Emission Spectra of BeO in Near Ultraviolet Region

Abstract

The emission spectra of isotopic BeO molecules as excited in low-pressure arc have been photographed in the region 300–350 nm at medium dispersion. The bands have been assigned to the c³II ? a³II system. The vibrational numbering was obtained from a study of the vibrational isotope effect. Vibrational constants for involved states are derived from least-squares fits of the measured bandhead wavenumbers.     

Ti和Al共掺杂ZnS的电子结构和光学性质

基于密度泛函理论的第一性原理研究Ti和Al单掺杂和(Ti,Al)共掺杂ZnS的能带结构、电子态密度分布、介电函数、光学吸收系数,分析了掺杂后电子结构与光学性质的变化.计算结果表明:掺杂后禁带中引入了新的杂质能级,费米能级进入导带.掺杂改变了ZnS晶体的导电特性,使它表现出金属特性,导电性能增强;与纯净ZnS相比,Ti单掺杂和(Ti,Al)共掺杂ZnS的吸收边均出现明显的红移,且在1.79eV左右出现了一个新峰;而Al单掺杂ZnS的吸收边则发生明显的蓝移,且不产生新的吸收峰.     

BaHf0.5Ti0.5O3电子结构与光学性质的第一性原理研究

基于密度泛函理论体系下的广义梯度近似（GGA）,利用第一性原理方法研究了BaHf0.5Ti0.5O3的电子结构和光学性质．计算结果表明,BaHf0.5Ti0.5O3是一种间隙的半导体材料,其导带底主要由Ba、Hf和Ti的d态电子构成,价带顶则主要由O的p态、Hf 和Ti的d态电子构成;理论计算的介电函数最高峰的峰位与实验结果吻合较好,相对误差小于4%;吸收系数最大峰值为2.43×105cm-1,且吸收主要集中在低能区,静态折射率为2.01,能量损失峰出现在13.24eV处．研究结果为BaHf0.5Ti0.5O3光电材料设计与应用提供了理论依据．     

Reflectivity measurements of superionic conductors for Li ion secondary battery materials

The reflection measurements of superionic conductors LiCoO₂ and Li_1-xCoO₂, which are already in use for the positive electrode material of 4 V rechargeable lithium batteries, have been performed in the millimeter wave region from 6 to 60 cm⁻¹ using the electron storage ring facilities of Institute of Molecular Science in Okazaki. The increase of the reflectivity has been observed in the low wavenumber region below 10 cm^-1 above 300 K in Li_1-xCoO₂ for the first time, while the reflectivity of LiCoO₂ has almost the constant value in all observed temperature region between 77 to 380 K. The results will be discussed in connection with our previous results of LiNiO₂.     

外来种喜旱莲子草的克隆生长特性

通过对外来种喜旱莲子草（Alternanthera philoxeroides（Mart．）Griseb）生长指标的测定和分析，研究了它的克隆生长规律，并探讨丁它的觅食行为．在一个生长季节内，喜旱莲子草生物量增加了近30倍，一级葡萄茎分株数增加了近50倍，最长的一级葡萄茎长度增长了近40倍，一级葡萄茎总长度增长了近13倍；一、二、三级葡萄茎上的总分株数增加了近130倍，3个级别匍匍苇总长度增长了近28倍．通过各级葡萄茎个数，葡萄茎总长度和葡萄茎总分株数比较发现，二级葡萄茎比一、二级葡萄苇生长的都要快，而一级葡萄茎的间隔物平均长度远远大于二级和三级葡萄茎．克隆植物的觅食行为与它的克隆生长紧密相连，从觅食行为来看，喜旱莲子草克隆构型随生长季节的变化说明了它对生长季节具有很强的适应性．这种快速克隆生长的特性和对生长季节的适应性有利于喜旱莲子成功入侵新的生境。     

Energy levels and spectral lines of Ne VIII

All experimental data on the valence-shell-excited and core-excited spectra of Li-like neon, including previously unpublished beam-foil spectroscopy data, have been compiled and critically evaluated. Seventeen spectral lines have been newly identified. Sets of recommended energy levels have been derived from the total list of observed lines and from selected results of theoretical and semi-empirical calculations. An accurate value of the ionization potential has been derived from existing theoretical calculations. Electronic supplementary material Online Material     

A multicriteria perspective on reverse auctions

This is a summary of the main contributions of the author’s PhD thesis. The thesis is written in English. It was supervised by Philippe Vincke and was defended on 20 December 2005 at the Université Libre de Bruxelles. A copy is available from the author upon request. The aim of this work is to investigate the use of a partial relations for bids’ comparisons in the context of multi-attribute auctions. At first a theoretical framework is developed. Then a specific model referred to as the butterfly model is presented. Finally the concept of bidding niches is formalized and related to the aforementioned model.      

Highly accurate solutions of the bifurcation structure of mixed‐convection heat transfer using spectral method

This paper is concerned with producing highly accurate solution and bifurcation structure using the pseudo‐spectral method for the two‐dimensional pressure‐driven flow through a horizontal duct of a square cross‐section that is heated by a uniform flux in the axial direction with a uniform temperature on the periphery. Two approaches are presented. In one approach, the streamwise vorticity, streamwise momentum and energy equations are solved for the stream function, axial velocity, and temperature. In the second approach, the streamwise vorticity and a combination of the energy and momentum equations are solved for stream function and temperature only. While the second approach solves less number of equations than the first approach, a grid sensitivity analysis has shown no distinct advantage of one method over the other. The overall solution structure composed of two symmetric and four asymmetric branches in the range of Grashof number (Gr) of 0–2 × 10⁶ for a Prandtl number (Pr) of 0.73 has been computed using the first approach. The computed structure is comparable to that found by Nandakumar and Weinitschke (1991) using a finite difference scheme for Grashof numbers in the range of 0–1×10⁶. The stability properties of some solution branches; however, are different. In particular, the two‐cell structure of the isolated symmetric branch that has been found to be unstable by the study of Nandakumar and Weinitschke is found to be stable by the current study. Copyright © 2002 John Wiley & Sons, Ltd.     

甲基多烯醛共轭体系电子光谱及线性关系的MHMO法研究

甲基多烯醛共轭体系电子光谱及线性关系的ＭＨＭＯ法研究马生元（青海民族学院化学系西宁８１０００７）关键词甲基多烯醛，电子光谱，线性关系，ＭＨＭＯ法有机共轭同系物的电子光谱有广泛的线性关系［１－３］，这是分子周期性结构的必然结果。分子电子光谱则是分子中轨...     

金属冲击温度测量中金属/窗口界面表观光谱辐亮度的再研究

 在冲击压缩下，理想接触的金属/窗口界面温度历史是时间无关的，因而一般认为界面的表观光谱辐亮度也是时间无关的。研究表明：（1）在冲击压缩下，将伴随金属对光的吸收系数减小和光学厚度增大。因此，在考虑辐射输运效应后，理想接触的金属/窗口界面处的表现光谱辐亮度是时间相关的。非常明显的时间相关过程自冲击波到达界面后持续约10 ns。（2）若把存在空间温度梯度的金属界面辐射看作是透光厚度内平均温度的等效辐射效应，其结果与辐射输运效应的计算结果是很相近的。