电热蒸发进样微波等离子体炬原子发射光谱法中共存元素的影响

本文考察了以微波等离子体炬（MPT）为光源，电热钽丝环进样时，溶液中共存元素对发射信号的影响。     

Magnetic relaxation phenomena in a CuMn spin glass

Experiments on the temperature and time dependence of the response function and the field cooled magnetisation of a Cu(Mn) spin glass at temperatures below the zero field spin glass temperature are used to explore the non-equilibrium nature of the underlying spin configuration. The results imply that a certain spin configuration is imprinted on the system as the temperature is decreased at a constant cooling rate. The cooling rate governs the magnitude of the FC magnetisation ((H,T)). Any intermittent halt at a constant temperature, , imprints an extended spin configuration, a process that is reflected e.g. in a downward relaxation of . On continued cooling at the same rate, the magnitude of (T) remains at a lower level than that of a continuous cooling curve. These results are put into the context of the corresponding behaviour of the response function as observed in measurements of the relaxation of the zero field cooled magnetisation. Received 27 October 1998 and Received in final form 30 November 1998     

Diffusional coagulation of superparamagnetic particles in the presence of an external magnetic field

In this paper, we investigate the diffusional coagulation of colloidal superparamagnetic (SP) latex particles that are under the influence of an external magnetic field. The cluster size distributions (CSDs) that evolve with time were determined using an optical set-up that permits the direct visualization of particle clusters. Following the dynamic scaling analysis of van Dongen and Ernst (Phys. Rev. Lett. 54 (1985) 1396), we find that the CSDs all collapse onto a master curve when properly scaled. The bell-shape of this master curve indicates that large clusters preferentially scavenge small clusters in our system. From the time evolution of the average cluster size we infer that the reactivity between large clusters diminishes with increasing cluster size. These results are consistent with a simple mathematical formulation of the coagulation rate constant, or kernel, for the Brownian coagulation of magnetic particles. Moreover, our results support a growing body of evidence that the dynamic scaling theory developed by van Dongen and Ernst is a useful framework with which to study the microscale processes governing particle coagulation.     

Antiferromagnetic Potts Models on the Square Lattice: A High-Precision Monte Carlo Study

We study the antiferromagnetic q-state Potts model on the square lattice for q=3 and q=4, using the Wang–Swendsen–Kotecký (WSK) Monte Carlo algorithm and a powerful finite-size-scaling extrapolation method. For q=3 we obtain good control up to correlation length 5000; the data are consistent with ()=Ae ^{2 p} (1+a ₁ e ^– + ...) as , with p1. The staggered susceptibility behaves as _stagg ^5/3. For q=4 the model is disordered (2) even at zero temperature. In appendices we prove a correlation inequality for Potts antiferromagnets on a bipartite lattice, and we prove ergodicity of the WSK algorithm at zero temperature for Potts antiferromagnets on a bipartite lattice.     

Multiple ionization of argon in coincidence with projectile ions in 60–120 MeV Si q+-Ar collisions

A projectile ion-recoil ion coincidence technique has been employed to study the multiple ionization and the charge transfer processes in collisions of 60–120 MeV Si ^q+ (q = 4−14) ions with neutral argon atoms. The relative contribution of different ionization channels, namely; direct ionization, electron capture and electron loss leading to the production of slow moving multiply charged argon recoil ions have been investigated. The data reported on the present collision system result from a direct measurement in the considered impact energy for the first time. The total ionization cross-sections for the recoil ions are shown to scale as q ^1.7/E _p ^0.5 , where E _p is the energy in MeV of the projectile and q its charge state. The recoil fractions for the cases of total- and direct ionizations are found to decrease with increasing recoil charge state j. The total ionization fractions of the recoils are seen to depend on q and to show the presence of a ‘shell-effect’ of the target. Further, the fractions are found to vary as 1/j ² upto j = 8+. The average recoil charge state 〈j〉 increases slowly with q and with the number of lost or captured electrons from or into the projectile respectively. The projectile charge changing cross-sections σ _qq′ are found to decrease with increasing q for loss ionization and to increase with q for direct-and capture ionization processes respectively. The physics behind various scaling rules that are found to follow our data for different ionization processes is reviewed and discussed.     

Characterization and investigation of the unique plasma behavior caused by variable driving frequencies in the formation of cold atmospheric plasma

The study presents the characterization of a novel variable frequency (11–50 kHz) Atmospheric Pressure Plasma Jet (APPJ) source and comparison of the results with 13.56 MHz source, in terms of species generation and species temperature. The behavior of variable frequency APPJ at different frequency regimes was investigated using optical emission spectroscopy to understand the interaction with the ambient environment. The quantitative dependence of the radical generation on driving frequency and time of treatment was also analyzed by direct synthesis of H₂O₂ by plasma-water interaction. The plasma formed with a kHz driving frequency had a low treatment temperature, which was suitable for biological species, but the plasma generated with a 13.56 MHz driving frequency had a substantially higher radical density than the kHz plasma. As a result, the APPJ device's ability to tune the radical density and treatment temperature with a change in kHz frequency has been demonstrated.     

A numerical method to compute exactly the partition function with application toZ(n) theories in two dimensions

I present a new method to exactly compute the partition function of a class of discrete models in arbitrary dimensions. The time for the computation for ann-state model on anL ^d lattice scales like . I show examples of the use of this method by computing the partition function of the 2D Ising and 3-state Potts models for maximum lattice sizes 10×10 and 8×8, respectively. The critical exponentsv and and the critical temperature one obtains from these are very near the exactly known values. The distribution of zeros of the partition function of the Potts model leads to the conjecture that the ratio of the amplitudes of the specific heat below and above the critical temperature is unity.     

Inverse problems of aggregation processes

The coagulation frequency is the key ingredient in the population balance (Smoluchowski) equation of coagulation kinetics. An inverse problem is formulated to extract the coagulation frequency from transient size distributions when these distributions are self-similar. Two numerical examples illustrate the procedure. The first demonstrates the inverse problem for the recovery of singular coagulation frequencies, while the second shows the procedure when self-similarity is approximate. Transient droplet coagulation experiments in a turbulent flow field have been performed. The resulting size distributions are observed to be self-similar. The inverse problem is used to determine the drop coagulation frequency. This frequency shows significant deviation from the coagulation frequencies derived from simple models of drop-drop interactions in a turbulent flow field.     

An investigation of finite-size scaling for systems with long-range interaction: The spherical model

A method is suggested for the derivation of finite-size corrections in the thermodynamic functions of systems with pair interaction potential decaying at large distancesr asr ^{–d –} , whered is the space dimensionality and>0. It allows for a unified treatment of short-range (=2) and long-range (<2) interaction. The asymptotic analysis is illustrated by the mean spherical model of general geometryL ^d–d× ^d subject to periodic boundary conditions. The Fisher-Privman equation of state is generalized to arbitrary real values ofd, 0d. It is shown that the-expansion may be used to study the breakdown of standard finite-size scaling at the borderline dimensionalities.