全文获取类型
收费全文 | 567篇 |
免费 | 17篇 |
国内免费 | 20篇 |
专业分类
化学 | 481篇 |
力学 | 2篇 |
综合类 | 10篇 |
数学 | 6篇 |
物理学 | 105篇 |
出版年
2023年 | 8篇 |
2022年 | 40篇 |
2021年 | 39篇 |
2020年 | 18篇 |
2019年 | 19篇 |
2018年 | 18篇 |
2017年 | 31篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 20篇 |
2013年 | 42篇 |
2012年 | 40篇 |
2011年 | 17篇 |
2010年 | 20篇 |
2009年 | 23篇 |
2008年 | 18篇 |
2007年 | 26篇 |
2006年 | 27篇 |
2005年 | 17篇 |
2004年 | 25篇 |
2003年 | 21篇 |
2002年 | 19篇 |
2001年 | 4篇 |
2000年 | 17篇 |
1999年 | 8篇 |
1998年 | 12篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
排序方式: 共有604条查询结果,搜索用时 15 毫秒
1.
车前子中多糖含量的测定 总被引:12,自引:1,他引:11
采用蒽酮-硫酸法比色测定,用精制车前子多糖测得车前子多糖对葡萄糖的换算因子,对我国同属不同品种的车前子不同采集时间及炮制前后其多糖含量进行了比较研究。结果表明:此测定方法简便可行。供试液在8h内显色稳定,重现性较好,平均回收率为97.8%,RSD=1.41%(n=5)。江西吉安产大粒车前子生品多糖含量在9.15%~9.83%之间,炮制后其多糖含量在6.29%~6.81%之间;南昌新祺周车前GAP标准基地的大粒车前子生品多糖含量为7.85%~8.38%,炮制后其多糖含量为6.01%~6.64%;东北产的小粒车前子生品多糖含量为6.61%,炮制后其多糖含量为6.45%。 相似文献
2.
3.
Richards模型在蔬菜生长预测中的应用 总被引:6,自引:0,他引:6
本文从 Richards模型的数学表达出发 ,阐述了模型中各参数初始值的确定以及优化过程 .并利用菜花和菠菜的试验数据建立其“最优”生长模型 . 相似文献
4.
5.
The chemical composition of neutral lipids from seeds of Cercis siliquastrum, Sapium sebiferum, and Koelreuteria paniculata were studied. Characteristic features of their individual classes were established.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 318–319, July–August, 2007 相似文献
6.
7.
GC-MS法测定粮谷及油料中55种有机磷农药残留量 总被引:3,自引:0,他引:3
采用ASE-300快速溶剂萃取仪提取样品中农药残留量,提取液经二氯甲烷液-液分配、凝胶色谱柱(GPC)净化,固相萃取柱(活性炭)再净化,浓缩定容后,用气相色谱-质谱仪(GC-MS)测定,外标法定量.采用选择离子检测进行阳性确证.选择玉米、糙米、大豆、花生为实验样品、敌敌畏等55种农药添加水平在0.5~2.00 mg/kg时,该方法回收率为68%~117%;精密度为4.04%~11.76%;方法测定低限为0.005~0.100 mg/kg,各项指标均满足有关要求. 相似文献
8.
The disrupting effect of three different ionic carbohydrates (xanthan, pectin and gum arabic) on the formation of tannin-protein insoluble aggregates was assessed by nephelometry using bovine serum albumin (BSA) and several procyanidin fractions previously extracted from grape seeds. The presence in solution of any of the carbohydrates studied was found to restrain the formation of insoluble protein-tannin aggregates for every procyanidin fraction used. Xanthan was the most effective carbohydrate, whereas gum arabic was the least effective. The present work has revealed that the disrupting effect of carbohydrates is quite different depending on the procyanidin structure complexity. In general, the three carbohydrates studied revealed a similar trend in that their disrupting effect on tannin-BSA aggregate formation decreased with increase of the procyanidin degree of polymerization. 相似文献
9.
Motoyuki Toki 《Journal of Sol-Gel Science and Technology》1994,2(1-3):97-101
This paper describes the attempt to prepare a new group of monodispersed silica-polymer hybrid particles, which consists of silica and amide polymer: poly(vinylpyrrolidone) (PVP) and poly(2-ethyloxazoline) (POXZ). Preparation method is based on the growth of hybrid seeds by the addition of TEOS-polymer solution.Monodispersed PVP-silica hybrid particles of 1.24 µm in diameter were prepared by growing the hybrid seeds of 0.54 µm by the addition of TEOS-PVP solution with ammonia catalyst. In the case of POXZ-silica particles, addition of TEOS-POXZ solution to the solution containing 0.54 µm seeds resulted in monodispersed POXZ-silica hybrid particles and four times repetition of the addition for particle growth gave the hybrid particles of the diameter of 1.6 µm.Improvement of mechanical properties of hybrid particles was observed when the particles were heated at 100 200°C. 相似文献
10.
Bjrn E. Berg Ellen M. Hansen Synnve Gjrven Tyge Greibrokk 《Journal of separation science》1993,16(6):358-363
Supercritical carbon dioxide can be utilized both as an introduction solvent in capillary SFC and as a reaction medium; both possibilities are illustrated in this study. An off-line SFE unit was modified for on-line SFE-SFC. To facilitate rapid depressurization of the extraction cell and to prevent memory effects, a 6-port valve was installed at the outlet line of the extraction unit. An increased background signal was obtained when PEEK polymer was used in the construction of the extraction vessel; when stainless steel was used, the blanks improved. The synthesis of methyl esters and butyl esters of fatty acids from triglycerides in edible fat was examined using an immobilized lipase as a catalyst in on-line SFE-SFC. As a result of 30 minutes reaction – extraction time, high yields of fatty acid esters were obtained at a pressure of 150 bar and a temperature of 50°C. 相似文献