基于单个和级联电吸收调制器超短光脉冲的产生

为研究电吸收调制器(EAM)产生超短光脉冲的性能,在考虑电吸收调制器频率响应的基础上,通过数值模拟和实验研究的方法,从理论和实验上研究了基于国产单个和级联电吸收调制器的超短光脉冲产生,实验和理论相符.基于单EAM可以产生占空比近12%的短脉冲,级联EAM可产生占空比为8%的短脉冲.     

电针对脑卒中后抑郁大鼠谷氨酸类神经递质及其受体的表达影响

观察电针对脑卒中后抑郁(PSD)大鼠的脑部氨基酸类神经递质表达的影响, 探讨电针治疗脑卒中后抑郁的分子机理. 将Wistar大鼠随机分为正常组、假手术组、模型组和电针治疗组, 采用夹闭颈总动脉和再通方法建立脑卒中模型. 7d后根据文献[1]方法建立PSD模型, 电针“百会”“大椎”穴, 留针20min, 1次·d-1共持续15d. 旷场试验观察其行为学表现, 免疫组织化学技术检测大鼠脑谷氨酸类神经递质的表达变化结果. 与模型组相比, 行为学实验发现电针治疗组大鼠旷场穿线抬壁次数明显增多, 差异具有统计学意义(P<0.05); 免疫组化检测发现谷氨酸及其受体NMDA/AMPA积分光密度值明显下降, 差异具有统计学意义(P<0.01). 表明电针可抑制脑卒中后抑郁大鼠脑NMDA/AMPA的表达, 这可能是电针治疗脑卒中后抑郁的分子机理之一.     

On the analysis of a simple evolutionary algorithm on quadratic pseudo-boolean functions

Evolutionary algorithms are randomized search heuristics, which are often used as function optimizers. In this paper the well-known (1+1) Evolutionary Algorithm ((1+1) EA) and its multistart variants are studied. Several results on the expected runtime of the (1+1) EA on linear or unimodal functions have already been presented by other authors. This paper is focused on quadratic pseudo-boolean functions, i.e., polynomials of degree 2, a class of functions containing NP-hard optimization problems. Subclasses of the class of all quadratic functions are identified where the (1+1) EA is efficient, for other subclasses the (1+1) EA has exponential expected runtime, but a large enough success probability within polynomial time such that a multistart variant of the (1+1) EA is efficient. Finally, a particular quadratic function is identified where the EA and its multistart variants fail in polynomial time with overwhelming probability.     

An adaptive decision maker for constrained evolutionary optimization

An adaptive decision maker (ADM) is proposed for constrained evolutionary optimization. This decision maker, which is designed in the form of an adaptive penalty function, is used to decide which solution candidate prevails in the Pareto optimal set and to choose the individuals to be replaced. By integrating the ADM with a model of a population-based algorithm-generator, a novel generic constrained optimization evolutionary algorithm is derived. The performance of the new method is evaluated by 13 well-known benchmark test functions. It is shown that the ADM has powerful ability to balance the objective function and the constraint violations, and the results obtained are very competitive to other state-of-the-art techniques referred to in this paper in terms of the quality of the resulting solutions.     

三苯基膦和三甲基氯硅烷直接引发丙烯酸乙酯基团转移聚合的核磁共振动力学研究

用FT-NMR的动态³¹P NMR谱及动态¹H NMR谱对用三苯膦(TPP)和三甲基氯硅烷(TMCS)直接引发丙烯酸乙酯(EA)的基团转移聚合(GTP)进行了动力学跟踪,初探了该GTP反应的引发阶段、链增长阶段、链终止阶段的基础反应;三苯膦对丙烯酸乙酯的共轭加成的动力学行为;溴化锌在该反应体系的催化作用等,提出了在这种新的引发体系内的GTP反应历程。     

Atmospheric pressure photoionization for coupling liquid-chromatography to mass spectrometry: A review

This review presents the state-of-the-art techniques that couple liquid chromatography (LC) and mass spectrometry (MS) via atmospheric pressure photoionization (APPI). The different ionization mechanisms are discussed as well as the influence of the mobile phase composition, the nature of the dopant, etc. A comparison with other ionization sources, such as electrospray ionization (ESI) and atmospheric pressure chemical ionization (APCI), is reported, and the combination of APPI with these sources is also discussed. Several applications, covering the time period of 2005-2008, for the analysis of drugs, lipids, natural compounds, pesticides, synthetic organics, petroleum derivatives, and other substances are presented.     

新型水溶性大π共轭高分子——聚吡咯｛2,5-[双(对二甲氨基苯甲烯)]｝的合成

该研究合成了一种新型水溶性大π共轭高分子———聚吡咯 ｛２ ,５ ［ 二（ 对二甲氨基苯甲烯）］｝（ＰＰＤＭＡＢ） ,它能溶于强酸的水溶液,在１ｍｏｌ／Ｌ 的盐酸中溶解度为０－５ ～１－０ｇ／１００ｍＬ．通过ＥＡ、ＸＰＳ、ＦＴ ＩＲ、ＵＶ Ｖｉｓ ＮＩＲ、Ｉｎ ｓｉｔｕ ＵＶ Ｖｉｓ ＮＩＲ 对ＰＰＤＭＡＢ进行了结构表征．通过质子化、碘掺杂、浓硫酸（９８ ％ ） 掺杂等处理,ＰＰＤＭＡＢ的电导率提高２～４ 个数量级（δ＝ １０ － ７ ～１０－ ５Ｓ／ｃｍ） ．在质子化、去质子化的过程中ＰＰＤＭＡＢ发生了可逆的颜色变化,本征态（ 综色） 质子态（ 墨兰色） ．     

High-Speed Coplanar Waveguide Based Submount for 40 Gbit/s Electroabsorption Modulator

A high-speed submount has been designed and fabricated for 40 Gb/s electroabsorption (EA) modulators. The submount contains a coplanar waveguide (CPW) for microwave signal feeding and a Ta₂N thin-film resistor for impedance matching. The CPW transmission line is designed to ensure low microwave loss and reflection, and Ti/Cu/Ni/Au metal is adopted for electrode fabrication to guarantee good contact with the Ta₂N thin-film. The typical reflection coefficient of fabricated submount is estimated to be lower than−21 dB up to 40 GHz. As a demonstration, a high-speed EA modulator was chip-level packaged using the high-speed submount, and the measured small-signal modulation bandwidth was over 40 GHz.     

Analysis of β‐CH2 signals in the 13C NMR spectra of the methyl methacrylate–ethyl acrylate copolymer as a tool for microstructure determination

The incremental method of the chemical shift calculation in the ¹³C NMR spectra of the methyl methacrylate–ethyl acrylate copolymer, PMMA/EA, has been applied to the β‐CH₂ carbons. A positive simulation of the DEPT sub‐spectrum shows that it is possible to determine in this way the distribution of configurational‐compositional tetrads providing a tool for microstructure analysis of acrylic copolymers. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2147–2155, 2000