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21.
A. Hollnder J. E. Klemberg-Sapieha M. R. Wertheimer 《Journal of polymer science. Part A, Polymer chemistry》1995,33(12):2013-2025
The emission from low-pressure microwave plasmas in the vacuum-ultraviolet (VUV) region (λ < 200 nm) was investigated in order to use these plasmas as light sources for the study of the VUV photochemistry of polyethylene (PE) and polypropylene (PP) as part of the study of plasma-polymer interaction. These polymers, immersed in low-presure oxygen, were exposed to radiation with wavelengths down to 112 nm, the cut off of magnesium fluoride used as a window to separate the polymer specimen from the plasma light source. Total oxygen incorporation in the surface [O], and the formation of hydroxyl, carbonyl, and carboxyl groups were measured using XPS in combination with chemical derivatizations, particularly their dependence upon the radiation spectrum and the oxygen pressure around the sample. In most experiments the surface oxygen concentration [O] attained a constant value that appears to be related to the initial oxidation rate; this suggests a competition between oxygen incorporation and chain scission reactions, followed by the removal of volatile oxidation products. PE is usually oxidized to a higher level than PP, the latter appearing to be more susceptible to reaction with atomic oxygen than PE. A general initiation mechanism for the VUV experiments is proposed that allows us to explain the observed differences in behavior between PE and PP, and the results obtained under different irradiation conditions. The nature of oxidation products is in both cases very similar to what is observed after direct plasma treatment of the polymers. We conclude that short wavelength radiation contributes very appreciably to the observed surface modification effects during plasma treatment of PE and PP. © 1995 John Wiley & Sons, Inc. 相似文献
22.
Polypropylene (PP) is one of the most common plastics used in the manufacturing of lead-acid battery cases, where the recycling of the material has become common practice, being both economically viable and environmentally friendly. During the recycling process, the various components of the spent battery are separated, where the crushed battery case is washed in order to remove any excess acid and lead-containing particles. The plastic components are subsequently melted and extruded into pellets that are then blended with virgin material to injection mold new battery cases and lids. This study showed that a significant amount of lead-containing particles in the form of lead dioxide and lead sulfate remain in the recycled plastic, and are evenly distributed throughout the polymer matrix. TEM studies showed that the particles are less than 1 μm in size and X-ray diffraction analysis of ashed recycled PP samples showed the presence, amongst others, of talc, calcium carbonate, rutile and iron oxide. These compounds come from a range of fillers, flame-retardants, colorants and impurities that originated from the various original battery cases that were recycled. The study showed that modern X-ray fluorescence (XRF) analysis is a quick and reliable method to quantify the amount of the elements found in the plastic and that the concentration of Pb in the plastic can be used as a type of “tracer” to determine the amount of recycled PP used in the manufacturing of a particular battery case. The study also showed that there is possible environmental contamination, in particular with Pb and Br contained in recycled PP during the injection molding process and the burning of the plastic. The Pb- and Br-containing particles are small enough to become air-borne during the burning process of the plastic, resulting in them being part of the soot and other hydrocarbon oils that are emitted. No Pb was observed in the gases emitted during simulated low-temperature injection molding conditions; however, a significant amount of Br was detected in the gases at the lower temperatures. Clear environmental waste classification of the battery case plastic should be done before its final incineration where the amount of trace metals present and its possible contamination to the environment should be considered. Care should also be taken for machine operators who work with the recycled plastic, that no excessive exposure to the halogenated compounds is experienced. 相似文献
23.
The General Rate model has been developed and solved to describe protein adsorption in an expanded bed. The model takes into account axial and local variation of particle size distribution (PSD), external and intra-particle mass transfer resistances, and dispersion in liquid phase. The influence of PSD on breakthrough profiles has been analysed. The simulation results show that for a significantly high expanded bed the lower part of the breakthrough curve profiles, calculated for local particle size distribution (LPSD) and for axial average particle size distribution (APSD) are very similar. However, the upper part of breakthrough profiles calculated for LPSD approaches inlet concentration much more slowly than those calculated for APSD. The retention times of the lower part of uptake curves calculated with average particle diameter are constantly shorter than those obtained from LPSD. For the calculation of the dynamic capacity (DC), the LPSD can be replaced by APSD for large expanded bed heights. Using breakthrough profiles calculated for average particle size, DC values are constantly underestimated. 相似文献
24.
The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”. 相似文献
25.
以聚丙烯微孔膜为基材,通过扩散控制原位共聚合的方法在人填充了组成沿膜的厚度方向逐渐改变的无规共聚物,X-光电子能谱(XPS)、全反射红外光谱(ATR)以及动态粘弹谱的分析结果。说明所制备得到的合膜具有明显的渐变聚合物性质。 相似文献
26.
