Metal-Support Interaction Which Controls the Oxidation State, Structure and Catalysis of Pd

A metal-support interaction between Pd and various kinds of zeolite and metal oxide supports was studied, which were active in the catalytic combustion and selective reduction of NO. The acid-base properties of supports affected the oxidation state, structure and catalytic activity of Pd. The acid sites of zeolite played the role to anchor the dispersed PdO as evidenced by the dynamic structural change of Pd. It was found that the metal-support interaction is an important factor, affecting the oxidation state, structure and catalytic performance of Pd.     

Evaluation of thermodynamic functions relative to cavity formation in aqueous solutions

The results of calculation of free Gibbs energy and enthalpy of cavity formation were described using the Scaled Particle and Sinanoglu's theories.

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Zusammenfassung Mittels der zitierten Theorien wurden die Resultate der Berechnung der freien Gibbs'schen Energien und Enthalpien für die Hohlraumbildung beschrieben.

     

带交互作用测度值分枝过程的绝对连续性

本文研究Meleard-Roelly（1992，1993）和Metivier（1987）构造的带交互作用的测度值分枝过程的状态性质．我们证明在自然假设下该过程关于Lebesgue测度是绝对连续的，其密度有连续修正且满足一个随机偏微分方程．     

Superthermal Electron Produced in Relativistic Laser-Plasma Interaction

The dynamics of a relativistic electron submitted to an intense, plane wave, linearly polarized laser field is reviewed. Based on the dynamics, the temperature of the electron in the laser field is delined and calculated. It is found that the calculated temperature fits the first temperature observed in the experiment by Malka et al. A model to evaluate the electron temperature by taking the electron-ion scattering into account is proposed. It is found that when I ≥ 4.0 × 101s W/cm2 the electron temperature by considering the scattering, T hs, is evidently larger than the electron temperature without considering the scattering, Th. This result is in favor of explaining the two-temperature distribution of the electron energy observed in the experiment by Malka et al.     

Numerical simulation of Richtmyer-Meshkov instability

The compressible Navier-Stokes equations discretized with a fourth order accurate compact finite difference scheme with group velocity control are used to simulate the Richtmyer-Meshkov (R-M) instability problem produced by cylindrical shock-cylindrical material interface with shock Mach number Ms=1.2 and density ratio 1:20 (interior density/outer density). Effect of shock refraction, reflection, interaction of the reflected shock     

基于流固耦合理论的长寿命陀螺仪浮子内部流场及温度场分析

为精确计算出陀螺仪内部温度场,有效改善影响陀螺仪精度的温度梯度分布状况,采用了精度更高的流固耦合计算方法,结合FLUENT软件,对卫星等上使用的某型长寿命陀螺仪浮子组件进行了内部流场及温度场计算。结果表明,浮子内部结构形式对高速旋转的电机产生的介质流场有较大影响,合理的结构设计有利于降低电机功耗;陀螺仪浮子表面存在最大温差为0.52℃的温度梯度,其所产生的液流力矩会对陀螺仪精度产生一定影响;浮子表面温度分布表现出一定的对称性和规律性。计算结果为下一步旨在减小温度梯度、提高陀螺仪精度的精密分区温控提供了数据基础。     

A modal analysis for the dynamic response of fluid-structure systems

In this paper a theory of modal analysis for the dynamic response of fluid-structure systems is presented. A pair of generalized eigenvalue equations with three real symmetric matrices and their relationships are derived from the finite element equations in the form of structural displacements and fluid velocity potential. Generalized orthogonality relations of modal vectors are then developed. The response of the system to external excitation is derived in closed form by modal expansion. Two examples of the solution are given for illustration.     

Metastable states in homogeneous Ising models

Metastable states of homogeneous 2D and 3D Ising models are studied under free boundary conditions. The states are defined in terms of weak and strict local minima of the total interaction energy. The morphology of these minima is characterized locally and globally on square and cubic grids. Furthermore, in the 2D case, transition from any spin configuration that is not a strict minimum to a strict minimum is possible via non-energy-increasing single flips.     

Concentration-dependence of faradaic currents and conductivity in a polystyrene sulfonic latex suspension

The conductivity, κ, in a suspension of polystyrene sulfonic latex without supporting electrolyte showed a linear dependence on the volume fraction, v_f, of the latex for v_f<0.03 with a finite intercept. In contrast, this deviated upward from the linear line for v_f>0.03. These variations were qualitatively consistent with the dependence of the voltammetric reduction current of H⁺ on v_f without supporting electrolyte. The current values were only a few percent of the theoretical diffusion-controlled current that could be observed in the suspension with supporting electrolyte. This fact indicates the electrostatic immobilization of the hydrogen ions by sulfonic latex particles. A plot of the current against κ at common values of v_f showed that the current for v_f>0.07 was smaller than the value predicted from the conductivity. This can be explained in terms of a combination of the increase in electrostatically unbounded H⁺ estimated by conductance measurements and electric migration in which the electrochemical depletion of [H⁺] also causes the depletion of the latex.