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101.
102.
103.
Syed A. Ali Mohammed A. Siddiqui and Mohammed A. Ali 《Reaction Kinetics and Catalysis Letters》2005,87(1):199-206
Summary A parametric study of catalytic reforming process in a pilot plant was carried out by varying the pressure, H2/HC ratio, and space velocity. The results show that lower aromatics and higher hydrogen yields can be accomplished by increasing
the space velocity in existing reformers, which will also result in better C5+yield. 相似文献
104.
105.
ZrO2在Cu-ZnO-ZrO2甲醇水蒸汽重整制氢催化剂中的作用 总被引:2,自引:0,他引:2
通过对一系列Cu-ZnO-ZrO2甲醇水蒸汽重整(SRM)催化剂的XRD、TEM和BET表征及催化性能测定,研究催化剂中ZrO2对催化剂粒径、比表面以及对SRM反应性能的影响.结果表明,ZrO2的加入,使催化剂的粒径从15 nm降至10 nm(其中CuO和ZnO的平均粒径分别从7.7和10.4 nm降至3.9和8.7 nm),BET比表面从60 m2•g-1增至78 m2•g-1.随着催化剂含ZrO2量不同,甲醇的转化率和H2、CO2的选择性均产生变化,当催化剂中Zr含量为24.0%(w),反应温度为220 ℃,水、醇摩尔比为1.3时,甲醇的转化率达到51.6%, H2和CO2的选择性达到100%(CO和CH4在产物气体中的体积分数小于10-4),这一结果对甲醇燃料电池甲醇重整器的应用具有重要的意义. 相似文献
106.
Characterization and electrochemical investigation of boron-doped mesocarbon microbead anode materials for lithium ion batteries 总被引:1,自引:0,他引:1
Mao-Hui Chen Guo-Tao Wu Guang-Ming Zhu Jin-Kua You Zu-Geng Lin 《Journal of Solid State Electrochemistry》2002,6(6):420-427
The structure and anodic performance of boron-doped and undoped mesocarbon microbeads (MCMBs) have been comparatively studied
and the results obtained by XPS, XRD, SEM, Raman spectroscopy and electrochemical measurements are discussed. It is found
that boron doping introduces a depressed d
002 spacing and the larger amount of "unorganized carbon", which induces vacancy formation in the graphite planes and leads to
a quite different morphology from that of the undoped material. Electrochemical charge/discharge cycle tests indicated that
after boron doping the lithium intercalation was carried through at a somewhat higher potential, being attended by greater
irreversible capacity loss.
Electronic Publication 相似文献
107.
Jiandong Zheng Xiaoguang Ren Yongji Song Guoliang Shen 《Reaction Kinetics and Catalysis Letters》2007,92(1):11-17
Manganese-substituted lanthanum hexaaluminates were prepared by the sol-gel method. The effect of water content on the catalyst
preparation was examined. Large water content caused a rapid decrease in the surface area. When the R (R is the mole ratio
of H2O/ Al(OC3H7)3) is equal to 1.5, the catalyst retains a specific surface area of 13.5 m2 g−1 and shows higher activity in CH4 combustion. 相似文献
108.
Qingde Zhang Yisheng Tan Caihong Yang Yizhuo Han Jun Shamoto Noritatsu Tsubaki 《天然气化学杂志》2007,16(3):322-325
The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40(40%)/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40(40%)/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40(40%)/SiO2. 相似文献
109.
Electrically conducting poly(3,4‐ethylenedioxythiophene) (PEDOT) film doped with silicomolybdate (SiMo12O404? or SiMo12) was synthesized by electrochemical polymerization. The synthesized film is capable of fast charge propagation during redox reactions in strong acid medium 0.2 M H2SO4 solution. The modified electrode was used towards reduction of bromate and successfully employed as an amperometric sensor for bromate and also above modified electrode was investigated for ascorbic acid oxidation. 相似文献
110.
Novel electrochemical synthesis and characterisation of poly(methyl vinylsilane) and its co-polymers
M. Elangovan 《European Polymer Journal》2005,41(10):2450-2460
The electrochemical synthesis and characterisation of poly(methyl vinylsilane) and a series of poly(methyl vinylsilane-co-metallocenes) network polymers are described in detail. This class of polymers are not accessible through Wurtz coupling reaction and are however prepared by electro-reduction of dichloro methyl vinylsilane in a non-aqueous system using aluminum electrodes in a single compartment cell. These polymers have been characterised using UV, FTIR, XRD, SEM and NMR spectral techniques. Cyclic voltammetric studies of the above polymers reveal their conducting behavior. These polymers show optical properties as explained from the results. Polymers of this type are proposed as potential soluble precursors for SiC and metal doped SiC materials. 相似文献