Overall isothermal melt-crystallization and subsequent melting behavior of metallocene-catalyzed syndiotactic polypropylene resins of various molecular weights were investigated using differential scanning calorimetry (DSC) technique. Two sets of molecular weight range were synthesized with two different metallocene catalyst systems. The kinetics of the overall isothermal melt-crystallization process was analyzed based on various macrokinetic models, i.e. the Avrami, Malkin and Urbanovici-Segal models. The effective activation energy describing the overall isothermal crystallization process over the crystallization temperature range studied was estimated based on an Arrhenius approximation of the obtained Avrami crystallization rate constants. The equilibrium melting temperature for each of these resins was estimated based on the linear and non-linear Hoffman-Weeks extrapolative methods. 相似文献
27.
Samples of thermal bonded polypropylene non-woven fabrics were exposed to light from two TUV 30W G30T8 Philips lamps (λ = 253.7 nm) in a covered open-air chamber at room temperature (25 °C and 55% relative humidity) for different periods of time. In order to determine the state of degradation, the samples were examined by optical microscopy, scanning electron microscopy, staining with an isopropanol solution of methylene blue and Sudan III, colourimetry, Fourier transform infrared (FTIR) spectroscopy and density measurements. Although the bonded areas formed under complex thermal and mechanical deformations during the fabric production, no localized staining was observed. The colour of the irradiated and stained fabrics changed uniformly due to the even production of polar groups in the process of irradiation. It was found that the change of redness and blueness of degraded and stained samples can be correlated linearly with the evolution of POOH groups as determined by FTIR spectroscopy. Products containing carbonyl (CO), hydroxyl and/or hydroperoxide (POOH) groups increase with time of degradation with a non-linear relation. It was also observed that the density and 997 cm−1/972 cm−1 FTIR absorbance ratio increases with degradation time. Density fluctuation and the build up of degradation products caused fibre cracks and embrittlement. 相似文献
28.
J.?MajumdarEmail author F.?Cser M.?C.?Jollands R.?A.?Shanks 《Journal of Thermal Analysis and Calorimetry》2004,78(3):849-863
Differential scanning calorimetry has been used to study the heat flow during melting and crystallisation of a range of polypropylene post-consumer waste (PP PCW) grades and blends. The heat flow curves and the heat capacity curves indicated that the PP PCW grades and blends contained contaminants even after manual sorting and a cleaning process. The enthalpies of the PP PCW grades were lower than that for the virgin grades, as a result of degradation. Small amounts of polymeric contaminants (up to 10%) did not affect the enthalpies of PP PCW although other contaminants may have had some effect. The enthalpies of the PCW blends could in general be predicted by a linear additive rule, which is of importance for recycling a variety of PP PCW products.The authors would like to thank Dr. M. Killen (Basell Australia Pty. Ltd.), Mr. P. Slaven (Citiwide MRF), Dasma Valley Waste Prop. Ltd. and Mr. I. Janetzki (Huhtamaki Australia Ltd.) for supplying materials for this project. Financial support for the project was provided by Basell Australia and Ecorecycle Victoria, Australia. 相似文献
29.
HIPS/PP熔融反应共混及其动态力学性质 总被引:2,自引:0,他引:2
研究了高抗冲聚苯乙烯(HIPS)/聚丙烯(PP)共混物在过氧化二异丙苯(DCP)存在下的熔融反应过程及其动态力学性质.HIPS在DCP存在下以聚苯乙烯(PS)的降解为主,伴随着聚丁二烯(PB)的交联和接枝,PP在DCP存在下以降解为主,HIPS/PP在DCP存在下以PP同HIPS的反应接枝为主,这种原位生成的增容剂显著地改善了HIPS/PP两组份间的相容性,其分子运动特征较前两者发生明显变化,PS的Tg下降,PB和PP的Tg升高. 相似文献
30.
Polypropylene (PP) has become an indispensable material in our daily lives. Annual worldwide production of PP is now more than 30000000 tons and is predicted to grow at an annual rate of about 6% during the first decade of the 21st century. Commercial production of PP began in 1957 with the use of TiCl(3) catalysts established by Ziegler and Natta. However, the low activities and low stereospecificities of the catalysts resulted in large amounts of catalyst residue and atactic PP in the product, necessitating steps for their removal in commercial production. As a means of finding appropriate catalysts, we developed MgCl(2)-supported TiCl(4) catalysts, which basic concept was introduction of organic compounds onto the inorganic crystal catalyst surface. This addition led to remarkable enhancements in stereospecificity with extremely high activity. Use of the new catalysts enlarged and simplified the PP production process by eliminating the steps previously required for removal of catalyst residue and atactic PP. In addition, it greatly improved the properties of the PP, enabling a much wider range of PP applications by replacing metal and engineering plastics with the highly stereoregular PP. Therefore, these catalysts helped the rapid establishment of the current PP industry and now play a major role in production. The latest MgCl(2)-supported TiCl(4) catalyst is providing precise control of the isotactic PP structure. Future expectations for this type of catalyst are to acquire a single-site nature and to contribute to the creation of a new class of hybrid materials. 相似文献