全文获取类型
收费全文 | 8848篇 |
免费 | 1642篇 |
国内免费 | 1231篇 |
专业分类
化学 | 5337篇 |
晶体学 | 317篇 |
力学 | 580篇 |
综合类 | 77篇 |
数学 | 71篇 |
物理学 | 5339篇 |
出版年
2024年 | 13篇 |
2023年 | 38篇 |
2022年 | 149篇 |
2021年 | 157篇 |
2020年 | 221篇 |
2019年 | 201篇 |
2018年 | 194篇 |
2017年 | 279篇 |
2016年 | 388篇 |
2015年 | 342篇 |
2014年 | 391篇 |
2013年 | 762篇 |
2012年 | 551篇 |
2011年 | 797篇 |
2010年 | 643篇 |
2009年 | 689篇 |
2008年 | 649篇 |
2007年 | 714篇 |
2006年 | 760篇 |
2005年 | 555篇 |
2004年 | 469篇 |
2003年 | 460篇 |
2002年 | 415篇 |
2001年 | 297篇 |
2000年 | 266篇 |
1999年 | 235篇 |
1998年 | 186篇 |
1997年 | 169篇 |
1996年 | 120篇 |
1995年 | 133篇 |
1994年 | 113篇 |
1993年 | 70篇 |
1992年 | 67篇 |
1991年 | 45篇 |
1990年 | 31篇 |
1989年 | 27篇 |
1988年 | 35篇 |
1987年 | 18篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 14篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1973年 | 3篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Non-stoichiometric ternary chalcogenides (Zn,Fe)S were prepared in the film form by pyrolytic spray deposition technique, using air/nitrogen as the carrier gas. The precursor solution comprised of ZnCl2, FeCl2 and thiourea. The depositions were carried out under optimum conditions of experimental parameters viz. carrier gas (air/nitrogen) flow rate, concentration of precursor constituents, nozzle substrate distance and temperature of quartz substrate. The deposited thin films were later sintered in argon at 1073 K for 120 min.The structural, compositional and optical properties of the sintered thin films were studied. X-ray diffraction studies of the thin films indicated the presence of (Zn,Fe)S solid solution with prominent cubic sphalerite phase while surface morphology as determined by scanning electron microscopy (SEM) revealed a granular structure.The chemical composition of the resulting thin films as analyzed by energy dispersive X-ray analysis (EDAX) reflected the composition of the precursor solutions from which the depositions were carried out with Fe at% values ranging from 0.4 up to 33.SEM micrographs of thin films reveal that the grain sizes of the thin films prepared using air as carrier gas and N2 as carrier gas are in the vicinity of 300 and 150 nm, respectively.The diffuse transmittance measurements for thin films, as a function of wavelength reveal the dependence of direct optical band gap on Fe content and type of phase. 相似文献
12.
Thin films of, N-N′diphenyl 1-4phenylene-diamineane are prepared using vacuum sublimation technique. The electrical conductivity from room temperature down to 127 K is studied. It is found that the conduction of charge carriers obeys T−1/2 dependence on temperature. The average hopping distance, hopping energy, density of states and their variation due to post-deposition heat treatment are studied. Schottky diodes are fabricated with gold as ohmic contact and aluminium as Schottky contact. From the observed current voltage characteristics the saturation current density, diode ideality factor and the barrier height are determined. Their variation with air annealing is also investigated. 相似文献
13.
14.
15.
V. V. Kuznetsov N. V. Morozova V. N. Kudryavtsev 《Russian Journal of Electrochemistry》2006,42(6):665-669
Dependences of the current and the chemical composition of cathodic deposits on the electrolysis time are studied in an ammonia-citrate electrolyte for the deposition of a nickel-molybdenum alloy in potentiostatic conditions. At potentials less negative than ?0.93 V, no nickel-molybdenum alloy deposition occurs and in the course of electrolysis there is observed a decrease in the current, which is connected with the blocking of the electrode surface by the formed molybdenum oxides. In the region of potentials of deposition of a nickel-molybdenum alloy there is realized the following shape of a time dependence of the current. Within the first few seconds of the electrolysis process, the current somewhat decreases. Then there occurs its increase, which is connected with the alloy deposition on the cathode. In the course of electrolysis there occurs a decrease in the molybdenum content in the cathodic deposit. 相似文献
16.
