全文获取类型
收费全文 | 24513篇 |
免费 | 2738篇 |
国内免费 | 2121篇 |
专业分类
化学 | 15027篇 |
晶体学 | 586篇 |
力学 | 1053篇 |
综合类 | 128篇 |
数学 | 2083篇 |
物理学 | 10495篇 |
出版年
2024年 | 82篇 |
2023年 | 271篇 |
2022年 | 593篇 |
2021年 | 582篇 |
2020年 | 762篇 |
2019年 | 716篇 |
2018年 | 701篇 |
2017年 | 897篇 |
2016年 | 1107篇 |
2015年 | 998篇 |
2014年 | 1291篇 |
2013年 | 2305篇 |
2012年 | 1567篇 |
2011年 | 1855篇 |
2010年 | 1355篇 |
2009年 | 1643篇 |
2008年 | 1519篇 |
2007年 | 1622篇 |
2006年 | 1359篇 |
2005年 | 1064篇 |
2004年 | 974篇 |
2003年 | 895篇 |
2002年 | 954篇 |
2001年 | 634篇 |
2000年 | 542篇 |
1999年 | 483篇 |
1998年 | 421篇 |
1997年 | 306篇 |
1996年 | 261篇 |
1995年 | 218篇 |
1994年 | 221篇 |
1993年 | 153篇 |
1992年 | 166篇 |
1991年 | 102篇 |
1990年 | 67篇 |
1989年 | 70篇 |
1988年 | 79篇 |
1987年 | 71篇 |
1986年 | 62篇 |
1985年 | 51篇 |
1984年 | 63篇 |
1983年 | 30篇 |
1982年 | 52篇 |
1981年 | 39篇 |
1980年 | 36篇 |
1979年 | 45篇 |
1978年 | 20篇 |
1977年 | 20篇 |
1974年 | 9篇 |
1973年 | 15篇 |
排序方式: 共有10000条查询结果,搜索用时 143 毫秒
141.
Capillary gas chromatography coupled to microwave-inducedplasma detection furnishes sensitivity adequate for trace analysis when the signal is monitored at a carbon emission line. Work performed with one of these systems at high electronic gain for the carbon signal has revealed solvent band widths in excess of four minutes; these impeded quantification of peaks eluting after the solvent. This report discusses two phenomena which could be related to the unexpected intensity of this solvent response: photomultiplier tube saturation and carbon deposits in the quartz plasma discharge tube. 相似文献
142.
无穷区间上二阶微分方程的边值问题 总被引:5,自引:0,他引:5
刘衍胜 《应用泛函分析学报》2002,4(3):211-216
利用Schauder不动点定理讨论了一类非线性二阶微分方程在无穷区间上的边值问题无界解的存在性,部分改进了郭大钧教授最近得到的结果。 相似文献
143.
Microstructures of nickel surfaces electrodeposited on indium tin oxides coated glasses are investigated using atomic force microscopy. The fractal dimension D and Hurst exponent H of the nickel surface images are determined from a frequency analysis method proposed by Aguilar et al. [J. Microsc. 172 (1993) 233] and from Hurst rescaled range analysis. The two methods are found to give the same value of the fractal dimension D∼2.0. The roughness exponent α and growth exponent β that characterize scaling behaviors of the surface growth in electrodeposition are calculated using the height-difference correlation function and interface width in Fourier space. The exponents of α∼1.0 and β∼0.8 show that the surface growth does not belong to the universality classes theoretically predicted by statistical growth models. 相似文献
144.
含铒碲酸盐玻璃的上转换荧光性质研究 总被引:1,自引:0,他引:1
在室温下,用804nm波长的半导体激光器作激发源,在TeO_2-PbO基掺铒碲酸盐玻璃中实现了中心波长分别为525nm,550nm和660nm的上转换发射.荧光强度与激发功率呈非线性关系.估测了PbO含量对上转换荧光相对强度的影响. 相似文献
145.
Enrique J. Baran 《Monatshefte für Chemie / Chemical Monthly》1991,122(6-7):479-481
Summary Mean amplitudes of vibration for OTeF
5
–
have been calculated from known spectroscopic and structural data in a wide temperature range. The results are briefly discussed in comparison with those of related species. 相似文献
146.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
147.
In the core of the seminal Graph Minor Theory of Robertson and Seymour lies a powerful theorem capturing the ``rough' structure
of graphs excluding a fixed minor. This result was used to prove Wagner's Conjecture that finite graphs are well-quasi-ordered
under the graph minor relation. Recently, a number of beautiful results that use this structural result have appeared. Some
of these along with some other recent advances on graph minors are surveyed.
Research partly supported by Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research, Grant number
16740044, by Sumitomo Foundation, by C & C Foundation and by Inoue Research Award for Young Scientists
Supported in part by the Research Grant P1–0297 and by the CRC program
On leave from: IMFM & FMF, Department of Mathematics, University of Ljubljana, Ljubljana, Slovenia 相似文献
148.
149.
Zhitian Liu Lei Wang Junwu Chen Feng Wang Xiaoying Ouyang Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):756-767
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007 相似文献
150.
D. Boilley A. Marchix B. Jurado K. -H. Schmidt 《The European Physical Journal A - Hadrons and Nuclei》2007,33(1):47-52
We propose a new formula for the saddle-to-scission time that is more general that the one based on Kramers' approach. Its
validity and applicability is then studied in detail. Such a formula is useful for the evaluation of the fission time of very
heavy nuclei. 相似文献