XRD and FTIR confirmed the electro-active β-phase of P(VDF-TrFe). The morphological changes were studied through SEM analysis of the blends. The dielectric and ac conductivity measurements were carried out as a function of temperature from 30 °C to 130 °C in the frequency range of 100 Hz - 1 MHz. The dielectric constant reveled a ferroelectric to paraelectric transition in all the samples with a decrease in the transition temperature of the blends. The temperature-dependent ac conductivity and power law analysis demonstrated the presence of a correlated barrier hoping mechanism with a change in the motional behavior in the blends. The blended films exhibited low dielectric loss and more stable dielecric properties with temperature in comparison to P(VDF-TrFe). These films demonstrated the potential to be used in high-temperature flexible capacitor applications.     

1D and 2D solid state NMR investigations of the framework structure of As-synthesized AlPO4-14

The framework structure of As-synthesized A1PO₄-14 has been investigated with a combination of different one-dimensional ²⁷Al and ³¹P solid state NMR techniques and ²⁷Al/³¹P double resonance methods. The results are found to be fully consistent with the assumed structural model. ²⁷Al MAS and DOR experiments at three different magnetic field strengths together with simulations show the presence of two tetrahedral sites, one pentacoordinated and one octahedral aluminum site. The ²⁷Al quadrupolar coupling constants and the ³¹P isotropic chemical shifts of the tetrahedral sites correlate well with tetrahedral shear-strain parameters and mean P-O-A1 bond angles, respectively. These correlations allow one to assign all of the NMR resonances to specific T-sites in the proposed framework structure. The assignments are then further confirmed by the application of three different two-dimensional heteronuclear correlation methods (i.e., ²⁷Al → ³¹P TEDOR, CP, and INEPT) which reveal the connectivities between AlO_x and PO₄ polyhedra. The two-dimensional INEPT experiment is applied here for the first time in the solid state.