P. Adamson 《Optics & Laser Technology》2002,34(7):561-568
The differential reflection characteristics for ultrathin inhomogeneous dielectric film on absorbing substrate are investigated in the long-wavelength approximation. The obtained first-order expressions for differential reflectivity and changes in the ellipsometric angles caused by ultrathin layer are of immediate interest to the solution of the inverse problem. The method to determine the averaged values (not the realistic profile) of refractive index for inhomogeneous nanometric films are shown. The novel possibilities for determining the dielectric constant and thickness of nanoscale homogeneous films by the differential ellipsometric and reflectivity measurements are developed, and a simple method to estimate whether the nanometric film is homogeneous or not is also discussed. 相似文献
17.
根据Co P非晶态合金结构的短程有序和结构中可能存在P -P相互作用的实验事实 ,选择了单磷原子簇模型ConP(n =1~ 5 )和双磷原子簇模型ConP2 (n =1~ 4 ) ,用密度泛函理论方法对其进行计算 .结果表明 ,在单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型体系中 ,Co原子供给P原子电子 ,与电负性规则一致 ,同时Co和P之间具较强化学作用 ,可以形成稳定的原子簇 ;而在双磷和单磷原子簇Co5P( 1) 模型体系中 ,形成的原子簇不稳定 ,采用单磷Co2 P( 2 ) 、Co3 P( 1) 及Co4P( 2 ) 模型能较好地反映Co P非晶态合金的结构特点 . 相似文献
18.
ZHU Yabin ZHOU Yueliang LIU Zhen WANG Shufang CHEN Zhenghao U Huibin YANG Guozhen XlAO Ling Ren Hongtao JIAO Yulei Zheng Minghui 《中国科学G辑(英文版)》2004,47(2):165-172
The irreversibility field (Hirr) of Y-based superconductor is much higher than that of Bi-based superconductor. Y-based superconductor is capable of maintaining stable electrical currents in high magnetic field and electric field, so it is a better suited mate-rial for electric-current applications. Commonly, the Y-based tapes comprise a YBCO thick film deposited on a flexible substrate, typically with an intermediate buffer layer, and an overcoat of noble metal. In this process, the interm… 相似文献
19.
Non-isothermal short-range-order kinetics of binary alloys as influenced by solute-vacancy complexes
A model describing the roles of bound and unbound vacancies is proposed in order to predict defect decay and short-range-order
kinetics of quenched binary alloys during linear heating experiments. This is an alternative treatment of a previous approach.
The model has been applied to the differential scanning calorimetry (DSC) curves of Cu-5 at.% Zn quenched from different temperatures.
An expression to calculate the activation energy for migration of solute-vacancy complexes was also developed which make use
of DSC trace data. A value of 89.12±0.32 kJ mol-1 was obtained for the above alloy. The relative contribution of bound and unbound vacancies to partition of effective activation
energy corresponding to the ordering process as influenced by quenching temperature was also assessed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
20.
Jacek Doskocz Jadwiga Sołoducho Joanna Cabaj Mieczysław Łapkowski Sylwia Golba Krystyna Palewska 《Electroanalysis》2007,19(13):1394-1401
A convenient and higher yielding synthetic route to N‐alkyl‐bis(thiophene)phenothiazine derivatives is reported and their aggregation, electrochemical properties and polymerization are characterized. The key step in the synthesis of this group of compounds has been the Stille type coupling reaction between the N‐alkyldibromophenothiazine and tin derivatives of thiophene as the best way for preparation of conjugated N‐alkylphenothiazine derivatives. For this group of compounds we also present an electrochemical polymerization effect and widely adopted approach to prepare structurally ordered thin, electroconducting films by Langmuir–Blodgett technique. 相似文献